In 2022 and 2023, the Korea Institute of Nuclear Safety (KINS), a regulatory body, revised the regulatory guidelines for off-site dose evaluation to residents, marine characteristics surveys around nuclear facilities, and environmental radiation surveys and evaluation around nuclear facilities. In addition, the NRC, a US regulatory body, has revised regulatory guide 1.21 (MEASURING, EVALUATING, AND REPORTING RADIOACTIVE MATERIAL IN LIQUID AND GASEOUS EFFLUENTS AND SOLID WASTE) to change environmental programs for nuclear facilities. The domestic regulatory guidelines were revised and added to reflect the experience of site dose evaluation for multiple units during the operation license review of nuclear facilities, the resident exposure dose age group was modified to conform to ICRP-72, and the environmental monitoring plan was clarified. In the case of the US, the recommended guidelines for updating the long-term average atmospheric diffusion factor and deposition factor, the clarification of the I-131 environmental monitoring guidelines for drinking water, and the clarification of the procedures described in the technical guidelines when changing environmental programs have been revised and added. Through such regulatory trend review, it is necessary to preemptively respond to changes in the regulatory environment in the future.

K-DOSE60, a off-site dose calculation program currently used by khnp, is performing evaluation based on the gaseous effluent evaluation methodology of NRC Reg. Guide 1.109. In particular, H-3 and C-14, which are the major nuclides of gaseous effluent, are evaluated using a ratio activity model. Among them, H-3 is additionally evaluating the dose to OBT (Organically Bound Tritium) and HT as well as HTO (Triated water). However, NRC Reg. Guide 1.109 is a methodology developed in the 1970s, and verification was performed by applying the evaluation methodology of H-3 and C-13 presented by IAEA TRS-472 in 2010 to the current K-DOSE60. The IAEA TRS-472 methodology also includes OBT and HT for H-3. In order to apply the ratio radioactivity model presented in IAEA TRS-472, the absolute and relative humidity were calculated using the weather tower of the nuclear site and used for H-3 evaluation. For the dose evaluation of HT, the previously used Canada Chalk River Lab. (CNL) conversion factor was used. For atmospheric carbon concentration, the carbon concentration presented in IAEA TRS-472 was used, not the carbon concentration in the 1970s of NRC Reg. Guide 1.109. It was confirmed that the K-DOSE60, which applied the changed input data and methodology, was satisfied by performing comparative verification with the numerical calculation value.

After the Fukushima nuclear power plant accident in 2011, interest in technology for evaluating residents’ exposure to effluents generated from nuclear power plants at the time of the accident has increased. KHNP has developed the S-REDAP program and is using it to evaluate radiation dose and recommend resident protection measures in the event of a nuclear power plant emergency. Its main functions are source term evaluation, atmospheric diffusion evaluation, radiation dose evaluation, etc. Based on these evaluations, resident protection measures are evaluated. In Japan, evaluation is conducted through a program called SPEEDI-MP (System for Prediction of Environmental Emergency Dose Information Multi-model Package) created by JAEA (Japan Atomic Energy Agency). Similar to S-REDAP, the program also evaluates effluents emitted from nuclear facilities through source term evaluation and atmospheric diffusion factor evaluation. In JAEA, through a program using SPEEDI-MP, the source term evaluation was performed in collaboration with NSC (Nuclear Safety Commission) in the event of the Fukushima nuclear plant accident, and dose evaluation in Japan was performed 2 months as an atmospheric diffusion factor using meteorological data for 2 days. Through comparative analysis of evaluation data from Japan, improvements to the current program be derived.

