Radioactive nickel (Ni59 and Ni63) is a major radionuclide that needs to be determined for quantifying the total radioactivity in radioactive waste disposal repository. Also, radioactive waste containing organic wastes, such as cotton and tissue can be decomposed to produce the Isosaccharinic acid (ISA) in a disposal facility. The presence of ISA in the disposal facility could increase the mobility of radionuclides. Therefore, it is necessary to confirm the mobility of Ni with the presence of ISA in the repository. This study investigated the effect of ISA on the sorption and the solubility of Ni in synthesized groundwater. The sorption test was conducted in different time intervals with Ni and ISA. Nickel nitrate hexahydrate and Ca(ISA)2 were used after purchase. Granite was used as the solid medium to simulate the major rock type of the repository. Ni and ISA solution with the medium were mixed using a platform shaker for 6 days. After 6 days, the solid parts were separated by centrifugation and additional syringe filters, and the supernatant was analyzed for Ni and ISA concentration using ICP-MS and IC, respectively. The solubility experiments were conducted at different temperatures (20, 40, and 80°C). Nickel hydroxide was used as the solubility limiting solid phase. To balance the ionic strength and confirm the effect of ISA on Ni solubility, 0.01 M of CaCl2 solution was prepared in a sample without ISA, and 0.01 M of Ca(ISA)2 solution was prepared in a sample with ISA. In solubility tests, the solution was also analyzed by ICP-MS and IC for Ni and ISA, respectively. The concentration of Ni was found to increase with ISA compared to Ni concentration without ISA. The concentration of ISA was not changed during the solubility test periods. For solubility tests, the concentration of Ni also increased according to the increase in temperature. The solid phase was characterized by XRD, FT-IR, and SEM-EDS. Based on the results of this study, the presence and effect of ISA on radioactive Ni mobility should be carefully investigated to secure the long-term safety assessment for the low and intermediate-level waste repository.

Organic waste generated by small and medium-sized (S&M-sized) metal decontamination in NPP decommissioning. To lower the concentration of these organic substances for a level acceptable at the disposal site, the project of “Development of Treatment Process of Organic Decontamination Liquid Wastes from Decommissioning of Nuclear Power Plants” is being carried out. The conditioning and treatment process of organic liquid waste was designed. Also, the literature was investigated to make simulated organic liquid waste, and the composition of these waste was analyzed and compared. As the decontamination agent, organic acids such as EDTA, oxalic acid, citric acid are used. The sum of the concentrations of these organic materials was set to a maximum value of 1,000 ppm. The major metal ions of the decontamination liquid waste estimated are 59Fe, 51Cr, 54Mn, 63Ni, and the concentrations are respectively 527, 163, 161, 159 ppm. Additional major metal ions are 60Co, 58Co, 137Cs. 58Co is replaced by 60Co because it has the same chemical properties as 60Co. Unlike the HLW, the contamination level of S&M-sized metal in primary system was quite low, so 60Co is set to 2,000 Bq/g. Considering the contribution of fission and gamma ray dose constant, 137Cs was estimated to 360 Bq/g. Also, suspended solids of decontamination liquid waste were set at 500 ppm. Under these assumptions, the simulated organic liquid waste was made, and then organic substances and metal ions were analyzed with TOC analyzer and ICP-OES. The TOC analysis value was expected to 392 ppm in consideration of the equivalent organic quantity. the test result was 302 ppm. Some of organics appears to have been decomposed by acid. The values of metal ions (Fe3+, Cr3+, Mn2+, Ni2+) analyzed by ICP-OES are 139, 4, 152, 158 ppm, respectively. A large amount of Cr3+ and Fe3+ were expected to exist as ions, but they existed in the form of suspended solid. Mn2+ and Ni2+ came out similar to the expected values. The designed conditioning and treatment process is largely divided into pretreatment, conditioning, and decomposition processes. After collecting in the primary liquid waste storage tank, large particulate impurities and suspensions are removed through a pretreatment process. In the conditioning process, treated liquid waste passes through UF/RO membrane system, and pure water is discharged to the environment after monitoring. Concentrated water is decomposed in the electrochemical catalyst decomposition process, then this water secondarily passes through the RO membrane system and then discharged to the environment after monitoring. Through an additional experiment, the conditioning and treatment process will be verified.

