반강성 포장공법은 콘크리트포장의 강성과 아스팔트포장의 연성을 동시에 만족시킬 수 있도록 개발된 포장공법으로 국내외에서 기술개발 및 현장적용이 활발히 이루어지고 있다. 반강성 포장공법은 포장 후 빠른 교통개방을 위하여 초속경 시멘트를 사용하여 주입재를 제조하는데 이때, 초속경 시멘트의 급결성 때문에 경화시 수화열로 인한 균열이 발생되는 문제점을 가지고 있다. 또한, 주입재의 유동성능 확보와 균열 저감을 목적으로 아크릴레이트 사용시 경제성이 낮은 단점을 가진다. 이에 대한 방안으로서, 수화열저감을 위하여 PCM(Pease change material)을 사용하고, 연간 120만톤 이상 부산되어 다량 폐기되는 유황을 에멀젼화하여 아크릴레이트의 대체재로서 사용 가능성을 검증하기 위한 기초연구를 수행하였다. PCM 및 SPE를 혼합한 반강성 포장용 시멘트 주입재의 압축강도 측정은 KS L ISO 679에 준하여 시험체를 제작하여 측정하였다. 배합조건은 W/B=40%, PCM 혼입률을 시멘트 질량의 0, 0.2, 0.5%로 첨가하고, SPE는 아크릴 대체률 0, 15, 30%로 하였다. 평가 결과, PCM의 혼입률에 따른 강도특성은 혼합하지 않은 Plain에 비하여 0.2%에서는 재령에 따라 유사한 강도특성을 나타내었지만, 0.5% 혼입시 약 8 ~ 13%의 강도저하가 발생되었다. 아크릴레이트에 대한 SPE의 대체율에 따른 강도특성은 초기 재령에서 혼입률의 증가에 따라 강도가 미소하지만 감소되는 것으로 나타났다. 본 연구에서 검토한 결과, PCM 및 SPE의 반강성 포장용 주입재에 대한 혼화재 및 대체재로서 사용가능성을 확인하였으며, 추후 수화열 저감성능 확인 및 내구성능 등의 검토가 이루어져야 할 것으로 사료된다.

the desulphurization process. To exploit this abundance, the applications of sulphur must be expanded. as excellent durability of reuse of leftover sulphur which has high potential for utilization in construction materials, the study is actively in progress. Meanwhile, there has been active research on semi-rigid pavements that draw on the strengths and overcome the weaknesses of asphalt and concrete pavements. Acrylate is used to prevent cracking but involves a high cost, thus, an alternative material is required. As such, this study presents methods on the reuse of leftover sulphur and examines the engineering performance of grout containing sulfur polymer emulsion (SPE) for use in semi-rigid pavements. Our analysis shows that grout in which 30% of acrylate is replaced with SPE has superior properties in terms of time of flow and strength compared to regular grout. However, performance declined when more than 50% of acrylate was replaced by SPE, indicating that the optimum replacement level is 30%. Through SEM analysis, we found that grout with utra harding cement in this study at three hours had similar hydration properties to that of Type 1 Ordinary Portland Cement (OPC) at seven days, and maintained the properties regardless of grout containing SPE. OPC and grout with a replacement level of 30% displayed similar levels of chloride invasion resistance, whereas grout without SPE was far less resistant. Within the scope of this paper, the optimum replacement level of acrylate with SPE was found to be 30% in consideration of various properties such as time of flow, strength, and chloride invasion resistance.

The study was carried out to evaluate the new analytical method of phthalate esters(diethylphthalate, di-n -butylphthalate, butylbenzylphthalate, bis(2-ethylhexyl)phthalate), one of the endocrine disruptors, which were performed by GC/MS-SIM(selected ion monitoring). The phthalate esters were extracted from water samples using solid-phase extraction on C18 columns. It investigated that the extraction recovery rate of phthalate esters with different solvents and solvent volume. The optimal solvent was dichloromethane and proper volume of dichloromethane for recovery of phthalate esters was 4 mL. There were good linearities(above R2=0.9975) in the range 0.01～0.50㎎/L, and the detection limits were below 0.01～0.03㎍/L. The recovery rates, RSD and MDLs for phthalate esters were 80～114%, 5.0～8.1% and 0.03～0.11㎍/L, respectively. This method shows a good precision of phthalate esters.