The experiment was performed for establishing the best condition of experiment and defining the issue of GC/FID methods based on HS-SPME-capillary column when TMA is measured in the air. Also the experiments are performed based on odor process test method alternately. At first, The result that KOH and NaOH were compared for eluting the TMA among the preprocessing processes, showed that NaOH is 2.2 times higher figure of area, 0.9972 of curve linearity(R2), and 1.96% of relative standard deviation. As a result using the ultrasonic cleaner and 30℃ constant temperature water bath, constant temperature water bath showed stabilized curve linearity (R2 0.9972) and relative standard deviation (RSD 2%). In advance of experiment conditions, the result performed acid filter paper method and acidic solution absorption among TMA sampling methods, is that acidic solution absorption detected 5 times better sensitivity than Acid filter paper method. Acidic solution absorption showed to provide excellent analysis sensitivity in this experiment restrictively. Therefore, in case of experiment by GC/FID method based on HS-SPME-capillary column, selection of sampling method expects that acidic solution absorption better effect and in case of disassemble reagent, NaOH and 30℃ constant temperature water bath is better effect in the experiment conditions.

IIn this research, ambient VOCs samples were collected by specially prepared stainless steel canisters from August 2002 to September 2004 at seven representative sites in Gumi. 29 kinds of VOCs which are presented by United States EPA method TO-14 were analyzed using GC/MSD. Based on the monitored data, the characteristics of VOCs concentrations in atmosphere in Gumi were grasped, pollution sources and contributions were also analyzed by PMF model, one kind of receptor models. As a whole, the average annual concentrations of VOCs in industrial complexes were higher than that in residential areas. In residential area1 and residential area2, the VOCs that had high concentrations in industrial complexes showed comparatively lower concentrations. But the aromatic substances mainly attributed to vehicle exhaust showed high concentrations which indicated that VOCs emitting sources in industrial areas have no direct effect on the VOCs concentration in residential areas. The results from PMF modeling indicated that a total of seven sources were independently identified and each source was contributed to the ambient Gumi City from Freon relation source (17%), electronic industrial complex source (27.86%), organic solvent source (19.26%), vehicle exhaust source (17.59%), Textile relation source (8.31%), and unknown source - 1, 2 were up to 2.96%, 7.02% in terms of VOCs, respectively.

The density characteristics of aldehydes in Kumi electronic Industrial Complex are measured in the summer and autumn in this study. Considering the characteristics of Kumi, five representative monitoring sites in Kumi are selected. According to fair Korean odor method, samples are collected and analyzed from July 26th, 2005 to October, 10th. Investigation objects include formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, iso-valeraldehyde, n-valeraldehyde. 40 samples in summer and 45 samples in autumn are measured and analyzed, respectively. The results show that the mean concentrations in residential area and industrial area are both obey the below sequence: acetaldehyde＞formaldehyde＞propionaldehyde＞butyraldehyde＞iso-valeraldehyde＞n-valeraldehyde. For acetaldehyde, its monitored concentration in industrial areas and residential areas close to industrial areas is higher than other areas. However, for formaldehyde, its concentration in the residential area 3 in tends to be higher than that in industrial areas. Based on seasons, concentrations in summer with long sunshine duration are higher than those in autumn. It can be seen that the density distribution of aldehyde in Kumi industrial complexes is closely related with the widely use of alcohol-type additives for automobiles and alcohol-type fuels. Meanwhile, most of the researches on aldehyde concentrate on capital areas or petrochemical industrial areas, taking the chance of odor prevention and control law implementing, the management scheme and reduction strategies on aldehyde ought to be carried out, which are also suitable to the enterprise characteristics in other industrial areas of this study.

This study focuses on the measurement of airborne Volatile Organic Compounds (VOCs) in the Kumi electronic industrial complex during the time periods of August and September, 2002 and January and February, 2003. This study was based on the US-EPA method TO-14 while the VOCs were analyzed with GC/MSD. The toluene level revealed high concentration at all measurement sites. The areal rank of average concentrations of VOCs is as follows : industry1>industry2>urban>middle>residential. Concentrations of VOCs in Kumi electronic industrial ones were generally higher than at Yeochon and Ulsan industrial complexes. Dichloromethane and trichloroethylene, which are used as a cleaner in the process of electronic industries, were observed 4 to 8 times higher than those of other areas. Among the aromatic compounds, toluene showed the highest level, while the concentrations of dichloromethane and trichloroethylene were higher than those of other halogen compounds. In Kumi, toluene, trichloroethylene, and dichloromethane were confirmed as the major compounds of VOCs by this research.