Ar 및 Ar과 N2 분위기하에서 rf 마그네트론 스퍼터링방법으로 Ta-AI과 Ta-AI-N합금막을 제조하였다. Ta-7.9at.% AI계열, Ta-26.7 at% AI게열과 Ta-45.4at.%AI계열에 Ar에 대한 질서유량비로 26%까지 질소를 첨가하여 Ta-AI-N박막을 증착한후, 300-600˚C온도 구산에서 열처리 전후의 구조 및 전기적 특성과 열적안정성을 통하여 레지스터의 적용가능성을 조사하였다. 구조 및 조성 분석은 X-선 회절과 Rutherford Backscattering Spectrometry(RBS)로 관찰하였고 열적안정성은 4단자법(four point probe method)을 이용한 저항변화를 통하여 측정하였다. 순수 Ta에 AI을 첨가하면 확장된 β(β-Ta)N 합금박막에서 가장 열적안정성이 우수하게 나타났던 질소첨가 범위는 Ta Nhcp또는 TaN/ sub fcc/또는 Ta Nfcc와 비정질과의 혼합상순으로 상천이를 나타내었다. Ta-AI-N 합금박막에서 가장 열적안정성이 우수하게 나타났던 질서첨가 범위는 Ta-26.7at. % AI계열의 경우 19-36at.% N2구간이었고, Ta-45.5at.% AI계열의 경우는 30-45at.%구간이었다. Ta-AI합금박막은 질소가 첨가되지 않아도 열처리 온도 및 시간에 따라 약 10% 이내의 비교적 작은 저항변화를 보여 열적안정성이 우수하지만 질소를 첨가하여 Ta-AI-N합금박막을 형성시킬경우, 증착된 상태에서 이미 큰 비저항을 나타내었고 열처리 동안 3%이내의 매우 작은 저항변화를 나타내었기 때문에 레지스터용 재료로써 열적안정성에 대한 잠재력이 크다. 크다.

In this study, the hydraulic gradient was calculated using the groundwater level and rainfall observed in the Hyogyo-ri area for a year, and the change in the hydraulic gradient according to the rainfall was analyzed. It was found that the groundwater level increased as the rainfall increased in all groundwater wells in the research site, and the groundwater level rise decreased as the altitude of the groundwater well increased. The hydraulic gradient in the research site ranged from 0.016 to 0.048, decreasing during rainfall and increasing after the end of the rainfall. As the rainfall increased, the groundwater level rise in the low-altitude area was more than the high-altitude area, and the hydraulic gradient decreased due to the difference in groundwater level rise according to the altitude. Through this study, it was found that the influence of rainfall is dominant for the fluctuation of the hydraulic gradient in the unconfined aquifer.

In this study, we analyzed seasonal variations in carbon dioxide fluxes, concentrations, and soil temperatures over three years in unvegetated tidal flats in the Beolgyo area. We also investigated the correlations between carbon dioxide fluxes and influencing factors. The average carbon dioxide flux was positive in summer and autumn but negative in winter and spring. A positive correlation was observed between carbon dioxide flux and soil temperature in spring whereas a negative correlation was noted in summer. In summer and autumn, as the soil temperature increased, the carbon dioxide flux decreased. In contrast, in spring and winter, as the soil temperature decreased, the carbon dioxide flux increased. Overall, this study reveals the significant influence of soil temperatures on carbon dioxide fluxes between the surface layer of the tidal flat and atmosphere.

In this study, sediment cores from unvegetated tidal flats in the Hampyeong Bay (west coastal wetland) and Dongdae Bay (south coastal wetland) were sampled, the blue carbon stock in the sediments was calculated, and the characteristics of the blue carbon stock were analyzed based on particle size of the sediments. The sediments in the Hampyeong Bay tidal flat had large particle size and low mud content, and the Dongdae bay tidal flat had small particle size and high mud content. The organic carbon content and blue carbon stock in the sediments were higher in the Dongdae tidal flat than in the Hampyeong Bay tidal flat. As a result of the regression function, in both the Hampyeong Bay and Dongdae Bay tidal flats, the sediments had the smaller particle size and higher mud contents the higher the organic carbon content and blue carbon stock. The sediments with smaller particle size had the larger specific surface area, so were feasible to adsorb and store more organic matters.

The intertidal zone has both land and marine characteristics and shows complex weather environments. These characteristics are suited for studying climate change, energy balance and ecosystems, and may play an important role in coastal and marine weather prediction and analysis. This study was conducted at Odo Island, approximately 300m from the mainland in Yeosu. We built a weather observation system capable of real-time monitoring on the mud flat in the intertidal zone and measured actual weather and marine data. Weather observation was conducted from April to June 2022. The results showed changes in air temperature and water temperature with changes in the tide level during spring. Correlation analysis revealed characteristic changes in air temperature and water temperature during the day and night, and with inundation and exposure.