Encapsulation using cement as a solidification method for disposal of radioactive waste is most commonly used in most advanced countries in the nuclear technology to date due to its advantages such as low material cost and accumulated technology. However, in case of cement solidification, since moisture or hydroxyl group in cement is decomposed by radioactivity, it may happen that gas is generated, structural stability is weakened, and leachability is increased due to low chemical durability. Therefore, the various new solidification methods are being developed to replace it. As one of these alternative technologies, for dispersible metal compounds generated through the incineration replacement process, the study on engineering element technology for powder metallurgy is under way, which overcomes the interference problem between mechanical elements and media that may occur during the process such as the homogeneous mixing process of the target powder substance and additives used in the powder metallurgy concept-based sintering process for the solidification of the final glass composite material (GCM), the process of creating a compressed molded body using a specific mold, the process of final sintering treatment. The solidification process of dispersible radioactive waste can be largely divided into pre-treatment stage, molding stage, and sintering stage, and the characteristics of the final radioactive waste solidification material can vary depending on the solidification treatment characteristics of each stage. In relation with these characteristics, the matters to be considered when designing device for each stage to solidify dispersible radioactive waste (property of super-mixing device for homogenized powder formation, structural geometry and pressure condition of molding device for production of compressed molded body, temperature and operation characteristics of sintering device for final glass composite material (GCM), etc.) are drawn out. It is expected that the solidification device design reflecting these considerations will meet all disposal conditions of radioactive waste material, such as compressive strength and leaching characteristics of solidified radioactive waste material, and create a uniformized solidification of radioactive waste material.

High Integrity Container (HIC) made of polymer concrete was developed for the efficient treatment and safe disposal of radioactive spent resin and concentrate waste in consideration of the disposal requirements of domestic disposal sites. Permission for application of Polymer Concrete High Integrity Container (PC-HIC) to the domestic nuclear power plants (NPPs) has been completed or is under examination by the regulatory agency. In the case of 860 L PC-HIC for very-low-level-waste (VLLW) or low low-level-waste (LLW), the application of four representative NPPs has been approved, and the license for extended application to the rest NPPs is also almost completed. A licensing review is also underway to apply 510 L PC-HIC for intermediate and low-level-waste (ILLW) to representative nuclear power plants. In order to handle and efficiently store and manage PC-HICs and high-dose PCHIC packages, a gripper device that can be remotely operated and has excellent safety is essential, and the introduction of NPPs is urgent. The conventional gripper device developed by the PC-HIC manufacturer for lifting test to evaluate the structural integrity of PC-HIC requires a rather wide storage interval due to its design features, and does not have a passive safety design to handle heavy materials safely. In addition, work convenience needs to be reinforced for safety management of high radiation work. Therefore, we developed a conceptual design for a gripper device with a new concept to minimize the work space by reflecting on-site opinions on the handling and storage management conditions of radioactive waste in NPPs, and to enhances work safety with the passive safety design by the weight of the package and the function of checking the normal seating of the device and the normal operation of the grip by the detector/indicator, and to greatly improves the work efficiency and convenience with the wireless power supply function by rechargeable battery and the remote control function by camera and wireless monitoring & control system. Through design review by experts in mechanical system, power supply and instrumentation & control fields and further investigations on the usage conditions of PC-HICs, it is planned to facilitate preparations for the application of PC-HIC to domestic NPPs by securing the technical basis for a gripper device that can be used safely and efficiently and seeking ways to introduce it in a timely manner.

