기후변화로 인해 전 세계적으로 수온이 상승하는 추세이며, 그에 따른 수계 내 유기물의 농도 증가에 따라 정수 처리 과정에서의 소독부산물 생성량 역시 상승하고 있다. 이 중 총트리할로메탄(Trihalomethanes, THMs)은 발암물질로 분류되며, 먹는 물 수질 기준이 0.1 mg/L로 설정되어 있다. 소독부산물 생성량 증가와 취수원에서의 수질 문제가 지속적으로 제기됨에 따라 안정적 수돗물 공급을 위한 대책이 필요한 상황에서 본 연구는 여름철 경기도와 경상북도 지역의 수도꼭지에서 THMs 농도를 모니터링 하였다. 또한, 과거 THMs 측정 자료와 더불어 다양한 자료를 비교ㆍ분석하여 THMs 농도 변화의 원인을 파악했다. 그 결과, 조사 지역들의 THMs 생성에는 원수의 종류, 그로 인한 용존유기탄소 (Dissolved organic carbon, DOC), 클로로필-a 인자와 더불어 계절적 요인들 중 기온과 강우량이 종합적으로 기여하는 것으로 나타났다. 특히, 선형 회귀분석을 통해 용존유기탄소와 THMs간의 상관관계가 높으며 수돗물의 용존유기탄소 농도가 2.7 mg/L 이상일 경우 THMs 농도가 법정 먹는 물 수질 기준을 초과할 가능성이 높다는 결과를 도출하였다. 이를 통해 여름철 강우가 집중되는 시기와 갈수기 THMs 관리를 위해 원수의 유기물 농도를 관리하는 노력이 필수적임을 확인하였다. 해당 결과는 정수장에서의 유기물 농도 관리를 통해 THMs 생성을 억제하는 것이 매우 중요함을 시사하며, 앞으로 먹는 물 수질 기준과 정수장 운영 관리에 용존유기탄소 수질 항목을 추가하는 방안의 검토가 필요하다 판단된다.

This study investigated the behavior and environmental impact of expanded polystyrene (EPS) in a simulated marine environment, focusing on the effects of UV exposure. Through a series of controlled experiments, it was found that UV-induced weathering increased the formation of smaller EPS degradation products, leading to higher concentrations of dissolved organic carbon (DOC) in the seawater. Additionally, it was suggested that the assembly behavior of dissolved organic matter (DOM) contributed to the reduction of DOC levels over time. The EPS layer exhibited slightly higher DOC concentrations compared to the seawater, likely due to hydrophobic interactions that retained degradation products near the EPS. Analysis of the soil layer revealed that EPS particles and degradation products settled or adsorbed more extensively under UV conditions, indicating a greater risk of sediment contamination. Soil layer elution experiments further confirmed that EPS particles and their degradation products could migrate through soil pores, posing a potential contamination risk to other environments. UV exposure resulted in a twentyfold increase in DOC release from EPS compared to dark conditions. These findings highlight the persistent pollution potential of EPS in marine environments, especially under UV exposure, and emphasize the need for effective EPS waste management and further research into its environmental impacts.

Dissolved organic matter (DOM) is a key component in the biogeochemical cycling in freshwater ecosystem. However, it has been rarely explored, particularly complex river watershed dominated by natural and anthropogenic sources, such as various effluent facility and livestock. The current research developed a new analytical method for TOC/TN (Total Organic Carbon/Total Nitrogen) stable isotope ratio, and distinguish DOM source using stable isotope value (δ13C-DOC) and spectroscopic indices (fluorescence index [FI] and biological index [BIX]). The TOC/TN-IR/MS analytical system was optimized and precision and accuracy were secured using two international standards (IAEA-600 Caffein, IAEA-CH-6 Sucrose). As a result of controlling the instrumental conditions to enable TOC stable isotope analysis even in low-concentration environmental samples (<1 mgC L-1), the minimum detection limit was improved. The 12 potential DOM source were collected from watershed, which includes top-soils, groundwater, plant group (fallen leaves, riparian plants, suspended algae) and effluent group (pig and cow livestock, agricultural land, urban, industry facility, swine facility and wastewater treatment facilities). As a result of comparing characteristics between 12 sources using spectroscopic indices and δ13C-DOC values, it were divided into four groups according to their characteristics as a respective DOM sources. The current study established the TOC/TN stable isotope analyses system for the first time in Korea, and found that spectroscopic indices and δ13C-DOC are very useful tool to trace the origin of organic matter in the aquatic environments through library database.