In this study, sediment cores were sampled from tidal flats (six sites) in the west and south coastal wetlands, the blue carbon stock in the tidal flat sediments was calculated, and the blue carbon stock characteristics and influencing factors were analyzed. The sediment particle size of the west coastal tidal flats was larger than that of the south coastal tidal flats, and the organic carbon content in the south coastal tidal flats was more than twice that of the west coastal tidal flats. Blue carbon stock per unit area was 28.4~36.8 Mg/㏊ on the west coastal tidal flats and 69.8~89.8 Mg/㏊ on the south coastal tidal flats, which was more than twice higher in the south coastal tidal flats than in the west coastal tidal flats. The total amount of blue carbon stock in the tidal flats was the highest in Suncheon Bay tidal flats at 153,626 Mg, and followed by Gomso Bay tidal flats at 141,750 Mg, Hampyeong Bay tidal flats at 58,420 Mg, Dongdae Bay tidal flats at 44,900 Mg, Cheonsu Bay tidal flats at 36,880 Mg, and Jinhae Bay tidal flats at 26,205 Mg. Blue carbon stock per unit area was higher in the south coastal tidal flats, but the total amount of blue carbon stock in the tidal flats was higher in the west coast. The slope of the regression function of blue carbon stock with respect to the organic carbon content in the tidal flat sediments was estimated to be about 0.05 to 0.07, and the slope of the regression function was higher in the west coastal tidal flats than in the south coastal tidal flats.

Baengnyeongdo, located within the Asian dust stream, is an ideal place to analyze Asian dust moving into the West Sea due to its low emission of artificial pollutants. Baengnyeongdo is being used to analyze the vertical distribution of dust from the lower atmosphere to the upper layer through remote observation. This study compared the ground concentration of dust between Baengnyeongdo and the metropolitan area, estimated the lag time of transport of Asian dust from Baengnyeongdo to the metropolitan area, and examined the homogeneity of upper winds using the rawinsonde method. The results showed that the cross correlation coefficient was higher and the lag time was shorter for each observation station when the distance from Baengnyeongdo was shorter. The upper wind at Baengnyeongdo is dominated by the west/northwest wind. It is the basis for the correlation of dust concentration between Baengnyeongdo and the metropolitan area located to the east. In the future, upper wind data and Asian dust concentration data over the West Sea and Baengnyeongdo are expected to contribute to research related to the movement and prediction of Asian dust and preparation for Asian dust in the metropolitan area.

This study analyzed the temporal and spatial characteristics of water quality for five hydropower dam reservoirs in South Korea. Water temperature, pH, dissolved oxygen, and chlorophyll-a (Chl-a) showed high fluctuations in summer and autumn at all reservoirs, indicating the existence of seasonal effects. At all five reservoirs, the concentrations of suspended solids (SS) and total nitrogen (TN) fell under the “slightly bad” category and those of total organic carbon (TOC) fell under the “slightly good” category or higher, according to “the standard for living environment of lake water quality.” Variations in the concentration ranges and degrees of change in SS, TN, and TOC among reservoirs were observed, indicating the influences of rainfall, surrounding environments, and seasonal changes. Daecheong and Namgang Dam showed high Chl-a concentrations in summer, indicating that the metabolism of microbial communities, such as algae, was active.

In this study, we installed a weather observation tower tailored to the intertidal zone and established an intertidal weather observation system capable of real-time monitoring through a wireless network. This provided weather observation data representing the meteorological characteristics of the intertidal zone. To optimize this system in the future, we present practical directions for the development of observation equipment and for the data management and sharing, and we contribute to establishing the infrastructure.

This research summarizes the generating factors of greenhouse gas (carbon dioxide, methane, nitrous oxide) in hydropower dams and related domestic/foreign researches. Microorganisms and eutrophication are the main factors in greenhouse gases in hydropower dam reservoirs. The greenhouse gas emission from the hydropower dam is affected by meteorological factors and dam operation periods, and greenhouse gases are also emitted from the outlets. The fluxes of greenhouse gas emission from the hydropower dams were –926~180,806 mg CO2 m-2d-1, -0.19~3800 mg CH4 m-2d-1, and 0.01~16.1 mg N2O m-2d-1. In South Korea, the study on the greenhouse gas emission from Korean hydropower dams has been rarely, and therefore it is inquired. This research suggested the methods on the greenhouse gas emission from Korean hydropower dams and flux calculation.

