Radioactive waste (hereinafter referred to as mixed waste) containing hazardous substances (heavy metals, organic and inorganic waste liquids, asbestos, etc.) has been continuously generated from domestic nuclear power plants, nuclear facilities, and other industrial facilities, and heavy metals were released during the dismantlement of Kori Unit 1 and Wolseong Unit 1. Lead, cadmium, mercury, arsenic), asbestos, decontamination waste liquid (organic/inorganic waste liquid), etc. may be generated. Although hazardous waste related to the nuclear industry continues to be generated, only the regulation direction for hazardous substances is presented in the provisions related to hazardous substances in the delivery regulations for low and intermediate-level radioactive waste and the acceptance criteria for low and intermediate-level radioactive waste disposal facilities. In particular, because there is no clear definition of “hazardousness” and specific standards such as concentration and characteristics for classification of hazardous substances, as well as hazard removal procedures when the hazardousness of radioactive waste is confirmed, no hazardous substances have been delivered in Korea to date and many mixed wastes are stored at each generation facility or at the NPP. As a plan to improve delivery standards related to mixed waste is being prepared recently, it is believed that if the acceptance standards are revised accordingly, it will be possible to confirm the suitability for disposal of drums produced after the establishment of the acceptance standards in 2015. However, it is believed that securing disposal suitability for waste that was packed in 200L drums and compressed under super high pressure in the absence of specific technical standards and regulatory guidelines for the disposal of radioactive waste containing hazardous substances would still remain a difficult problem. In this report overseas acceptance standards related to hazardous waste were reviewed and a plan to secure the disposal suitability of 200 L drums compressed with of super high pressure was proposed.
As the decommissioning of Kori Unit 1 progresses, securing technology for treatment and disposal of radioactive wastes that have not been disposed of so far, such as spent filters, is recognized as an urgent task. In this study, a method of confirming the disposal suitability of spent filters was presented by reviewing the waste characteristics as presented in the waste acceptance criteria (WAC). The waste characteristics to be satisfied to ensure disposal suitability of waste are largely classified into general requirements, solidification and immobilization requirements, radiological requirements, physical requirements, chemical requirements, and biological requirements. First, the general requirement is to prove that the prohibited waste form has not been introduced into items related to waste form and packaging, and to confirm the suitability of disposal through step-by-step packaging photos, generation information, X-ray inspection, and visual inspection. Second, in the solidification and immobilization requirements, spent filters are non-homogeneous waste, and if the total radioactivity concentration of nuclides with a half-life of more than 20 years is 74,000 Bq·g−1 or more, they must be immobilized. Third, in order to meet the characteristic criteria for nuclides and radioactivity concentration, sampling and scaling factors development are required and based on this, nuclides must be identified and demonstrated to be below the disposal concentration limits. Surface dose rate and surface contamination should be measured in accordance with standardized procedures and disposal suitability should be confirmed through document tests recording the measured values. Fourth, in order to satisfy the physical requirements of the particulate matter and filling rate characteristics, the spent filter must be immobilized, if necessary, thereby ensuring disposal suitability. Meanwhile, free water in the spent filter should be removed through pre-drying and dehydration, and the disposal suitability should be confirmed by applying a test. Fifth, the criteria for chelating agents should be checked for disposal suitability through operation records and component analysis of spent filters, and documents, that can prove harmful substances are removed in advance and no harmful substances are included in the package, should be provided. Lastly, in biological requirements, if the spent filters contain corrosive or infectious substances, they should be removed in advance and disposal suitability should be confirmed by providing documents that can prove that such substances are not included in the package.