The concentration of VOCs, NO2 was measured both inside and outside residential homes surrounding an industrial complex. Measurements were performed in the area of the industrial complexes and around 10 km away from the industrial complex area. Benzene did not exceed the air quality standard value. Toluene exhibited a high value of concentration in outdoor Yeosu investigated group. The concentration of NO2 is higher than outside concentrations of houses in both inside housing research group compared with the group of Gwangyang and Yeosu. Benzene and toluene showed high correlation (p<0.001) in the housing interior in Gwangyang, It showed a high correlation (p<0.01) in the housing interior in the comparison group. In Yeosu there was a high correlation (p<0.001) between the inside and outside of the housing in the survey group. In the control group there was only high correlation (p<0.05) in the inside of the housing.