According to the ‘Regulations on the Delivery of Low and Medium Level Radioactive Waste’, Notification No. 2021-26 of the Nuclear Safety and Security Commission, a history of radioactive waste and a total amount of radioactivity in a drum are mandatory. At this time, the inventory of radionuclides that make up more than 95% of the total radioactivity contained in the waste drum should be identified, including the radioactivity of H-3, C-14, Fe-55, Co-58, Co-60, Ni-59, Ni-63, Sr- 90, Nb-94, Tc-99, I-129, Cs-137, Ce-144, and total alpha. Among nuclides to be identified, gamma-emitting nuclides are usually analyzed with a gamma ray spectrometer such as HPGe. When a specific gamma-ray is measured with a detector, several types of peaks generated by recombination or scattering of electrons are simultaneously detected in addition to the corresponding gamma-ray in gamma-ray spectroscopy. Among them, the full energy peak efficiency (FEPE) with the total gamma energy is used for equipment calibration. However, this total energy peak efficiency may not be accurately measured due to the coincidence summing effect. There are two types of coincidence summing: Random and True. The random coincidence summing occurs when two or more gamma particles emitted from multiple nuclides are simultaneously absorbed within the dead time of the detector, and this effect becomes stronger as the counting rate increases. The true coincidence summing is caused by simultaneous absorption of gamma particles emitted by two or more consecutive energy levels transitioning from single nuclide within the dead time of the detector. This effect is independent of the counting rate but affected by the geometry and absolute efficiency of the detector. The FEPE decreases and the peak count of region where the energy of gamma particles is combined increases when the coincidence summing occurs. At the Radioactive Waste Chemical Analysis Center, KAERI, samples with a dead time of 5% or more are diluted and re-measured in order to reduce the random coincidence summing when evaluating the gamma nuclide inventory of radioactive waste. In addition, a certain distance is placed between the sample and the detector during measurement to reduce the true coincidence summing. In this study, we evaluate the coincidence summing effect in our apparatus for the measurement of radioactive waste samples.

Polycarboxylic ether-based high-range water reducer (PCE) has been proposed to use due to the operational advantages of reduced water content and increased fluidity of cementitious mixtures. But the concern about using PCE can increase the mobility of radionuclides as well. Nuclear Decommissioning Authority (NDA) showed that the PCE formulations increased radionuclide solubility in free solution. Solubility of U(VI), 239Pu, 241Am with the cementitious materials tested with 3:1 pulverized fuel Ash/Ordinary Portland Cement (PFA:OPC) and 9:1 Ground Granulated Blast Furnace Slag/OPC (GGBS:OPC) with PCE that increased at least one and, in some cases, more than three orders of magnitude (between 10-9 and 10-4 mol dm-3) for these radionuclides in the cement-equilibrated solution. It is possible that the relatively low molecular weight substances present in the PCE cement mixture increase the solubility of radionuclides. In addition, the organic substances that are easily miscible with water can contribute to increase the solubility. In this study, several radionuclides (Nb, Ni, Pd, Zr, and Sn) that may be present in intermediate and low-level waste (LIW) repositories were selected based on the half-life and the estimated dose accordingly, and the solubility tests were conducted with and without PCE in solution. To simulate the field condition of the underground repository, synthetic groundwater was prepared based on the recipe by the KAERI Underground Research Tunnel (KURT) DB-3 GW and used as a solvent. The solubility limiting solid phase (SLSP) of each radionuclide was determined using Geochemist’s WorkBench (GWB) model. The selected solid phases are Ni(OH)2, ZrSiO4, Nb2O5, Pd(metal), and SnO2, respectively, and the solubility experiments were conducted with 1.0wt% of PCE per total weight and 0.5 g / 250 ml of selected radionuclide’s SLSP for 90 days at room temperature (25°C). Compared with and without PCE presence in solution, the selected radionuclides also showed an increased solubility with the presence of water reducing agent like PCE. This results can be used to correctly estimate the mobility of target radionuclides with the presence of PCE in repository environments.

