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Corrosion Behavior of 10-year-old Copper Specimens in a 30°C Aerobic KURT Environment

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한국방사성폐기물학회 학술논문요약집 (Abstracts of Proceedings of the Korean Radioactive Wasts Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

Corrosion cells that simulates engineering barrier system have been stored in an aerobic KURT environment for 10 years, which were recovered and dismantled in 2021. The test specimens were compressed copper (Com. Cu), Cold spray copper (CSC Cu), Ti Gr.2, STS 304, and Cast nodular iron. The specimens were buffered by compact Ca-type Gyeongju bentonite (KJ-I) and compact Na-type Wyoming bentonite. And the corrosion cells were exposed to KURT groundwater at 30°C for about 10 years (3,675 days). As a result of the long-term experiment in aerobic environment, it was confirmed that Na-bentonite is more advantageous for inhibiting corrosion than Ca-bentonite. The corrosion thickness of the most specimens in Ca bentonite was slightly lower than in Na bentonite until the initial 500 days, but after 10 years, the corrosion thickness of copper and cast iron specimens in Na bentonite was clearly lower. The corrosion thickness of the copper specimen in Na bentonite was very low about 0.5 um in both Com. Cu and CSC Cu. Moreover, the corrosion thickness in Ca bentonite was very high about 4 um for Com. Cu and 6 um for CSC Cu. In the case of cast iron, the corrosion thickness in Na bentonite was about 13 um, and 15 um in Ca bentonite. The common feature of copper and cast iron specimens in Ca bentonite, which showed a high corrosion thickness, is the forming of a white mineral deposition layer on the specimen surface, which was presumed to be some kind of feldspar. On the other hand, it was found that the STS304 and Ti specimens were hardly corroded even after 10 years. In conclusion, when a white mineral deposition layer was formed on the specimen surface, the corrosion thickness always increased sharply than before, and thus it was estimated that the generation of the mineral deposition layer cause the increase of bentonite permeability, and rather the weakening of existing passive corrosion film.

저자
  • Minsoo Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon) Corresponding author
  • Junhyuk Jang(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Gha-Young Kim(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Mihye Kong(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Jin-Seop Kim(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)