The US NRC developed a program called NRCDose3 to evaluates the environmental impact of radiation around nuclear facilities. The NRCDose3 code is a software suite that integrates the functionality of three individual LADTAP II, GASPAR II, and XOQDOQ Fortran codes that were developed by the NRC in the 1980’s and have been in use by the nuclear industry and the NRC staff for assessments of liquid effluent and gaseous effluent, and meteorological transport and dispersion, respectively. Through the integrated program, it is possible to conduct safety assessment and environmental impact assessment from liquid and gaseous effluent when operating permits are granted. In addition to a more user-friendly graphic user interface (GUI) for inputting data, significant changes have been made to the data management and operation to support expanded capabilities. The basic calculation methods of the LADTAP II, GASPAR II, and XOQDOQ have not been changed with this update to the NRCDose3 code. Several features have been added. The previous program used only ICRP-2 dose conversion factor, but the new program can additionally use dose conversion factor of ICRP-30 and ICRP-72. In the previous program, 4 age groups (infant, child, teen, and adult) were evaluated during dose evaluation, but when ICRP-72 was selected, 6 age groups (infant, 1-year, 5-year, 10-year, 15-year, and adult) could be evaluated. In addition, when selecting ICRP-72, many user-modifiable parameters such as food intake and exposure time were added. It will be referred to E-DOSE60, a program currently under development.

In-situ gamma spectrometer with mobile equipment can be used for rapid determination of radioactivity in the environment within a very short interval. 2”×2” NaI(Tl) scintillator are used to build a mobile radiation measurement system (called as Monitoring of Ambient Radiations of KAERI for Backpack, MARK-B3) with a signal processing unit, and GPS and interface units to a PC for wireless controlling system. Development of the survey system is to measure ambient gamma-ray spectrometry for estimating ground radioactivity and radiation dose in the environment. The ambient dose rate is estimated using G-factor method. For determination of G-factor, we conducted MCNP simulations in assumptions of various incident photons into the detector system. And the scintillator was exposed to Cs-137 source in the range of 1- 300 mGy/hr. Calculated dose rates for different simulation results were compared to the irradiated dose rate to derive correction factor of G-factor. To evaluate performance of the MARK-B3, in-situ gamma spectrometry was conducted in Jeju island.

Radionuclide analysis methods must be secured in the event of emergencies such as the discovery of unknown nuclear material or nuclear accidents in neighboring countries or Korea. Most institutions in Korea are in their early stages of radionuclide analysis method development and do not even have Radiation Controlled Areas where they can handle the samples safely. Some institutions such as the Korea Atomic Energy Research Institute have the ability to perform radionuclide analysis for nuclear facilities or verification of nuclear activities. In Korea, it is necessary to secure nuclide analysis technology to enable independent verification in times of emergency or need. This paper analyzes uranium as the target nuclide using alpha spectrometer and TIMS. Alpha spectrometer detects alpha particles emitted from uranium samples and measures the concentration of uranium isotopes. This method has a high selectivity that distinguishes it from other elements, and accurate measurements can be made even when uranium samples are mixed with other elements. In addition, there is minimal interference from other radioactive isotopes in the sample, and the sample preparation is simple, resulting in relatively short analysis times. In contrast, TIMS detects ionized uranium ions by heating the uranium sample. This method may have potential interference from other elements and may take relatively longer analysis times. However, TIMS has high sensitivity and accuracy and can detect various elements other than uranium, making it suitable for various analyses. Therefore, when analyzing uranium, it is recommended to select and use the appropriate device according to the purpose, as both alpha spectrometer and TIMS have their pros and cons. Furthermore, by using both devices in parallel, more accurate and reliable results can be obtained. This paper aims to compare the analysis methods of alpha spectrometer and thermal ionization mass spectrometry, which are widely used for nuclide analysis in unknown nuclear materials.