Concrete is used as the main engineering barrier in low and intermediate level radioactive waste disposal facilities. As the time passed, the radionuclides stored in repository may contact with groundwater and leak into the ecosystem through the rock media. In this process, the radionuclides can react with calcite via sorption or coprecipitation, because calcite is the major mineral of concrete. Under the various background conditions in repository, frequent dissolution-precipitation reactions can happen. Dissolution of Sr-coprecipitated calcite may be different from that of SrCO3(s) which can mislead the safety performance of radioactive Sr and the estimate of Sr mobility based on the solubility of SrCO3(s). Strontium is not only one of the fission products but also emits beta rays with a long half-life almost 29 years. The strontium may be released or retarded by the dissolution-precipitation reactions in repository. In this study, the dissolution of Sr-coprecipitated with respect to calcite was tested in various environment conditions. The Sr-coprecipitated calcite, (Sr,Ca)CO3(s) was synthesized by coprecipitation method in alkaline condition. The 250 mL of 0.1 M of CaCl2 solution was mixed with 250 mL of 1.14 mM SrCl2·6H2O solution. Then, independently prepared 500 mL of 0.1 M Na2CO3 solution was mixed with the mixed solution of CaCl2 and SrCl2. The precipitates could be made and they were aged for 3 days at room temperature. Then, the supernatant was separated by the centrifugation and the solid at the bottom was dried in an oven at temperature 80°C. After that, the Srcoprecipitated calcite powder was washed using the DI water several times and dried again before use. Characterization of solid powder was conducted by XRD and SEM, and the ICP-MS and ICP-AES were used to analyze the concentrations of Ca and Sr. The batch dissolution experiment was conducted with a solid-to-solution ratio of 10 g/L groundwater in polyethylene tubes. The oxidative groundwater was synthesized by simulating the chemical composition of KAERI Underground Research Tunnel (KURT) DB-3 groundwater. Different temperatures and pHs were prepared and tested for the release of Sr and Ca from the coprecipitated (Sr,Ca)CO3(s) to compare the results with the release of Sr and Ca from SrCO3(s) and CaCO3(s), respectively. Such as, these results will be used to provide better understanding of Sr release and mobility in various repository environments.

Organic complexing agents may affect the mobility of radionuclides at low- and intermediate-level radioactive waste repositories. Especially, isosaccharinic acid (ISA) is the main cellulose degradation product under high pH conditions in cement pore water. ISA can combine with radionuclides and form stable complexes that adversely influence adsorption in the concrete phase, resulting in radionuclides to leach to the near- and far-fields of repositories. This study focuses on investigating the sorption of ISA onto engineered barriers such as concrete, thereby studying adsorption isotherms of ISA on concrete and comparing various isotherm models with the experimental data. The adsorption experiment was conducted in three background solutions, groundwater (adjusted to pH 13 using NaOH), State 1 (artificial cement pore water, pH 13.3), and State 2 (artificial cement pore water, pH 12.5), in a batch system at a temperature of 20°C. Concrete was characterized using BET, Zeta-potential analyzer, XRD, XRF, and SEM-EDS. ISA concentrations were detected using HPLC. The experimental data were best fitted to one-site Langmuir isotherm; On the other hand, either two-site isotherm or Freundlich isotherm couldn’t give reasonable fitting to the experimental data. The observed ISA sorption behavior on concrete is crucial for the disposal of radioactive waste because it can significantly lower the concentration of ISA in the pore water. Although one-site Langmuir isotherm might effectively represent the sorption behavior of ISA on concrete, the underlying mechanism is still unknown, and further investigation should be done in the near future.

