This study aimed to fabricate composites with high thermal conductivity using diglycidyl ether of bisphenol-A (DGEBA), incorporating carbon fiber cloth (CFC) and graphene as reinforcing agents. Notably, the dispersion of graphene within the DGEBA matrix was enhanced through surface modification via a silane coupling agent. The effects of CFC and graphene addition on the impact strength, thermal conductivity, and morphology of the composites were examined. The experimental results showed that the incorporation of 6 wt% CFC resulted in a substantial (16-fold) increase in impact strength. Furthermore, the introduction of 6 wt% CFCs along with 20 wt% graphene led to a remarkable enhancement in thermal conductivity to 5.7 W/(m K), which was approximately 22 and 4 times higher than the intrinsic thermal conductivities of pristine DGEBA and the CFC/DGEBA composite, respectively. The increased impact strength is ascribed to the incorporation of CFC and silane-modified graphene. Additionally, the gradual increase in thermal conductivity can be attributed to the enhanced interaction between the acidic silane-modified graphene and the basic epoxy–amine hardener within the system studied.

Dimethyl silicone oil is widely used due to its excellent thermal stability and good wetting properties. In this study, a series of thermal conductive materials was prepared by physically blending and chemically loading graphene as a thermal conductive filler into dimethyl silicone oil, and their thermal conductivity and tribological properties were investigated. The thermal conductivity of the composites was tested by a thermal conductivity meter and a thermal imaging camera, while the tribological properties of the composites were evaluated using a CSM friction and wear tester. The results showed that both thermal conductivity and tribological properties were improved to a certain extent. The particle size and amount of graphene had a significant influence on the thermal conductivity. For graphene with a single particle size, the thermal conductivity increased with increasing graphene content. The friction coefficient under dry friction conditions was significantly reduced by adding graphene to the silicone oil, as revealed by the friction and wear test.

Graphene nanoplatelets (GNPs) have garnered significant attention in the field of thermal management materials due to their unique morphology and remarkable thermal conductive properties. Their impressive thermal properties make them an interesting choice of nanofillers with which to produce multifunctional composite materials and a host of other applications whilst their structural and thermal properties significantly improve their target materials or composites. Therefore, this present study reviewed recent advances in the use of GNPs as nanofillers to enhance the thermal conductivity of various materials or composites. The improved thermal conductivity that GNPs impart in composites is also comprehensively compared and discussed. Therefore, this review may reveal hitherto unknown opportunities and pave the way for the production of materials with enhanced thermal applications including electronics, aerospace devices, batteries, and structural reinforcement.

Graphene fiber is considered as a potential material for wearable applications owing to its lightness, flexibility, and high electrical conductivity. After the graphene oxide (GO) solution in the liquid crystal state is assembled into GO fiber through wet spinning, the reduced graphene oxide (rGO) fiber is obtained through a reduction process. In order to further improve the electrical conductivity, herein, we report N, P, and S doped rGO fibers through a facile vacuum diffusion process. The precursors of heteroatoms such as melamine, red phosphorus, and sulfur powders were used through a vacuum diffusion process. The resulting N, P, and S doped rGO fibers with atomic% of 6.52, 4.43 and 2.06% achieved the higher electrical conductivities compared to that of rGO fiber while preserving the fibrious morphology. In particular, N doped rGO fiber achieved the highest conductivity of 1.11 × 104 S m−1, which is 2.44 times greater than that of pristine rGO fiber. The heteroatom doping of rGO fiber through a vacuum diffusion process is facile to improve the electrical conductivity while maintaining the original structure.

Herein, we report significantly enhanced mechanical properties and thermal conductivity of polyimide (PI) by incorporating a small amount (0.01 wt %) of individualized boron-doped high-quality graphene as a filler. The boron-doped expandable graphite (B-EG) was synthesized by mixing boric acid ( H3BO4) with expandable graphite (EG) and thermally treating the mixture at 2450 °C for 30 min using a graphite furnace in an argon atmosphere. The boron-doped graphene (B-g) was prepared by the solution-phase exfoliation of B-EG with an ultrasonication process, which is a method to obtain individualized graphene as well as few-layer graphene. The PI nanocomposites were prepared using the obtained graphene. The PI nanocomposites synthesized with high-quality B-graphene (B-g) showed enhanced mechanical properties and thermal conductivity compared to those of pure PI due to the doping effects and strong interfacial interactions between graphene and the PI matrix.

Facile process for the fabrication of multi-layer graphene thin film (MLGF) is reported here. Multi-layer graphene dispersion prepared by liquid-phase exfoliation of graphite was sprayed on a glass substrate by spray pyrolysis method. The structural, optical and electrical properties of the deposited MLGF are investigated. The sheets of graphene are deposited uniformly on the substrate and distribution of small graphene sheets with size of 300–500 nm can be observed in SEM image. AFM and micro-Raman results ensured that the spray-coated graphene thin film is composed of multi-layer graphene sheets. Spray coated graphene thin film showed significant optical transparency of 57% in the visible region (400–550 nm). MLGF possessed the electrical conductivity in the order of 744 S/m with surface resistivity of 3.54 k Ω/sq. The prepared liquid-phase exfoliated graphene thin film showed superior photoelectric response. The results of this study provided a framework for fabricating an optimized MLGF using a spray pyrolysis route for optoelectronics devices.

본 연구에서는 뛰어난 전도도와 물리적 강도를 가지는 그라핀의 고른 분산성을 얻기 위하여 두 가지 다른 방법으로 그라핀을 개질시켰다. 그리고 SPAES/그라핀 복합막은 각기 다른 함량을 첨가하여 제조되었으며 그라핀의 제조방법과 첨가된 그라핀의 함량에 따른 성능을 비교하였다. 복합막의 모폴로지는 SEM을 이용하여 관찰하였으며 개질된 그라핀의 화학적 구조는 FT-IR과 TGA를 사용하여 분석되었다. 그라핀의 함량변화가 0.5~3.0 wt% 일 때 복합막의 이온전도도와 메탄올 투과도를 측정하였으며 80℃, 100% 가습상태에서 SPAES/그라핀 복합막의 이온전도도(0.216 S/cm)는 순수한 SPAES 전해질 막보다 높은 이온전도도(0.098 S/cm)를 나타내었으며 그라핀의 함량이 1.5 wt%까지 증가될 때 메탄올 투과도는 감소되었다.

Carbon materials such as graphite and graphene exhibit high electrical conductivity. We examined the electrical conductivity of synthetic and natural graphene powders after the chemical reduction of synthetic and natural graphite oxide from synthetic and natural graphite. The trend of electrical conductivity of both graphene (synthetic and natural) was compared with different graphite materials (synthetic, natural, and expanded) and carbon nanotubes (CNTs) under compression from 0.3 to 60 MPa. We found that synthetic graphene showed a marked increment in electrical conductivity compared to natural graphene. Interestingly, the total increment in electrical conductivity was greater for denser graphite; however, an opposite behavior was observed in nanocarbon materials such as graphene and CNTs, probably due to the differing layer arrangement of nanocarbon materials.