We report the synthesis and gas sensing properties of bare and ZnO decorated TeO2 nanowires (NWs). A catalyst assisted-vapor-liquid-solid (VLS) growth method was used to synthesize TeO2 NWs and ZnO decoration was performed using an Au-catalyst assisted-VLS growth method followed by a subsequent heat treatment. Structural and morphological analyses using X-ray diffraction (XRD) and scanning/transmission electron microscopies, respectively, demonstrated the formation of bare and ZnO decorated TeO2 NWs with desired phase and morphology. NO2 gas sensing studies were performed at different temperatures ranging from 50 to 400 oC towards 50 ppm NO2 gas. The results obtained showed that both sensors had their best optimal sensing temperature at 350 oC, while ZnO decorated TeO2 NWs sensor showed much better sensitivity towards NO2 relative to a bare TeO2 NWs gas sensor. The reason for the enhanced sensing performance of the ZnO decorated TeO2 NWs sensor was attributed to the formation of ZnO (n)/ TeO2 (p) heterojunctions and the high intrinsic gas sensing properties of ZnO.

2020년 중국의 COVID-19 폐쇄는 한국의 풍상측에 위치한 중국의 대기오염 배출량을 감소시켰다. 몽골 북부로 부터 중국 동부를 거쳐 한반도에 이르는 지역에서는 2020년 1~2월에 기온 아노말리가 양(+)으로 온난하였고, 2020년 1월에는 동서류 아노말리가 음(−)으로 정체적인 특징을 보였다. 2019년 12월~2020년 3월에 한국 중부 서쪽의 석모리와 파도리에서 중국 배출량 감소의 영향에 따라 PM10, NO2, O3 농도 변동이 나타났다. 파도리에서 PM10, O3 월평균 농도와 최근 4년의 월평균 농도의 비는 2019년 12월과 비교하여 중국의 COVID-19 폐쇄 이후인 2020년 1~3월에 각각 0.7~4.7%, 9.2~22.8%로 감소하였다. 2020년 1월 중국의 춘절 기간에는 석모리와 파도리에서 PM10, NO2, O3 농도가 최근 4년의 춘절 기간과 마찬가지로 감소하였다. 그러나 2020년 1월 평균 농도가 최근 4년 1월과 비교하여 감소한 것은 중국 춘절 전후의 기간에도 배출량이 감소하였던 것과 관련 있다. 2020년 1~3월 석모리의 PM10, NO2, O3 농도의 비 ( /M)는 각각 70.8~89.7%, 70.5~87.1%, 72.5~97.1%이었고, 파도리에서도 각각 79.6~93.5%, 67.7~84.9%, 83.7~94.6% 로 추정 월평균(M)보다 월평균(Os)이 감소하였다. 2020년 1월에 몽골 북부로부터 중국 동부와 한반도에 이르는 지역의 온난화로 인한 광화학 반응으로 최근 4년과 비교하여 AOD가 높게 나타났으나 2020년 3월에는 풍상측인 중국에서 2차 에어로졸을 생성하는 전구물질 배출 감소로 최근 4년과 비교하여 낮은 AOD 분포를 보였던 것으로 분석되었다.

In2O3 doped WO3 powders were prepared by a polymer solution route and their NO2 gas sensing properties were analyzed. The synthesized powders showed nano-sized particles with specific surface areas of 6.01~21.5 m2/g and the particle size and shape changed according to the content of In2O3. The gas sensors fabricated with the synthesized powders were tested at operating temperatures of 400~500 oC and 100~500 ppm concentrations of NO2 atmosphere. The particle size and In2O3 content affected on the initial sensor resistance in an air atmosphere. The highest sensitivity (8.57 at 500 oC), which was 1.77 higher than the sensor consisting of the pure WO3 sample, was measured in the 0.5 mol% In2O3 doping sample. In addition, the response time and recovery time were improved by the addition of In2O3.