Waste containers for packaging, transportation and disposal of NPP (Nuclear Power Plant) decommissioning wastes are being developed. In this study, drop tests were conducted to prove the safety of containers for packaging of the wastes and to verify the reliability of the analysis results by comparing the test and analysis results. The drop height of the waste containers was considered to be 30 mm, which is the maximum lifting speed of a 50 tons crane in the waste treatment facility converted to the drop height. Drop orientation of the containers was considered for bottom-end on drop. The impact acceleration and strain data were obtained to verify the reliability of the analysis results. Before and after the drop tests, measurement of the dose rate and the radiographic testing for concrete wall, and measurement of the wall thickness of steel plate were conducted to evaluate the radiation shielding integrity. Also, measurement of bolt torque, and visual inspection were conducted to evaluate the loss or dispersion of radioactive contents. After the drop tests, the radiation dose rate on the container surface did not increase by more than 20%, and there was no crack in the concrete. In addition, the thickness of the steel plate did not change within the measurement error. Therefore, the radiation shielding integrity of the container was maintained. After the drop tests, the lid bolts were not damaged and there was no loss of pretension in the lid bolts. In addition, there was no loss or dispersion of the contents as a result of visual inspection. In order to prove the reliability of the drop analysis results, safety verifications were performed using the drop test results, and the appropriate conservatism for the analysis results and the validity of the analysis model were confirmed. Therefore, the structural integrity of the waste containers was maintained under the drop test conditions.

There are various types of level gauging method such as using float, differential pressure, hypersonic, displacement and so on. In this study, among them, the method utilizing the differential pressure was reviewed. The strengths include: the differential pressure type level gauge can measure the level without direct contact of the sensor with media. That is to say, the level can be measured even if the sensor is far away from the tank. And regardless of the size of the tank, the level can be measured if the pneumatic pipes are installed. The weaknesses include: the sensor needs intermedium to recognize the level. The intermedium utilizes a fluid, which is compressed air. It is difficult to handle that compressed air has the properties of a gas. And to make compressed air needs compressor, tank and pneumatic pipes. So if you have many tanks, you need to install exponentially the pneumatic pipes. As well, level measurement range is limited to the points where the pneumatic pipes of the tank is installed. And if a compressed air that supplies to the sensor leaks, uncertainty will increase. A compressed air is colorless and odorless, so it’s difficult to pinpoint the leak. Finally, events like cracks and clogging can cause inaccurate measurement. Rather than using only differential pressure, it is better to use another measurement method according to the situation of the facility.

In KAERI, Waste storage facility in the radiation management area has stored a large amount of wood waste. The amount of waste is approximately 27,000 kg, it accounts for 17% of the total waste in waste storage facility. Proper disposal of wood waste improves the fire resistance performance, secure storage space and reduce disposal costs. In order to self-disposal of wood waste, it is necessary to satisfy the self-disposal standards stipulated by the domestic Atomic Energy Act and the treatment standards of the Waste Management Act. The main factors of standards are surface contaminant, radionuclide activity and radiation dose effects. To confirm the contamination of wood waste, direct indirect measurement methods and gamma nuclide analysis were performed. To evaluate radiation dose, various computational programs were used. The results of the analysis were satisfied with domestic regulations on the classification and self-disposal of radioactive wastes. Based on this results, KAERI submitted the report on wood waste self-disposal plan to obtain approval. After final approval, wood waste is to be incinerated and incineration ash is to be buried in the designated place. The objective of this study is to provide total procedure of wood waste self-disposal and effective representative sampling method.

In general, dose assessment must be performed to obtain approval for clearance of radioactive waste. If the annual dose criteria through dose evaluation satisfies the clearance condition, radioactive waste can be disposed of. Various programs are used to perform dose assessment. NRCDOSE GASPAR is used as a program to assess the amount of radiation exposed to atmospheric emissions. Program is easy to use and results can be checked immediately after execution. GASPAR requires main input factors by exposure route such as site specifics, source term, special location, block data. Basically, program has default input values but user can easily modify it. The most important factor is that when entering a nuclide, the effect on progeny radionuclides is not automatically calculated. User should consider the dose contribution from progeny radionuclides. In this study, dose assessment was performed for combustible waste incineration using NRCDOSE GASPAR. And it was confirmed that exposure dose of individuals and groups criteria for clearance regulation.