According to ISO 4037, the thickness of the inherent filtration for the radiation qualities L-40 to L- 240, N-40 to N-400, W-60 to W-300 and H-80 to H-400 shall be equivalent to 4 mm Al for matched reference radiation fields or adjusted as far as possible to 4 mm Al for characterized reference radiation fields. And for matched reference fields, the tube window must be made of beryllium and its thickness should not exceed 10 mm. In the case of characterized reference fields, the thickness of the beryllium window should not exceed 10 mm, but it is acceptable to use an aluminum window with a maximum thickness of 1.5 mm. 320 KV X-ray tube installed at KHNP-CRI has been designed to equipped with a 3 mm Be for tube window and an additional 4 mm Al to obtain a total inherent filtration equivalent to that of 4 mm Al. In the previous study, the inherent filtration of 320 kV X-ray tube at KHNP-CRI has been verified by MCNP simulation. However, the ISO standards suggest a method for determining the thickness of the inherent filtration by half-value layer (HVL) measurement and spectrometry. In this regard, the inherent filtration was reassessed using HVL measurement. To determine the inherent filtration, 1st HVL of the beam generated by the tube at a tube potential 60 kV was measured. The measurements were conducted with a calibrated spherical ionization chamber (model A3, Exradine) placed at a distance of 1 m from the target, at the center of the radiation field size. The X-ray tube current was set to 2 mA. The thickness of aluminum absorbers was gradually adjusted in subsequent measurements until approached the 1st HVL. 1st HVL were estimated using the linear regression equation computed with the current values for the thickness of the absorbers. As a results, the thickness of the 1st HVL was estimated as 2.845 mm Al. According to the correlation between the inherent filtration and 1st HVL suggested in ISO standard, the value of the inherent filtration was deduced as 4.25 mm Al that is rounded to the nearest 0.05 mm by interpolation. Further studies on the effects of the inherent filtration thickness determined in this study will be conducted.

Tritium is a radioactive isotope of hydrogen with a half-life of about 12.3 years, and it is commonly found in the environment as a result of the production of Nuclear Power Plants. The World Health Organization (WHO) has established guidelines for the permissible levels of tritium in drinking water. The guideline value for tritium in drinking water is 10,000 Bq/L. It is important to note that the guideline value for tritium is not a legal limit, but rather a recommendation. National and local authorities may establish legal limits that are more restrictive than the WHO guideline value based on local conditions and risk assessments. The Australia and Finland have set a limit for tritium in drinking water at 76,103 Bq/L and 30,000 Bq/L respectively, which is more than three to seven times higher compare to guideline value of WHO. The United States Environmental Protection Agency (EPA) has set a maximum contaminant level (MCL) for tritium in drinking water at 20,000 picocuries per liter (pCi/L), which is equivalent to 740 Bq/L. The Health Canada has set a guideline value for tritium in drinking water at 7,000 Bq/L. Assuming drinking water corresponding to each tritium limit (or guideline value) for one year, the expected exposure dose is 0.01 mSv to 1 mSv. It means that the tritium in drinking water below the limits or guideline value does not pose a significant risk to human health.

According to attached Table 1 of the Enforcement Ordinance of the Nuclear Safety Act, the effective dose limit of transport workers shall not exceed 6 mSv per year. In addition, the enforcement ordinance defines a transport worker as a person who transports radioactive substances outside the radiation management area and does not correspond to a radiation worker. In the nuclear power plants (NPPs), substances in radiation management areas are frequently transported inside or outside the plant. During loading of substances in the radiation management area onto the vehicle, the transport workers (including driver) are located outside the radiation management area. And also the exposure dose of transport workers is managed by using Automatic Dose Reader (ADR). However, the exposure dose of transport workers managed by NPP licensee is limited to the exposure caused by the transport actions required by the plant. This means that radiation exposure caused by the transport of radioactive materials carried out separately by individual transport workers other than the plant requirements cannot be managed. Therefore, even if the NPP licensee manages the transport worker’s dose below 6 mSv, it is difficult to guarantee that the total annual exposure dose, including the transport worker’s individual transport behavior, is less than 6 mSv. Therefore, it would be appropriate to manage the dose of the transport worker by the transport worker’s agency rather than by the NPP licensee.