We measured VOCs and NO2 in the indoor and outdoor air at 125 houses in Jeollanam-do and Gyeongsangnamdo, from March 2007 to January 2008. The concentration of benzene measured in the Gwangyang survey group was higher than in Yeosu and Hadong, and showed a statistically significant difference from Yeosu (p<0.05). The concentration of toluene in outdoor air was highest in the Gwangyang survey group. The concentration of NO2 measured in the Yeosu survey group was higher than in Gwangyang and Hadong, and showed a statistically significant difference from Hadong (p<0.01). According to the results of a correlation analysis, VOCs (benzene, toluene, xylene, ethylbenzene) exposure of individuals showed a significant correlation with the residential indoor air (p<0.01). Also, VOCs of residential indoor and outdoor air showed a significant correlation (p<0.01). The concentration of NO2 exposure of individuals measured in the Yeosu comparison group showed a high correlation with the residential indoor air.

The concentration of VOCs, NO2 was measured both inside and outside residential homes surrounding an industrial complex. Measurements were performed in the area of the industrial complexes and around 10 km away from the industrial complex area. Benzene did not exceed the air quality standard value. Toluene exhibited a high value of concentration in outdoor Yeosu investigated group. The concentration of NO2 is higher than outside concentrations of houses in both inside housing research group compared with the group of Gwangyang and Yeosu. Benzene and toluene showed high correlation (p<0.001) in the housing interior in Gwangyang, It showed a high correlation (p<0.01) in the housing interior in the comparison group. In Yeosu there was a high correlation (p<0.001) between the inside and outside of the housing in the survey group. In the control group there was only high correlation (p<0.05) in the inside of the housing.

The purpose of this study is to evaluate the performance of a tube and badge type NO2 passive air sampler. The principle of the method is a colorimetric reaction of NO2 with N-1-naphthylethylendiamine under acidic conditions. The sampling rates for the tube and badge type passive air samplers was determined 12.3 ± 4.4 mL/min and 27.3 ± 4.9 mL/min, respectively, as obtained from the slope of the linear correlation between the NO2 mass collected by the passive air sampler and the NO2 concentration with the NO2 analyzer. The tube and badge type passive air sampler were moderately correlated with a correlation coefficient of 0.9112. The measurement for the precision and accuracy of the passive air sampling was carried out with duplicate measurement of passive air samplers. The passive air sampler had good precision and accuracy for measuring NO2 in atmosphere. A good correlation was observed between the passive air sampler and the NO2 analyzer with a coefficient of determination of 0.9153 (tube type) and 0.9514 (badge type). This passive air sampler would be suitable for the NO2 concentration monitoring in atmosphere.

The triboelectric property of a material is important to improve an efficiency of triboelectric generator(TEG) in energy harvesting from an ambient energy. In this study, we have studied the TEG property of a semicon-ducting SnO2 which has yet to be explored so far. As a counter triboelectric material, PET and glass are used. Verticalcontact mode is utilized to evaluate the TEG efficiency. SnO2 thin film is deposited by atomic layer deposition on bareSi wafer for various thicknesses from 5.2 nm to 34.6 nm, where the TEG output is increased from 13.9V to 73.5V. Tri-boelectric series are determined by comparing the polarity of output voltage of 2 samples among SnO2, PET, and glass.In conclusion, SnO2, as an intrinsic n-type material, has the most strong tendency to be positive side to lose the electronand PET has the most strong tendency to be negative side to get the electron, and glass to be between them. Therefore,the SnO2-PET combination shows the highest TEG efficiency.

The objectives of this study were to characterize the factors affecting exposure to the VOCs and NO2 in the vicinity of Gwangyang industrial complex. The VOCs and NO2 levels were measured for residents of an exposure group (industrial area within 5 km) and a control group (15 km farther), respectively using the VOCs and NO2 filter badge as a passive sampler from August to September 2006. The means of indoor, outdoor, workplace and personal exposure levels of benzene were 1.10 ppb, 0.94 ppb, 1.85 ppb and 2.35 ppb respectively in the exposure group. The means regarding toluene for the exposure group were 9.29 ppb indoor, 8.09 ppb outdoor, 14.5 ppb workplace, 14.2 ppb personal exposure. The means regarding ethylbenzene were 4.96 ppb(indoor), 4.45 ppb(outdoor), 6.84 ppb (workplace), 6.10 ppb(personal exposure), and the means regarding xylene were 0.10 ppb(indoor, outdoor), 0.18 ppb(workplace) 0.17 ppb(personal exposure). The means for the indoor, outdoor, workplace and personal exposure level of NO2 were 18.40 ppb, 18.51 ppb, 18.59 ppb, 18.80 ppb respectively in the exposure group. Correlations between personal exposures and workplace concentrations of individual VOCs and NO2 exposures, and each of the microenvironment was statistically significant.