A large amount of concrete radioactive waste is generated during the decommissioning of nuclear facilities, including nuclear power plants, and it is expected that the radioactive waste management expenses will be huge. In order to reduce the concrete radioactive waste, a decontamination or removal process is required, but working on concrete may present a risk of worker exposure in a high-radioactive space. Therefore, in this study, a remote control integrated decontamination equipment that can reduce concrete radioactive waste and ensure the safety of workers during the concrete decontamination process in a high-radioactive space was developed. The integrated decontamination equipment consists of remote movement, automatic surface contamination measurement, automatic surface decontamination and debris/dust removal systems. The remote movement system generates ‘mapping data’ of topographic features for the work space and ‘location data’ that coordinates the location of the integrated decontamination equipment through LiDAR (Light Detection and Ranging) sensor and SLAM (Simultaneous Localization And Mapping) technique. The user can check the location of the integrated decontamination equipment through ‘location data’ outside the work space, and can move it by remote control through wired/wireless communication. The automatic surface contamination measurement system uses a radiation detector and an automatic measurement algorithm to generate ‘surface measurement data’ based on the measurement distance interval and measurement time set by the user. ‘Surface measurement data’ is combined with ‘location data’ to create a visualized map of radioactive contamination, and users can intuitively realize the location and degree of contamination based on the map. The automatic surface decontamination system uses a laser and an automatic removal algorithm to decontaminate the concrete surface. Concrete debris and dust generated during this process were collected by the debris/dust removal system, minimizing waste generation and radiation exposure due to secondary pollution. The integrated decontamination equipment developed through this study was applied with technologies that reduced radioactive concrete waste and ensured the safety of workers. If technology verification and on-site applicability review are performed using concrete specimens simulating nuclear power plant or similar environments, it is reasoned to contribute to the domestic and overseas decommissioning industry.

The dismantlement of the Kori Unit 1 and Wolsong Unit 1 nuclear power plants is scheduled. Since about 40% of the cost of dismantling nuclear power plants is the cost of disposing of generated wastes, it is important to secure recycling technologies. Among them, low and intermediate level radioactive wastes are made of porous filters and adsorbent materials of ceramic foam to remove nuclides such as C-14, I, and Xe generated during nuclear dismantling. In order to remove a large amount of nuclides, physical properties such as a specific surface area and porosity of a ceramic foam filter are important, however when a heat treatment temperature is increased to increase the strength of the filter, the nuclides removal ability is reduced. In order to remove a large amount of nuclides, physical properties such as a specific surface area and porosity of a ceramic foam filter are important, however when a heat treatment temperature is increased to increase the strength of the filter, the nuclides removal ability is reduced. Therefore, in this study, the foam filter performance was improved by applying a sacrificial material to increase the specific surface area and porosity of the ceramic foam filter. The sacrificial material is burned out with polyurethane (PU) of the green filter before the heat treatment temperature to increase the strength of the ceramic foam filter so that it can be maintained as pores, thereby improving the specific surface area and porosity. The sacrificial materials and melting temperature (Tm) reviewed in this study were anthracite (530~660°C), PMMA (160°C), Cellulose acetate (260~270°C), and aluminum particle (660°C), and their effect on the manufacture of foam filters was studied by applying this. The specific surface part and porosity of the foam filter were improved when anthracite and aluminum particle were added, and PMMA and Cellulose acetate, which are relatively low temperature melting points, were burned out at a temperature lower than PU, and thus their physical properties were not greatly affected. The physical properties and specific surface part and porosity of ceramic foam filters manufactured using various sacrificial materials will be discussed.

