HANARO, a multi-purpose research reactor, uses a reflector as heavy water to obtain high neutron flux. Therefore, two ion exchangers were installed to manage the heavy water quality of the reflector system. The operator of HANARO manages it according to the limit value (Conductivity: less than 0.5 mS/m, pH: 5.5~6.5), and if the limit value is not satisfied, the resin must be replaced. The reflector system is in the enclosed structure and it is designed to delay the release of tritium to the outside. Tritium is produced by a nuclear reaction between neutrons and deuterium. Tritium is inhaled into the body in the form of water or vapor, which is likely to cause internal exposure problem. In addition, since tritium spreads to other regions, thorough management is required. Therefore, HANARO measures and manages tritium in Rx and RCI using the bubbler collection method. In this paper, the change in the behavior of tritium due to the replacement of the reflector ion exchanger resin was analyzed. Due to the increase in conductivity of the reflector, the ion exchanger resin was replaced on March 3, 2022. Therefore, the concentration of tritium was measured to be about 5 times higher than usual. It did not exceed the emission limit, and the concentration values of tritium is stably managed by constant monitoring and analysis.
The purpose is to study the identification method of Huangjinju powder for injection and the medicinal materials by the fingerprint off-ray Diffraction Fourier (XRDF). We used the same method on both the studying of Huangjinju and the medicinal materials. Then we selected a few components alignment to compare. We analyzed the data by setting up the deviation d(a) as ±0.05 to calculate the rate of special mark on the sample (Px) and on the patent (P). The special XRDF of Huangjinju[d(a)/(I/I0)] have 5 peaks that have not expressed in medicinal materials. Therefore Px is 22.73%. Flos Trollii Chinensis has 3 special marks and Px is 17.65%. Flos Chrysanthemi Indici has 1 special mark and Px is 3.57%. Its coincided interplanar spacing with the patent is 2.907a. Flos Lonicerae Japonicae has 6 special marks and Px is 23.08%. Its special mark in the patent are 4.95/14 and 4.50/15, respectively. The P is 9.09%. Its coincided interplanar spacing with the patent is 2.910a and 3.05a, respectively. The number of special XRDF mark peaks of baicalin is 9 and Px is 18.37%. Its coincided interplanar spacing with the patent is 2.910a. It has visible mark and specificity adopting XRDF fingerprint to identify Huangjinju and medicinal materials. Establishing the quality standard is a synthetic index that depends both on special marks in the medicinal materials of the patent and on the coincidence peak data.