We report a highly sensitive NO2 gas sensor based on multi-layer graphene (MLG) films synthesized by a chemical vapor deposition method on a microheater-embedded flexible substrate. The MLG could detect low-concentration NO2 even at sub-ppm (<200 ppb) levels. It also exhibited a high resistance change of ~6% when it was exposed to 1 ppm NO2 gas at room temperature for 1 min. The exceptionally high sensitivity could be attributed to the large number of NO2 molecule adsorption sites on the MLG due to its a large surface area and various defect-sites, and to the high mobility of carriers transferred between the MLG films and the adsorbed gas molecules. Although desorption of the NO2 molecules was slow, it could be enhanced by an additional annealing process using an embedded Au microheater. The outstanding mechanical flexibility of the graphene film ensures the stable sensing response of the device under extreme bending stress. Our large-scale and easily reproducible MLG films can provide a proof-of-concept for future flexible NO2 gas sensor devices.

The purpose of this study was to assess an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Using a mass balance model and regression analysis, penetration factor and source strength factor were calculated using multiple indoor and outdoor measurements. This study was performed in 30 selected apartments in Seoul, Asan, and Daegu area which were constructed within 4 years and over 4 years, to measure the concentration of NO₂ from July, 2004 to September. The results of this study are as follows. The average concentration of NO₂ in Seoul, Asan, and Daegu area in the apartment constructed within 4 years are nitrogen dioxide 48.01㎍/m³ and in the apartment over 4 years are nitrogen dioxide 46.54㎍/m³. Mean ratios of indoor to outdoor NO₂ concentrations are Seoul 0.99, Asan 0.83, Daegu 1.18. The deposition constant and the source strength of NO₂ were 0.97±0.55 hr-1 and 16.33±12.30 ppb/h, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

Recently, one-dimensional semiconducting nanomaterials have attracted considerable interest for their potential as building blocks for fabricating various nanodevices. Among these semiconducting nanomaterials,, SnO2 nanostructures including nanowires, nanorods, nanobelts, and nanotubes were successfully synthesized and their electrochemical properties were evaluated. Although SnO2 nanowires and nanobelts exhibit fascinating gas sensing characteristics, there are still significant difficulties in using them for device applications. The crucial problem is the alignment of the nanowires. Each nanowire should be attached on each die using arduous e-beam or photolithography, which is quite an undesirable process in terms of mass production in the current semiconductor industry. In this study, a simple process for making sensitive SnO2 nanowire-based gas sensors by using a standard semiconducting fabrication process was studied. The nanowires were aligned in-situ during nanowire synthesis by thermal CVD process and a nanowire network structure between the electrodes was obtained. The SnO2 nanowire network was floated upon the Si substrate by separating an Au catalyst between the electrodes. As the electric current is transported along the networks of the nanowires, not along the surface layer on the substrate, the gas sensitivities could be maximized in this networked and floated structure. By varying the nanowire density and the distance between the electrodes, several types of nanowire network were fabricated. The NO2 gas sensitivity was 30~200 when the NO2 concentration was 5~20ppm. The response time was ca. 30~110 sec.

Indoor air quality tends to be the dominant contributor to personal exposure, because most people spend over 80% of their time indoors. In this study, indoor and outdoor NO2 concentrations were measured simultaneously with personal exposures of 30 university students in weekday and weekend in Daegu, Korea. House characteristics and subject's activity pattern were used to determine the effects on personal exposure. Since university students spent most of their times indoor, their NO2 exposure was associated with indoor NO2 level during both weekday and weekend in spite of different time activity. Using a time-weighted average model, NO2 exposures of university students were estimated by NO2 measurements in indoor home, indoor school, and outdoor home. In conclusion, major personal exposure to NO2 resulted from air quality of indoor environment at house.

