Mars is the planet closest to Earth. Many support that it may house humanity in the future. On the surface of Mars, sufficient resources are available to support life. Active studies are required to fundamentally comprehend the varied operating conditions and the major governing parameters involved in the growth of space colonization and supported atmospheric conditions. The existing legal framework of the Outer Space Treaty (OST), which was designed several decades ago, describes its goal of peaceful collaboration based on principles that we have not been able to uphold on Earth. It is vital to address the gaps in the legal system and ultimately deal with the mostly unanswered legal and regulatory questions. As interest in Martians colonisation missions from both government agencies and the private sector evolves, a workable solution that respects the essence of the OST and allows for limited sovereignty claims outside of protected habitation has been proposed.
Cu2+/polyacrylonitrile composite fibers were prepared by electrospinning, and then Cu/carbon nanofibers (denoted as Cu/ CNF-X; X = Cu content, 0, 3, or 5 wt%) were formed by calcining them. The effects of Cu2+ content and carbonization temperature on the conductivity and electrothermal conversion of Cu/CNF-X were investigated. The results revealed that the conductivity and electrothermal properties of Cu/CNF-X improve with the increase in the Cu2+ content and carbonization temperature. When the carbonization temperature was 800, 900, or 1000 °C, the conductivity of Cu/CNF-5 (0.08, 0.68, or 2.48 S/cm, respectively) increased to 1.6, 1.5, or 1.6 times that of Cu/CNF-0, respectively. The highest instantaneous surface temperatures of Cu/CNF-5 calcined at 800, 900, and 1000 °C (36, 145, and 270.2 °C, respectively) increased by 4, 25.5, and 44.6 °C, respectively, compared with those of the corresponding Cu/CNF-0 samples (32, 120.3, and 225.6 °C, respectively). Thus, the addition of a small amount of Cu2+ effectively improved the conductivity and electrothermal conversion performance of Cu/CNF-X, which has potential application value in industrial products in the future.
Heavy metal ions pollution has become of worldwide critical concern, thus, it is particularly important to monitor it in the environment and food for ensuring human health. In this study, p-phenylenediamine and 2-mercaptothiazoline were used to prepare nitrogen (N) and sulfur (S) co-doped carbon dots (N/SCDs) for fluorescent and colorimetric detection of Cu2+. The fabricated N/SCDs with bright green fluorescence showed excellent optical characteristics and favorable water solubility. In an aqueous system, a significant fluorescence quenching of N/SCDs at 512 nm is obtained in the presence of Cu2+. It also caused a significant colorimetric response with the color of prepared N/SCDs solution changed from colorless to yellow. Under optimal conditions, the analytical results showed that the linear range spanning from 5 to 400 μM, with a detection limit of 0.215 μM in fluorescence and 0.225 μM in colorimetric detection. In addition, N/SCDs displayed high selectivity toward Cu2+. No obvious interference was observed over other metal ions. Furthermore, we have also used N/SCDs to monitor Cu2+ in tap and lake water. The recovery of Cu2+ ranged between 89.6% and 113.1%. Exhibiting remarkable sensitivity and selectivity, the designed sensor offers a promising detection method for Cu2+ detection in the real sample.
A series of ZIF-67-C-IL catalysts were prepared using ZIF-67 and 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide ([ BMIM]NTf2) ionic liquid as precursors. The structure of the catalysts was characterized by XRD, TEM, SEM and XPS. The catalytic performance of the catalysts for the oxygen reduction reaction (ORR) was evaluated in a three-electrode system. The results confirmed that the high-temperature treatment of the precursors resulted in the formation of N, S codoped carbon-encapsulated Co9S8 nanoparticles. To create N, S co-doped carbon coated Co9S8 nanoparticle catalysts, ionic liquids are used as sulfur and nitrogen sources. The catalytic activity of ORR can be improved using N, S co-doped carbon to prevent the aggregation of Co9S8 nanoparticles. Graphitized and N, S co-doped carbon shells are optimal for achieving high activity stability. Optimal 600-ZIF-67-C(1:1.5)-30IL catalytic activity was observed for ORR. The half-wave potential of ORR was 0.88 V vs. RHE in 0.1 mol L− 1 KOH, with a limit current density of 4.70 mA cm− 2. Similar ORR electrocatalytic activity was observed between this catalyst and commercial Pt/C (20 wt%).
Background: The abdominal drawing-in maneuver (ADIM), a method of lumbar stabilization training, is an effective neuromuscular intervention for lumbar instability associated with low back pain (LBP). Objects: The purpose of this study was to compare the effect of a 2-week period of the ADIM and tensor fasciae latae-iliotibial band (TFL-ITB) self-stretching on lumbopelvic rotation angle, lumbopelvic rotation movement onset, TFL-ITB length, and pain intensity during active prone hip lateral rotation. Methods: Twenty-two subjects with lumbar extension rotation syndrome accompanying shortened TFL-ITB (16 males and 6 females) were recruited for this study. The subjects were instructed how to perform ADIM training or ADIM training plus TFL-ITB self-stretching program at home for a 2-week period. A 3-dimensional ultrasonic motion analysis system was used to measure the lumbopelvic rotation angle and lumbopelvic rotation movement onset. An independent t-test was used to determine between-group differences for each outcome measure (lumbopelvic rotation angle, lumbopelvic rotation movement onset, TFL-ITB length, and pain intensity). Results: The results showed that ADIM training plus TFL-ITB self-stretching decreased the lumbopelvic rotation angle, delayed the lumbopelvic rotation movement onset, and elongated the TFL-ITB significantly more than did ADIM training alone. Pain intensity was lower in the ADIM training plus TFL-ITB self-stretching group than the ADIM training alone group; however, the difference was not significant. Conclusion: ADIM training plus TFL-ITB self-stretching performed for a 2-week period at home may be an effective treatment for modifying lumbopelvic motion and reducing LBP.
Athalia japonica (Klug, 1815) is a significant insect pest of turnips in Korea. The complete mitochondrial genome of this species isolated in Korea is reported in this study, which is the first attempt to study Korean Athalia species. The circular genome is 15,662 bp in length and consists of 13 protein-coding genes, two rRNA genes, 22 tRNA genes, and an A+T-rich region. Consistent with most members of the genus Athalia, five of the tRNA genes are rearranged from the typical ground pattern of ancestral insect gene order. Phylogenetic analyses inferred from the nucleotide sequences of 25 mitochondrial genomes indicate that the Korean A. japonica is a distinct member of the genus Athalia. This study accumulates mitochondrial genome data of A. japonica from various countries, providing useful information on mitochondrial genetic differences across geographical distances in the East Asian region.
This study presents the results of mosquito surveillance monitoring in Chungnam Province from 2017 to 2020. A total of 130,750 mosquitoes were collected, and we analyze variations of mosquito populations with emphasis on the most abundant species. We also provide the field survey data based on the different habitats in Chungnam Province.
In the study, a variation of Haemaphysalis longicornis, a major vector of fever-causing conditions, was statistically analyzed to identify the spatial and climatic factors affecting the time-dependent variations of its population. The survey occurred in different habitats in South Korea. In addition, we developed a predictive model by using a probability function to find the peak occurrence time annually. As a result, the numbers of adults and nymphs were found to be related to temperature and relative humidity and their population peaked at the end of May in all habitats except deciduous forests. This study is expected to provide information on habitat types, times, and climate patterns that require attention to help control H. longicornis populations.