For the selective catalytic reduction of NOx with ammonia (NH3-SCR), a V2O5WO3/TiO2 (VW/nTi) catalyst was prepared using V2O5 and WO3 on a nanodispersed TiO2 (nTi) support by simple impregnation process. The nTi support was dispersed for 0~3 hrs under controlled bead-milling in ethanol. The average particle size (D50) of nTi was reduced from 582 nm to 93 nm depending on the milling time. The NOx activity of these catalysts with maximum temperature shift was influenced by the dispersion of the TiO2. For the V0.5W2/nTi-0h catalyst, prepared with 582 nm nTi-0h before milling, the decomposition temperature with over 94 % NOx conversion had a narrow temperature window, within the range of 365-391 °C. Similarly, the V0.5W2/nTi-2h catalyst, prepared with 107 nm nTi-2h bead-milled for 2hrs, showed a broad temperature window in the range of 358~450 °C. However, the V0.5W2/Ti catalyst (D50 = 2.4 μm, aqueous, without milling) was observed at 325-385 °C. Our results could pave the way for the production of effective NOx decomposition catalysts with a higher temperature range. This approach is also better at facilitating the dispersion on the support material. NH3-TPD, H2-TPR, FT-IR, and XPS were used to investigate the role of nTi in the DeNOx catalyst.
This study was conducted to develop a heat interception permeability aggregate pavement material that resists increase of air temperature and has permeability by decreasing pavement temperature of city in summer. For this study, a heat interception polymer binder mixed with heat interception material and polyurethane binder. And the study made heat interception permeability aggregate pavement material by mixing heat interception polymer binder. Using the materials, the study conducted flexural strength test and temperature reduction effect experiment. As the result, flexural strength was 5.43MPa average and the temperature reduction effect was effective up to maximum 16 degrees Celsius compared to current asphalt concrete.
Nanosized Gd2O3:Eu3+ red phosphor is prepared using a template method from metal salt impregnated into a crystalline cellulose and is dispersed using a bead mill wet process. The driving force of the surface coating between Gd2O3:Eu3+ and mica is induced by the Coulomb force. The red phosphor nanosol is effectively coated on mica flakes by the electrostatic interaction between positively charged Gd2O3:Eu3+ and negatively charged mica above pH 6. To prepare Gd2O3:Eu3+-coated mica (Gd2O3:Eu/mica), the coating conditions are optimized, including the stirring temperature, pH, calcination temperature, and coating amount (wt%) of Gd2O3:Eu3+. In spite of the low luminescence of the Gd2O3:Eu/mica, the luminescent property is recovered after calcination above 600℃ and is enhanced by increasing the Gd2O3:Eu3+ coating amount. The Gd2O3:Eu/mica is characterized using X-ray diffraction, field emission scanning electron microscopy, zeta potential measurements, and fluorescence spectrometer analysis.
The aim of this study was to investigate the effect of ethanol extract of Fagopyrum escuentum(FE) on the melanogenesis. To determine whether ethanol extract of FE suppress melanin synthesis in cellular level, B16F10 melanoma cells were cultured in the presence of different concentrations of FE ethanol extract. In the present study, the author examined the effects of FE ethanol extract on cell proliferation, melanin contents, tyrosinase activity. Cell proliferation was slightly increased by treatment with ethanol extract of FE (25-200 μg/ml). The ethanol extract of FE effectively suppressed melanin contents at a dose of 100 μg/ml. It was observed that the color of cell pellets was totally whitened compared with the control. The ethanol extract of FE inhibited tyrosinase activity, regulate melanin biosynthesis as the key enzyme in melanogenesis. These results suggest that the ethanol extract of FE exerts its depigmenting effects through the suppression of tyrosinase activity. And it may be a potent depigmetation agent in hyperpigmentation condition.
Purpose – It suggests that making a policy and strategies for a way of Dubai has a strong priority strategy on science and technology by using much oil dollars to prepare risk when oil dollar’s decrease. This has been now investigated how the leading innovator has changed the periphery countries.
Research design, data, and methodology – Analyze policy, status, what other neighbouring Middle East countries also want to benchmark a successful case of a leading Dubai strategy. Higher manpower is needed absolutely to develop S&T. and etc. Dubai and Arab countries establish university to nurture as well as invite the talented manpower from overseas to recover deficient manpower. Dubai built totally academy city and invited branch of the overseas famous university, and Saudi Arabia built university(KAUST) and invite faculty and support good scholarship for students. Abrab countries especially, This is studied the process of differentiating and integrating the migrant workers of these cities into the globalized cities. This has resulted in large-scale employment for foreign and local companies in these cities and the spread of science and innovation.
Results – Dubai supports venture or SMEs by using a strong priority strategy and attracts foreigner’s investor, with which the neighbouring countries have been preparing together for 4th wave. It demonstrates that the gravitational model has been activated from neighboring countries of innovation science to create Dubai‘s hub. The maturity of long-term urban innovation is related to innovation capability through the national response and review. As a result, the flow of skilled international migration has been localized because of the mutual intersection with the local employment structure, and the development has spread as it spreads to neighboring countries.
Conclusion – For the exploiting of new Distribution market in the neighbouring countries, Middle East countries’ a strong priority strategy on S&T and education system give an influence on economic situation of the 4th wave in the world and world order of leading by USA, Japan, or EU, and etc. This is due to the creation of clusters in the form of SEZs, friendly industrial policies and world-class infrastructure and innovation development. Its neighbours benchmark the cases of distribution of science innovation and centralizes the surrounding people.