It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO2 and also chemically and thermally stable, Therefore, lots of MPcs have been studied for the potential chemical sensor for NO2 gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, ultra-thin films of octa(2-ethylhexyloxy)copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS absortion spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO2 gas as a function of film thickness and temperature were discussed.

Ultra thin films of Tetra-3-hexadecylsulphamoylcopperphthalocyanine(HDSM-CuPc) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT-IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of Ultrathin Langmuir-Blodgett(LB) films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscopies. A quartz piezoelectric crystal coated with LB films of HDSM-CuPc was examined as a gas sensor for N02 gas. HDSM-CuPc LB films were transferred to a quartz crystal microbalance(QCM) in the form of Z-type multilayers. Response characteristics of film-coated QCM to NO2 gas concentrations over a range of 100~600ppm have been tested with a thickness of 5~20 layers of HDSM-CuPc. Changes in frequency by adsorption of NO2 were increased With the number of LB layers and NO2 concentration, but the response time was slow.

Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.

This research investigated the characteristics of CO, CO2, and NO2 concentrations at main subway stations in Busan. The annual mean CO concentrations at the Suyeong and Nampo stations were 0.75 ppm and 0.48 ppm, respectively. Annual CO2 concentration at the Seomyeon 1- platform was 649 ppm. The NO2 concentrations at the Seomyeon 2- waiting room and the Yeonsan station were 0.048 ppm and 0.037 ppm, respectively. CO concentration was highest at two times of the day, and was proportional to the number of passengers commuting to and from work. The CO and CO2 concentrations were highest in winter, but NO2 concentration was highest in spring. CO and CO2 concentrations were highest on Saturday and lowest on Sunday. The correlation of CO and NO2 concentrations measured at the subway stations with those at the ambient air quality station were highest at the Seomyeon 1 and 2- waiting room and Jeonpodong. The correlation was lowest at the Yeonsan and Yeonsandong station. The number of days when CO2 concentration exceeded 700 ppm over the last three years at the Seomyeon 1- platform was 174. The findings of this research are expected to deepen understanding of the fine particle characteristics at subway stations in Busan and be useful for developing a strategy for controlling urban indoor air quality.

This research investigated the characteristics of NO and NO2 concentration at roadside (Choryangdong) and residential (Sujeongdong) locations in Busan. The NO concentration at roadside and residential were 34.7 and 8.0 ppb, respectively, and NO2 at roadside and residential were 31.6 and 18.0 ppb ㎍/㎥ , respectively. The NO concentration was the highest in winter at roadside at 37.1 ppb, followed by 35.0 ppb and 34.0 ppb in summer and fall, respectively. NO2 concentration was the highest in spring at roadside at 39.6 ppb, followed by 30.4 ppb and 28.3 ppb in fall and winter, respectively. Number of exceedances per year of 1 hr limit value (0.10 ppm) for NO2 at roadside and residential were 3,585 and 3 hours, respectively. Number of exceedances per year of 24 hr limit value (0.06 ppm) for NO2 at roadside and residential were 32 and 1 days, respectively. Number of exceedances per year of 1 hr limit value (0.1 ppm) for O3 at roadside and residential were 1 and 14 days, respectively. These results indicated that understanding the relationship between roadside and residential could provide insight into establishing a strategy to control urban air quality.

Long-term passive diffusive samplers(PDS) have been used to measure NO2 and SO2 concentrations at 21 sampling sites in Daejeon, Korea during the period of January 2000 - December 2002. The spatial distributions of annual NO2 and SO2 concentrations were mapped. Average annual NO2 concentration over the sampling period was 28.5±12.5 ppb, ranging from 1.2 to 81.7 ppb. Average annual SO2 concentration over the sampling period was 7.7±4.8 ppb, ranging from 0.6 to 26.8 ppb. On average, NO2 concentration was approximately 5.8%(1.6 ppb) larger in 2002. SO2 concentration was decreased by 13%(1.1 ppb) during the sampling period. The seasonal variation of NO2 and SO2 concentration was observed with a tendency to be higher in fall and winter. NO2 and SO2 concentrations measured at different site types(patterns of land use) show significant difference. The observed difference in concentration was associated with difference in emissions of NO2 from motor vehicles and SO2 by non-traffic fuel consumption for heating.