In response to a regulatory mandate, all nuclear licensees are obligated to establish an information system that can provide essential information in the event of a radiation emergency by connecting the monitoring data of the Safety Parameter Display System (SPDS) or equivalent system to the Korea Institute of Nuclear Safety (KINS). Responding to this responsibility, the Korea Atomic Energy Research Institute (KAERI) has established the Safety Information Transmission System (SITS), which enables the collection and real-time monitoring of safety information. The KAERI monitors and collects safety information, which includes data from the HANARO Operation Work Station (OWS) and the HANARO & HANARO Fuel Fabrication Plant (HFFP) Radioactivity Monitoring System (RMS), and the Environmental Radiation Monitoring System (ERMS) & meteorological data. Currently, the transmission of this safety information to the AtomCARE server of the KINS takes place via the SITS server located in the Emergency Operations Facility (EOF). However, the multi-path of transmission through SITS has caused problems such as an increase in data transmission interruptions and errors, as well as delays in identifying the cause and implementing system recovery measures. To address these issues, a new VPN is currently being constructed on the servers of nuclear facilities that generate and manage safety information to establish a direct transmission system of safety information from each nuclear facility to the AtomCARE server. The establishment of a direct transmission system that eliminates unnecessary transit steps is expected to result in stable information transmission and minimize the frequency of data transmission interruptions. As of the improvement progress, a security review was conducted in the second and third quarters of 2022 to evaluate the security of newly introduced VPNs to the nuclear facility server, and based on the results of the review, security measures were strengthened. In the fourth quarter of 2022, the development of a direct transmission system for safety information began, and it is scheduled to be completed by the fourth quarter of 2023. The project includes the construction of the transmission system, system inspection, and comprehensive data stability testing. Afterward, the existing SITS located in the EOF will be renamed as the Safety Information Display System (SIDS), and there are plans to remove any unused servers and VPNs.

In this research, the dose rate was measured using a backpack-type scan survey device at 4 sites in sites around Nuclear Power Plants (Kori, Wolsong, Hanbit, Hanul), and the radioactivity ratio for each nuclide was evaluated using an high-purity germanium (HPGe) detector. Kori, Wolsong and Hanul power plants were measured within 2 km of the power plant, and Hanbit power plants were measured about 6.7 km from the power plant. As a result of measuring the dose rate with a backpacktype scan survey device, the average dose rate was the lowest in the measurement site 1 at 0.090 μSv/h, and the highest in the measurement site 4 at 0.145 μSv/h. All measurement points showed the domestic environmental dose rate level. The data obtained by the scan survey was visualized using the classed post and gridding functions of the surfer program. As a result of measurement with the HPGe detector, 137Cs was not detected, and only natural nuclides were detected. Among the detected natural nuclides, the radioactivity ratio was the highest for 40K with an average of 94.56%, and the lowest for 214Pb with an average of 0.26%. The results of this research can be used as basic data for radiation environment surveys around nuclear power plants. Further studies are needed to evaluate the radiation impacts by region and environment through periodic measurements.

The 2007 Recommendation of the International Commission on Radiological Protection recommended the application of dose constraints to optimize radiation protection to resolve the inequity of exposure among radiation workers. The average annual occupational doses in Korean nuclear power plants (NPPs) are 0.3-0.8 mSv. These doses are much lower than the annual effective dose limit of 50 mSv for radiation workers stipulated by the Nuclear Safety Act. In addition, most NPP workers received less than 0.1 mSv per year. These doses are lower than the average annual occupational doses of 0.3- 0.8 mSv. Korean regulatory body conducted the study to legislate the dose constraints in the Korean regulatory system and determine dose constraints (draft) for radiation workers. The legislation of dose constraints would not greatly affect the radiation protection programs in Korean NPPs because most workers received very low doses. However, some workers received relatively higher doses than others. This study analyzed the occupational exposure conditions, such as exposure type and situation, in Korean NPPs. This study investigated the internal and external radiation doses and the radiation doses depending on the NPP operating conditions, including normal operation, planned maintenance, and intermediate maintenance, for the last ten years (2012-2021). As a result, most NPP workers received external exposure rather than internal exposure. Furthermore, most radiation exposures occurred during the planned maintenance period. The results of this study can be used for optimizing occupational doses in Korean NPPs.

