Herein, we analyzed the spatial and temporal variation of DO (dissolved oxygen), BOD (biochemical oxygen demand), and COD (Chemical Oxygen Demand) with the monthly mean observed data for 10 years (2008~2017) in the main stream of the Nakdong River. The water quality of the stations declined in a downstream direction, with the BOD and COD showing their highest values at the ST5 station. From the analysis of the correlation of water quality components at 10 stations, the correlation coefficient between the DO and water temperature was more than –0.90, and that between BOD and Chl-a was 0.48~0.85, and that between COD and TOC was more than 0.65 except for the ST5 and ST10 stations. From the regression analysis using data collected from all stations, the water temperature and DO decreased linearly with a coefficient of determination of 0.90, and the Chl-a and BOD could be described by increasing power functions with a coefficient of determination of 0.83. The TOC and COD followed increasing logarithm functions with a coefficient of determination of 0.58. The TOC efficiency at the 10 stations was estimated and the average efficiencies of BOD and COD were 15.5~36.3% and 57.4~89.6%, respectively.

In this study, the water quality components (pH, BOD, COD, TOC, SS, DO, TP) and the water quality, observed for 10 years (2008~2017) in the five tributaries of the Nakdong River with the highest flow rates, were analyzed. Monthly levels of the water quality components were estimated and regression functions were used to quantitatively explain the changes in the BOD and COD components, with respect to the TOC components. The results of analyzing the water quality levels in terms of the living environmental standards show that the lowest water quality was observed midstream (ST-3) and the highest water quality was observed upstream (ST-1 and ST-2). The regression function was estimated to be a linear function in all five tributaries, and the goodness of fit of the function was high upstream (ST-2), midstream (ST-3), and downstream (ST-4). According to the regression analysis using the observation data from 2008~2017, we found that the consumption of dissolved oxygen increased with an increase in organic matter in the major tributaries of the Nakdong River.

In this study, we analyze changes in soil heat flux and air temperature in August (summer) and January (winter) according to net radiation, at a mud flat in Hampyeong Bay. Net radiation was observed as -84.2~696.2 W/m2 in August and -79.4~352.5 W/m2 in January. Soil heat flux was observed as -80.7~139.5 Wm-2 in August and -49.09~137 W/m2 in January. Air temperature was observed as 24.2~32.9˚C in August and -1.5~11.1˚C in January. The rate of soil heat flux for net radiation (HG/RN) was 0.17 in August and 0.34 in January. Because the seasonal fluctuation in net radiation was bigger than the soil heat flux, net radiation in August was bigger than in January. We estimated a linear regression function to analyze variations in soil heat flux and air temperature by net radiation. The linear regression function and coefficient of determination for the soil heat flux by net radiation was y=0.19x-7.94, 0.51 in August, and y=0.39x-11.69, 0.81 in January. The time lag of the soil heat flux by net radiation was estimated to be within ten minutes in August 2012 and January 2013. The time lag of air temperature by net radiation was estimated at 160 minutes in August, and 190 minutes in January.

For areas with the diverse contamination sources, the change of 4-nitrophenol contamination and impact of potential contamination sources have been evaluated using monitoring data and a numerical model (HydroGeoSphere). The model considered several parameters including land cover, precipitation, and flow rate. And, the model has been performed to investigate the effect of decay rate of 4-nitrophenol. The results of the simulations showed that the influence on 4-nitrophenol in downstream was mainly greater than that in upstream, and the tributaries did not significantly affect the mainstream because of their low flow rates. In addition, the effect of contamination sources was simulated for each section, then the measured data were higher than the corresponding simulated data in most sections of the Geumho river. In particular, the impact of the potential contamination sources in the upstream area was much higher than that in the other area, thus more monitoring data for the upstream area is required.

This study investigated the characteristics of variations in carbon dioxide concentration and air temperature with the vertical change of surface in a grassplot. Field observations were carried out at a grassplot in Gyeongnam Science High School, over four days in August and November, 2015. Continuous observation equipment (GMP343, VAISALA) was installed at the LP (0.1 m from the surface) and UP (1.1 m from the surface) points, and the carbon dioxide concentration and air temperature were measured simultaneously at 1-min intervals. To summarize the results of the observation, August had higher than average concentrations of carbon dioxide, while November showed average air temperatures. Moreover, the concentration of carbon dioxide was higher at the UP point, while the air temperature was higher at the LP point. The correlation coefficient of carbon dioxide concentration between the UP and LP points was 0.80 in August across all the four days, while it was higher in November at 0.58 0.95. The results of the regression analysis of carbon dioxide concentration with air temperature changes for both August and November showed a distinct change at the LP point (R2=0.36 0.76), as compared to the UP point (R2=0.1 0.57). Between the UP and LP points, the carbon dioxide concentration and air temperature regression analysis results indicated that an active exchange was taking place between the two points.

The degradation of 3-chlorophenol(3-CP) by various AOPs(Advanced Oxidation Processes) including the ultraviolet / hydrogen peroxide, the Fenton and the ultraviolet(UV)-Fenton process has been conducted. The highest removal efficiency for 3-CP in the aqueous phase was obtained by the UV-Fenton process among the AOPs. In the UV-Fenton process, The removal efficiency of 3-CP decreased with increasing pH in the range of 3 to 6, and it decreased with increasing initial concentration. As the intermediates of 3-CP by UV-Fenton reaction, 3-chlorocatechol, 4-chlorocatechol, and chlorohydroquinone were detected thus the degradation pathways were proposed.