Exploring highly efficient, and low-cost oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts is extremely vital for the commercial application of advanced energy storage and conversion devices. Herein, a series of graphene-like C2N supported TMx@C2N, (TM = Fe, Co, Ni, and Cu, x = 1, 2) single- and dual-atom catalysts are designed. Their catalytic performance is systematically evaluated by means of spin-polarized density functional theory (DFT) computations coupled with hydrogen electrode model. Regulating metal atom and pairs can widely tune the catalytic performance. The most promising ORR/OER bifunctional activity can be realized on Cu2@ C2N with lowest overpotential of 0.46 and 0.38 V for ORR and OER, respectively. Ni2@ C2N and Ni@C2N can also exhibit good bifunctional activity through effectively balancing the adsorption strength of intermediates. The correlation of reaction overpotential with adsorption free energy is well established to track the activity and reveal the activity origin, indicating that catalytic activity is intrinsically governed by the adsorption strength of reaction intermediates. The key to achieve high catalytic activity is to effectively balance the adsorption of multiple reactive intermediates by means of the synergetic effect of suitably screened bimetal atoms. Our results also demonstrate that lattice strain can effectively regulate the adsorption free energies of reaction intermediates, regarding it as an efficient strategy to tune ORR/OER activity. This study could provide a significant guidance for the discovery and design of highly active noble-metal-free carbon-based ORR/OER catalysts.

PURPOSES : This study is to compare sound transmission loss(STL) value depending on the four kinds of materials, PC(Polycarbonate), PMMA(Polymethyl mathacrylate), PE(Polyethlyene), PP(Polypropylene), and two types of structure, single layer and double with vacuum layer, of soundproof panel. METHODS : With four sorts of polymer material, the specimens were made as various structures, 4 mm and 8 mm of single soundpoof panel and vacuum layered 4 mm of one. The experimental condition and procedures were complied with authorized process test, KS F 2808. RESULTS: STL of single panel made of PC were the greatest followed by PMMA, PE, PP regardless of the thickness of panel, However, STL of PMMA panel began to decrease around 2500 Hz and reached the lowest value among others in 5000 Hz. Vacuum layer soundproof panel showed good performance in more than 2000 Hz. Only vacuum layer panel made of PC presented resonance frequency at 800 Hz while that of other vacuum ones at 1000 Hz. CONCLUSIONS: According to results of single layer, it was found that single panel functioned as the theorical way we expected in terms of surface density. That trends were blurred as the panel got thicker. And it was suggested also that vacuum layer panel performed well at high frequency, more than 2000 Hz.