For the effective treatment of shipboard sewage continuously, a non-diaphragm electrolytic treatment device using DSA type insoluble electrode, Ti/IrO2, anode and H-C metal cathode, was studied. The most effective electrolytic conditions were obtained when cell clearance, 6mm, pH 5-6 and the concentration of seawater, more than 20% as batch test results. The COD removal rate was varied in logarithmic function, showed as C=Coe-KE and the required current was E = A/QCo [A.min/mgCOD]. When the COD removal effeciency was more than 90%, the electrolytic reaction constant was 0.02.
Each factor for the most effective electrolytic reaction in treating shipboard sewage was enhanced by means of batch electrolyitc reactor using DSA electrode. The effective clearance was 6mm and pH was 5-6. In such case, more than 20% of sea water concentration was needed to attain 90% of COD removal rate. The suspended solids was effectively removed by electro-floatation in proportion as charged current density. The nitrogen and posporous were effectively removed in the electrolytic device when mixed seawater.
An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.
The lifetime of the electrode is one of the most important factors on the stability of the electrode. Since the lifetime of the DSA (Dimensionally stable anode) electrode is long, an accelerated lifetime test is required to reduce the test time. Beacuse there is no basis or standard method for accelerated lifetime testing, many researchers use different methods. Therefore, there is a need for basis and methods for accelerated lifetime testing that other researchers can follow. We designed a reactor system for accelerated lifetime testing and planned specific methods. Reactor system was circulating batch reactor. Reactor volume and cooling water tank were 12.5 L and 100 L, respectively. Electrode size was 2 cm x 3 cm (real electrolysis area, 5 cm2). In order to maintain the harsh conditions, accelerated lifetime test was carried out in a high current density (0.6 A/cm2) and low electrolyte concentration (NaCl, 0.068 mol/L). Maintaining a constant temperature was an important operation parameter for exact accelerated lifetime test. As the accelerated lifetime test progressed, the active component of electrode surface was consumed and desorption occurred. At the point of 5 V rise, corrosion of the surface of the base material(titanium) also started.
뇌혈관을 관찰할 수 있는 영상 진단장치 중 MRA, CTA, DSA 3장비 영상에 관한 SNR과 CNR을 비교, 분 석하여 뇌혈관 검사 시 최적의 검사기기를 알아보고자 하였다. 2016년 11월부터 2017년 5월까지 뇌혈관 진 단 검사를 받은 환자 90명을 대상으로 하였고, 측정부위는 Rt MCA, Lt MCA, ACA Image J를 이용하여 측 정 하였다. 정량적 분석 결과 MRA의 평균 SNR은 254.87 CNR은 178.13, 신호강도는 326.81, CTA의 평균 SNR은 74.75, CNR은 62.2, 신호강도는 356.66, DSA의 SNR은 26.85, CNR은 25.89, 신호강도는 4400.69 로 평가되었다(p<0.05). 결과적으로 SNR과 CNR 모두에서 MRA>CTA>DSA 순으로 측정 되었다. 유의성 평가 방법으로 SPSS 통계 분석 프로그램을 이용하여 ANOVA 분석을 하였고, 사후분석으로 bonferroni method를 사용하여 p<0.05 일 때 유의한 것으로 판단하였다. 결론적으로 본 실험에서 뇌혈관 질환 환자를 무작위로 선정하여 평가하였을 때 최적의 영상진단 장비로 MRA, CTA, DSA의 결과를 얻었다.
PACS에서 용량이 큰 의료영상은 대용량 저장장치를 필요로 하고, 느린 전송으로 인하여 PACS의 성능을 저하시킨다. 따라서 판독의에 의해 판독되어진 영상이나 장기간 저장하는 영상의 질을 떨어뜨리지 않고, 추후 판독에 영향을 주지 않는 범위 내에서 압축하여 보관하게 된다. 압축 및 영상 저장·전송시 발생되는 noise과 영상저장 및 전송시 발생하는 정보손실 그리고 의료영상을 모니터에서 출력시 발생하는 화질저하 등 많은 문제점 들이 발생한다. 본 연구는 P사 DSA 시스템의 Server display monitor와 Client display monitor의 PSNR을 평가하여 Server display 신호획득에서 부터 Client display monitor까지의 과정에서 발생하는 PSNR에 대한 평가 및 개선방안을 제안하고자 한다. 실험에 사용한 장비는 P사 DSA를 사용하였다. 혈관조영술 영상을 display하여 실험에 사용한 모니터로는 2가지로써 P사의 해상도 1280×1024 픽셀 모니터와 W사의 해상도 1536×2048 픽셀 모니터를 사용하였다. PACS Program은 MARO-view를 이용하였고 실험을 위해서 Visual C++을 이용한 PSNR 측정 Program을 구현하여 실험에 사용하였다. 실험결과 No 1, 3번의 PSNR에 변화가 없는 것은 영상의 전송과 디스플레이상에 Error가 없는 것으로 나타났으며, 압축률에서는 압축률이 낮은 쪽이 화질저하가 적었고, 영상의 손실 차이가 미미해 압축률에 따른 큰 문제점은 발견되지 않았다.
Fabrication and oxidants production of 3 or 4 components metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru as main component and Pt, Sn, Sb and Gd as minor components) were used for the 3 or 4 components electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at 500℃ for 1 h. The removed RhB per 2 min and unit W of 3 components electrode was in the order: Ru:Sn:Sb=9:1:1 > Ru:Pt:Gd=5:5:1 > Ru:Sn=9:1 > Ru:Sn:Gd=9:1:1 > Ru:Sb:Gd=9:1:1. Although RhB decolorization of Ru:Sn:Sb:Gd electrode was the highest among the 4 components electrode, the RhB decolorization and oxidants formation of the Ru:Sn:Sb=9:1:1 electrode was higher than that of the 3 and 4 components electrode. Electrogenerated oxidants (free Cl and ClO2) of chlorine type in 3 and 4 components electrode were higher than other oxidants such as H2O2 and O3. It was assumed that electrode with high RhB decolorization showed high oxidant generation and COD removal efficiency. OH radical which is electrogenerated by the direct electrolysis was not generated the entire 3 and 4 components electrode, therefore main mechanism of RhB degradation by metal oxide electrode based Ru was considered indirect electrolysis using electrogenerated oxidants.
Fabrication and oxidants formation of 1 and 2 component metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru, Pt, Sn, Sb and Gd) were used for the 1 and 2 component electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at 500℃ for 1 h. The removed RhB per 2 min and unit W for one component electrode decreased in the following sequences: Ru/Ti > Sb/Ti > Pt/Ti > Gd/Ti > Sn/Ti. The concentration of oxidants generated in 1 and 2 component electrodes was in the order of: ClO2 > free Cl > H2O2 > O3. OH radical was not generated from in entire one and two component electrodes. RhB degradation rate and generated oxidants of the Ru-Sn=9:1 electrode was higher than that of the two component electrode. The exact relationship between the removal of RhB and the generated oxidants concentration was not obvious. However, it was assumed that electrode with high RhB decolorization had high oxidant concentration.