Low- and intermediate-level radioactive waste for permanent disposal often contains organic complexing agents, so-called chelating agents. Organic complexing agents, which are polycarboxylic acids, can increase the mobility of radionuclides into the environment by forming water-soluble complexes with most heavy metals. Therefore, analyzing the complexing agents in radioactive waste is crucial for comprehensive management of nuclear wastes. According to regulatory guidelines, specifically Notice No. 2021-16 issued by the Nuclear Safety and Security Commission, the determination of chelating agent content in radioactive waste materials is required to ensure proper management and safe disposal. However, only a few methods are available to analyze the chelators in various matrices such as concrete, metals, soil, and mixed solid wastes like plastics, vinyl, and rubber. Recently, we found a UV-Vis method based on an enzymatic reaction is inadequate for analyzing citric acid in radioactive waste with a complex matrix like concrete. To address this, we developed a method to determine the contents of EDTA and NTA using a UV-Vis spectrophotometer and citric acid using ion chromatography. The results showed good validity and reliability to determine the chelating agents in various radioactive wastes.

Bacterial metabolisms influence the behavior of uranium (U) in deep geological repository (DGR) system because bacteria are ubiquitous in the natural environment. Nevertheless, most studies for the U(VI) bioreduction have focused on a few model bacterium, such as Shewanella putrefaciens, Desulfovibrio desulfuricans, and Geobacter sulfurreducens. In this study, the potential of aqueous U(VI) ((U(VI)aq) reduction by indigenous bacteria was examined under anaerobic conditions with addition of 20 mM sodium acetate for 24 weeks. Three different indigenous bacterial communities obtained from granitic groundwater at depths of 44–60 m (S1), 92–116 m (S2), and 234–244 m (S3) were applied for U(VI)aq reduction experiments. The S2 groundwater contained the highest U concentration of 885.4 μg/L among three groundwater samples, where U mainly existed in the form of Ca2UO2(CO3)3(aq). The S2 groundwater amended 20 mM of sodium acetate was used for the U(VI)aq bioreduction experiment. Variations in the U(VI)aq concentration and redox potential were monitored for 24 weeks to compare U(VI)aq removal efficiency in response to indigenous bacteria. The U(VI)aq removal efficiencies varied among three indigenous bacteria: 57.8% (S3), 43.1% (S2), and 37.7% (S1). The presence of the thermodynamically stable uranyl carbonate complex resulted in the incomplete U(VI)aq removal. Significant shifts in indigenous bacterial communities were observed through highthroughput 16S rRNA gene sequencing analysis. Two SRB species, Thermodesulfovibrio yellowstonii and Desulfatirhabdium butyrativorans, were dominant in the S3 sample after the anaerobic reaction, which enhanced the bioreduction of U(VI)aq. The precipitates produced by bacterial activity were determined to be U(IV)-silicate nanoparticles by a transmission electron microscope (TEM)-energy dispersive spectroscope (EDS) analysis. These results demonstrated that considerable U immobilization is possible by stimulating the activity of indigenous bacteria in the DGR environment.