Moving average precipitation provides periodic precipitation patterns by solving precipitation irregularities. However, due to uncertain moving average periods, excessive data smoothing occurs, which limit the possibility to analyze groundwater levels in the short term. Nonetheless, groundwater level fluctuation can compensate these limitations as it can calculate appropriately for unit time and verify the effect of precipitation penetrated into groundwater in a short time period. In this study, the characteristics of groundwater level were evaluated using groundwater level fluctuation to compensate for limitations of groundwater level analysis using moving average precipitation. In addition, the groundwater quality was investigated using the electrical conductivity fluctuation. The study site was Hyogyo-ri, Yesan-si, Chungcheongnam-do. Four observation wells and an automated weather system were used. The correlation between groundwater level fluctuation and precipitation (Case 1) and the correlation between groundwater level and moving average precipitation (Case 3) were compared. In the analysis for 1 hour data, the correlation coefficient of Case 1 was higher than that of Case 3, and in the analysis for 1 day data, the correlation coefficient of Case 3 was higher than that of Case 1.

In this study, the necessity for a village unit Automatic Weather System (AWS) was suggested to obtain correct agricultural weather information by comparing the data of AWS of the weather station with the data of AWS installed in agricultural villages 7 km away. The comparison sites are Hyogyo-ri and Hongseong weather station. The seasonal and monthly averaged and cumulative values of data were calculated and compared. The annual time series and correlation was analyzed to determine the tendency of variation in AWS data. The average values of temperature, relative humidity and wind speed were not much different in comparison with each season. The difference in precipitation was ranged from 13.2 to 91.1 mm. The difference in monthly precipitation ranged from 1.2 to 75.4 mm. The correlation coefficient between temperature, humidity and wind speed was ranged from 0.81 to 0.99 and it of temperature was the highest. The correlation coefficient of precipitation was 0.63 and the lowest among the observed elements. Through this study, precipitation at the weather station and village unit area showed the low correlation and the difference for a quantitative comparison, while the elements excluding precipitation showed the high correlation and the similar annual variation pattern.

In this study, the antibiotic components in the final effluent from the 12 wastewater treatment facilities located in the Nakdong River basin were investigated, and the correlation between organic matters, nutrients and antibiotics was analyzed. In the final effluent of the wastewater treatment facilities, three sulfonamides antibiotics (sulfamethazine, sulfathiazole, sulfachlorpyridazine) and tetracyclines antibiotics (oxytetracycline, doxycycline) were detected. Sulfamethazine were detected at all points and ranged from 10.398 to 278.784 ng/L. Sulfathiazole were detected at 6 points (Andong, Gumi, Hapcheon, Miryang, Uiryeong, Haman), and ranged from 23.773 to 144.468 ng/L. The correlation coefficients between sulfathiazole and TSS, COD, TOC, NH3-N, NO2-N, and T-N components were high in the range of 0.73 to 0.92. The correlation coefficient between sulfamethazine and T-N was 0.48, and the correlation with the rest of the water quality components was low. The correlation coefficient between sulfamethazine and sulfathiazole was 0.78. Through this study, it was confirmed that the concentration of sulfonamides antibiotics was higher than the concentration of tetracyclines antibiotics in the final effluent of 12 wastewater treatment facilities in the Nakdong River basin, and the concentration of sulfathiazole increased with organic matters and nutrients.

In this study, carbon dioxide concentration and air temperature at different elevations were observed and analyzed in the upper atmosphere of mud flat and reed beds at low tide in Suncheon Bay. The carbon dioxide concentration and air temperature sensors were mounted on the drone, and the carbon dioxide concentration and air temperature by altitude (5 m, 10 m, 20 m, 40 m) at five points in the tidal flat and reed beds were observed in the morning and afternoon. The carbon dioxide concentrations in the upper atmosphere of the tidal flat ranged from 453.0 to 460.2 ppm in the morning and 441.6 to 449.7 ppm in the afternoon. The carbon dioxide concentrations in the upper atmosphere of the reed beds ranged from 448.9 to 452.4 ppm in the morning and 446.0 to 454.4 ppm in the afternoon. The carbon dioxide concentrations in the upper atmosphere of the tidal flat was higher in the morning than in the afternoon, and the carbon dioxide concentration decreased as the altitude increased. The carbon dioxide concentration in the upper atmosphere of the reed beds was similar in the morning and afternoon at all altitudes, and the carbon dioxide concentration decreased as the altitude increased. The correlation coefficient between carbon dioxide concentration and air temperature observed in the tidal flat in the morning was -0.54 ~ -0.77, and the correlation coefficient between carbon dioxide concentration and air temperature observed in the afternoon was 0.56 ~ 0.80. The correlation coefficient between carbon dioxide concentration and temperature observed in the morning in the reed field was low, below 0.3, and the correlation coefficient between carbon dioxide concentration and air temperature observed in the afternoon was 0.35 ~ 0.77. In the upper atmosphere of the tidal flats and reed beds, the linear function was suitable for the change of carbon dioxide concentration as a air temperature, and the coefficient of determination of the estimated linear function was higher in the afternoon than in the morning. Through this study, it was confirmed that the carbon dioxide concentration in the upper atmosphere of the tidal flat and the reed beds was different, and the increase rate of carbon dioxide concentration in the upper atmosphere of the tidal flat and the reed beds was higher in the afternoon than in the morning.