We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N NaClO4 solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.

Electron transfer through an Langmuir-Blodgett(LB) monolayer film sandwiched between metal electrodes. We used an eicosanoic acid material and the material was very famous as a thin film insulating material. Eicosanoic acid monolayer was deposited by Langmuir-Blodgett(LB) technique and a subphase was a CdCl2 solution as a 2×10-4 mol/L. Also we used a bottom electrode as an Al/Al2O3 and a top electrode as a Al and Ti/Al. Here, the Al2O3 on the bottom electrode was deposited by thermal evaporation method. The Al2O3 layer was acted on a tunneling barrier and insulating layer in tunnel diode. It was found that the proper transfer surface pressure for film deposition was 25 mN/m and the limiting area per molecule was about 24 a2/molecule. When the positive and negative bias applied to the molecular device, the behavior shows that a tunnel switching characteristics. This result were analyzed regarding various mechanisms.

Polyamic acid alkylamine (N, N-dimethylhexadecylamine)(PAAS)염을 합성하여 그 합성여부를 확인하였으며 PAAS염의 Langmuir막의 π-A 등온선 및 표면 전위 특성 등을 조사 하였다. Langmuir-Blodgett법에 의하여 PAAS염의 LB막을 여러종류의 기관에 누적하였으며 누적여부를 자외선 흡수 스펙트럼 및 적외선 투과 스펙트럼을 이용하여 조사하였다. 그리고 PAAS LB막을 열처리에 의하여 이미드(imide)화시켜 폴리이미드 LB막을 제조하였으며 그 이미드화 여부를 자외선 및 적외선 스펙트럼을 이용하여 조사하였다.