Dissolution behaviors of ThO2(cr) and PuO2(cr) in synthetic groundwater were investigated at room temperature (23  2°C) under atmospheric conditions. The synthetic groundwater was prepared according to the chemical composition of the KURT-DB3 groundwater. The pH and Eh of the synthetic groundwater were pH 8.9 and 0.5 V, respectively, and the major components were Na, K, Ca, Mg, Si, Cl, SO4, F and HCO3 ions. A few mg of ThO2(cr) and PuO2(cr) powder were added in the synthetic groundwater and the concentrations of Th and Pu in supernatant were monitored for 5 months of reaction time. The concentrations of Th before and after ultracentrifugation were compared, while the solid-liquid phase separation of Pu samples could not be applied due to the small volume of sample solutions. The concentrations of Th and Pu were measured by ICP-MS and alpha spectrometry, respectively. Geochemist’s Work Bench (GWB, standard, 17.0) was applied for the modeling with ThermoChimie TDB v. 11a, which was updated with the latest NEA-TDB (vol. 14). Aqueous species distributions and solubility limiting solid phases of Th and Pu under the synthetic groundwater conditions were evaluated. The results of geochemical modeling indicate that aqueous Th-OH-CO3 ternary species and Pu(IV) species are dominant in solutions equilibrated with ThO2(s) and PuO2(am, hyd), respectively. The dissolution behaviors of ThO2(cr) and PuO2(cr) are comparable to the dissolution of ThO2(aged, logKsp = 8.5) and the oxidative dissolution of PuO2(am, hyd) in the presence of PuO2(coll, hyd), respectively.

Measurement of oxide ion (O2-) concentration is a basic technology required in molten salt fields, from energy storage systems to electrolytic reduction of rare earth elements or spent nuclear fuels. In a molten salt reactor, O2- ions react with actinide elements to form their oxides or oxy-chlorides to induce actinide precipitation, and promote metal corrosion to cause a failure of structural material. For these reasons, removal of O2- ions and monitoring of the O2- concentration in molten salt reactors are essential. In this study, methods using chemical and electrochemical methods were investigated for measuring the concentration of O2- ions in a molten salts. The acid-base neutralization reaction was used as a chemical analysis method. And electrochemical methods using the O2- diffusion limit current and YSZ (yttria stabilized zirconia) indicator electrode were used for measuring the O2- concentration. Finally, a modified method using porous membrane electrode was applied to monitor the O2- concentration. The O2- concentration was measured up to about 2wt% of Li2O by the method using the O2- diffusion current, up to about 4wt% by the YSZ indicator electrode, and about 6wt% by the porous membrane electrode in LiCl molten salts.

A molten salt reactor (MSR) is a conceptual nuclear reactor that uses molten salt with liquid fuel as its primary coolant. Based on the thermophysical and neutronic properties, MSR has advantages such as high efficiency, safety, combustion of transuranic (TRU) elements, and availability of miniaturization and on-power refueling. Various research on MSR such as system development, neutronic analysis, material development, and molten salt property analysis has been conducted, but the biggest problem is the molten salt corrosion. The molten salt corrosion on structural materials can be explained by two processes; electrochemical and chemical reactions. The reduction of oxidative ions such as fuel and TRU elements is one of the major causes of molten salt corrosion. Contamination by humidity and oxygen is also known as the accelerating factor of molten salt corrosion. Also, molten salt corrosion behaviors on structural material deteriorate when dissimilar alloys are introduced in the molten salt system. Various techniques to mitigate molten salt corrosion in fluoride system has been developed, but these are not well-verified in chloride system. In this research, various methodologies to mitigate molten salt corrosion are studied. The corrosion behaviors of 80Ni-20Cr alloy in molten eutectic NaCl-MgCl2 salt at 973 K are analyzed with various applications such as salt purification, sacrificial metal injection, and salt redox potential control. Oxygen and water impurities that can accelerate molten salt corrosion have been removed by electrochemical and chemical methods; Applying the reduction potential for H+/H2 and oxidation potential for O2-/O2, introducing HCl and CCl4 gas, and introducing the metallic Cr and recovering the ionized Cr. Corrosion acceleration/deceleration effects were analyzed when introducing the reducing reagent such as Mg and Nb or oxidizing reagent such as metallic Mo and the effect of inert metallic element (W) was also investigated. The salt potential was controlled by applying the potential to the salt and adjusting the Eu3+/Eu2+ ratio.