Radioactive spent resin and concentrate waste powder generated from the primary system of nuclear power plants (NPPs) should be treated and disposed of in the form of solidified products or high integrity container (HIC) packages. We are preparing for the application of polymer concrete high integrity containers (PC-HICs) that has been approved for disposal and field application after going through the disposal suitability review of the repository operator and the license review process of the regulatory body. A reliable assessment of nuclide inventory in waste drum is required for the disposal of the radioactive waste drums, and the representative samples should be collected for both the indirect (non-destructive assessment based on the scaling factor, average radioactivity concentration, etc.) and direct (destructive analysis) evaluation of the difficult-to-measure (DTM) nuclides. It is important to secure the representativeness of samples for reliable and accurate evaluation of radionuclide inventory and approval of methodologies for highly radioactive waste such as spent resin and concentrate waste poser, and in order to secure the radiation safety of the sampling workers and representativeness of the samples, a remote sampling method is required with excellent convenience and safety and sufficient representativeness of the sample. The simple sampling device used in the past to collect samples for the scaling factor does not have a remote control function, so high-radiation samples must be collected within a very short time and it is difficult to obtain sufficiently representative samples due to structural characteristics that cannot collect the entire sample in the axial direction of the package. Therefore we developed concept designs for a remote sampling device that can satisfy both sample representativeness, operator convenience and safety.

Lubricant oil waste contaminated with radioactive materials generated at nuclear facilities can be disposed of as industrial waste in accordance with self-disposal standards if only radioactive materials are removed. Lubricant oil used in nuclear facilities consists of oil of 75-85% and additives of 15-25%, and lubricant oil waste contains heavy metals, carbon, glycol, etc. In addition, lubricant oil waste from nuclear facilities contains metallic gamma-ray emission radionuclides including Co-60, Cs-137 and volatile beta-ray emission radionuclides such as C-14 and H-3, which are not present in lubricant oil waste from general industries and these radionuclides must be eliminated according to the Atomic Energy Act. In general industries, the wet treatment technologies such as acid-white soil treatment, ion purification, thin film distillation, high temperature pyrolysis, etc. are used as the refining technology of lubricant oil waste, but it is difficult to apply these technologies to nuclear industrial sites due to restrictions related with controlling the generation of secondary radioactive waste in sludge condition containing radionuclides of metal components, and limiting the concentration of volatile radioactive elements contained in refined oil to be below the legal threshold. In view of these characteristics, the refinement system capable of efficiently refining and treating lubricant oil waste contaminated with radioactive materials generated in nuclear facilities has been developed. The treatment process of this R&D system is as follows. First, the moisture in the radioactive lubricant oil waste pretreated through the preprocessing system is removed by the heated evaporating system, and the beta-emission radionuclides of H-3 and C-14 can be easily removed in this process. Second, the heated lubricant oil waste by the heated evaporating system is cooled through the heat exchanging system. Third, the particulate matters with gamma-ray emission radionuclides are removed through the electrostatic ionizing system. Forth, the lubricant oil waste is stored in the storage tank and the purified lubricant oil waste is discharged to the outside after sampling and checking from the upper, middle and lower positions of the lubricant oil waste stored in the storage tank. Using this R&D system, it is expected that the amount of radioactive waste can be reduced by efficiently refining and treating lubricant oil waste in the form of organic compounds contaminated with radioactive materials generated in nuclear facilities.

To efficiently manage the waste packages like drums, it is meaningful to utilize the data of placement and emplacement of disposed waste in geological storage. For the transparent and real-time management of disposal data, both technical as well as administrative factors must be included. To this end, MIRAE-EN Co., Ltd. has developed a radioactive waste tracking and management system (m-trekⓇ v1.0) through radioactive waste management life cycle which is supported by KETEP. Enhancing the functional features of m-trekⓇ, IoT-based drum location measuring and data of those drums, such as position, radionuclides, activity, and dose etc., are to be collected and monitored through data modeling and visualization, which might be utilized in emplacing the loaded drums according to specifically certain criteria of internal and external data of disposal site. Position measuring using Beacon utilizes Received Signal Strength Indicator (RSSI) to locate the correct position in 3D area. Since RSSI is affected by the surrounding environment, it is required to corrective optimization. In addition, error and deviation of previously applied Gaussian filter method, was corrected and improved through AI learning model. According to this location information and those data, the prototype in future provides the visualization of drum position and its relevant data for administrative purpose such as monitoring, emplacement and other management policy.

A radioactive waste disposal facility needs to be developed in a way to protect present and future generations and its environment. A safety assessment is implemented for normal and abnormal scenarios and human intrusion scenarios as a part of a safety case in developing a disposal facility for the radioactive waste. The human intrusion scenarios include a well scenario which takes into account various potential exposure groups (PEGs) who use a groundwater well contaminated with radionuclides released from the disposal facility. It is observed that a pumping rate has a negative correlation with the biosphere dose conversion factor (BDCF) in the well scenario. C-14 is shown to be a key radionuclide in the well scenario, and a special model based on the carbon cycle is applied for C-14. For Tc-99, an adsorption coefficient should be adjusted to be suitable for the site. The safety assessment for the radioactive waste disposal facility is successfully carried out for the well scenario. However, it is observed that site-specific models needs to be developed and sitespecific input data need to be collected in order to avoid unnecessary conservatism.

Important medical radionuclides for Positron Emission Tomography (PET) are producing using cyclotrons. There are about 1,200 PET cyclotrons operated in 95 countries based upon IAEA database (2020). Besides, including PET cyclotrons, demands for particle accelerators are continuously increasing. In Korea, about 40 PET cyclotrons are in operating phases (2020). Considering design lifetime (about 30-40 years) and actual operating duration (about 20-30 years) of cyclotrons, there will be demands for decommissioning cyclotron facilities in the near future. PET cyclotron produces radionuclides by irradiating accelerated charged particles to the targets. During this phase, nuclear reactions (18O(p,n)18F etc.) produce secondary neutrons which induce neutron activation of accelerator itself as well as surrounding infrastructures (the ancillary subsystems, peripheral equipment, concrete walls etc.). Generally, experienced cyclotron personnel prefer an unshielded cyclotron because of the repair and maintenance time. In unshielded cyclotron, water cooling systems, air compressor, and other equipment and structures could be existed for operating purposes. Almost all the equipment and structures are consisted of steel, and these affect neutron distribution in vault especially thermal neutron on the concrete wall. In addition, most of them can be classified as very low level radioactive wastes by Nuclear Safety and Security notice (NSSC Notice No. 2020-6). However, few studies were estimating radioactivity concentrations (Bq/g) of surrounding structures using mathematical calculation/simulation codes, and they were not evaluating the effect of surrounding structures on neutron distribution. In this study, by using computational neutron transport code (MCNP 6.2), and source term calculation code (FISPACT- II), we evaluated effect of the interaction between surrounding structures (including surrounding equipment) and secondary neutrons. Discrepancies of activation distribution on/in concrete wall will be occur depending on thickness of structure, distance between structures and walls, and consideration of interaction between structures and neutrons. Throughout this study, we could find that the influence of those structures can affect neutron distribution in concrete walls even if, thickness of the structure was small. For estimating activation distribution in unshielded cyclotron vault more precisely, not only considering cyclotron components and geometry of target, but also, considering surrounding structures will be much more helpful.

Recently, Japan’s government has announced Tokyo Electric Power Company’s plan to discharge contaminated water stored from the tanks of the Fukushima Daiichi nuclear power plant site into the sea. The contaminated water is treated by advanced liquid processing system (ALPS) to remove 62 radionuclide containing cesium, strontium, iodine and etc. using co-precipitation (or precipitation) and adsorption for other nuclides (except for tritium and carbon-14). The total amount of the contaminated water generated by ALPS facility is 1,311,736 m3 (as of August 18, 2022). The amount of contaminated water is estimated same as Tokyo dome volume. Under the sea discharge plan, the contaminated water will be diluted in seawater more than 100 times, and tritium concentration lowered 1/7 of the drinking water standard set by the World Health Organization (10,000 Bq/liters). The diluted water will then move through an undersea tunnel and be discharged about 1 kilometer off the coast.