Radioactive wastes, including used nuclear fuel and decommissioning wastes, have been treated using molten salts. Electrochemical sensors are one of the options for in-situ process monitoring using molten salts. However, in order to use electrochemical sensors in molten salt, the surface area must be known. This is because the surface area affects the current of the electrode. Previous studies have used a variety of methods to determine the electrode surface area in molten salts. One method of calculating the electrode surface area is to use the reduction current peak difference between electrodes with known length differences. The method is based on the reduction peak and has the benefit of providing long-term in-situ monitoring of surfaces immersed in molten salt. A number of assumptions have been made regarding this method, including that there is no mass transport by migration or convection; the reaction is reversible and limited by diffusion; the chemical activity of the deposit should be unity; and species should follow linear diffusion. For the purpose of overcoming these limitations, a variety of machine learning algorithms were applied to different voltammogram datasets in order to calculate the surface area. Voltammogram datasets were collected from multiarray electrodes, comprising a multiarray holder, two tungsten rods (1 mm diameter) working electrodes, a quasi-reference electrode, and a counter electrode. The multiarray electrode holder was connected to the auto vertical translator, which uses a servo motor, for changing the height of the rod in the molten salts. To make big and diverse data for training machine learning models, various concentrations of corrosion products (Cr, Fe) and fission products (Eu, Sm) in NaCl-MgCl2 eutectic salts were used as electrolyte; electrolyte temperatures were 500, 525, 550, 575, and 600°C. This study will demonstrate the potential of utilizing machine learning based electrochemical in situ monitoring in molten salt processing.

Molten salts have gained significant attention as a potential medium for heat transfer or energy storage and as liquid nuclear fuel, owing to their superior thermal properties. Various fluoride- and chloride-based salts are being explored as potential liquid fuels for several types of molten salt reactors (MSRs). Among these, chloride-based salts have recently received attention in MSR development due to their high solubility in actinides, which has the potential to increase fuel burnup and reduce nuclear water production. Accurate knowledge of the thermal physical properties of molten salts, such as density, viscosity, thermal conductivity, and heat capacity, is critical for the design, licensing, and operation of MSRs. Various experimental techniques have been used to determine the thermal properties of molten salts, and more recently, computational methods such as molecular dynamics simulations have also been utilized to predict these properties. However, information on the thermal physical properties of salts containing actinides is still limited and unreliable. In this study, we analyzed the available thermal physical property database of chloride salts to develop accurate models and simulations that can predict the behavior of molten salts under various operating conditions. Furthermore, we conducted experiments to improve our understanding of the behavior of molten salts. The results of this study are expected to contribute to the development of safer and more efficient MSRs.

The operation of nuclear power plants, nuclear waste depositories, and the decontamination and decommissioning of nuclear power plants all have the possibility of generating various kinds of radionuclides that can be formed as gaseous or liquid phases. Among the radionuclides, strontium is considered as most harmful substance due to its abundance in nuclear accident effluent, long half-life, high fission yield, high water solubility, and high mobility in aquatic environment. To remove strontium from aquatic environment, adsorption technique is mainly used with high economic feasibility, efficiency, and selectivity. Previously, we synthesized sodium titanates with mid-temperature hydrothermal method as selective strontium adsorbent in aqueous solution. Moreover, it was demonstrated that synthesized sodium titanates show high strontium adsorption rate with high selectivity with high surface area, pore diameter and volume. Herein, we investigated the surface structure of synthesized sodium titanates before and after strontium adsorption in aqueous solution using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) analysis. According to SEM and EDS experimental results, aquatic strontium can be adsorbed as surface precipitation with formation of cube-shaped structure, which is quite similar strontium titanate structure crystals onto the surface of sodium titanates. In addition, XPS experimental results revealed that the titanium ions on the surface of sodium titanates were oxidized during strontium surface precipitation process, and the sodium ion on the surface of sodium titanates were exchanged with aquatic strontium ions via ion exchange process during strontium adsorption process.