To address the pressing societal concern in Korea, characterized by the imminent saturation of spent nuclear fuel storage, this study was undertaken to validate the fundamental reprocessing process capable of substantially mitigating the accumulation of spent nuclear fuel. Reprocessing is divided into dry processing (pyro-processing) and wet reprocessing (PUREX). Within this context, the primary focus of this research is to elucidate the foundational principles of PUREX (Plutonium Uranium Redox Extraction). Specifically, the central objective is to elucidate the interaction between uranium (U) and plutonium (Pu) utilizing an organic phase consisting of tributyl phosphate (TBP) and dodecane. The objective was to comprehensively understand the role of HNO3 in the PUREX (Plutonium Uranium Redox Extraction) process by subjecting organic phases mixed with TBPdodecane to various HNO3 concentrations (0.1 M, 1.0 M, 5.0 M). Subsequently, the introduction of Strontium (Sr-85) and Europium (Eu-152) stock solutions was carried out to simulate the presence of fission products typically contented in the spent nuclear fuel. When the operation proceeds, the complex structure takes the following form. 􀜷􀜱􀬶 􀬶􀬾(􀜽􀝍) + 2􀜰􀜱􀬷 􀬿(􀜽􀝍) + 2􀜶􀜤􀜲(􀝋􀝎􀝃) ↔ 􀜷􀜱􀬶(􀜰􀜱􀬷)􀬶 ∙ 2􀜶􀜤􀜲(􀝋􀝎􀝃) Subsequently, separate samples were gathered from both the organic and aqueous phases for the quantification of gamma-rays and alpha particles. Alpha particle measurements were conducted utilizing the Liquid Scintillation Counter (LSC) system, while gamma-ray measurements were carried out using the High-Purity Germanium Detector (HPGe). The distribution ratio for U, Eu (Eu-152), and Sr (Sr-84) was ascertained by quantifying their activity through LSC and HPGe. Through the experiments conducted within this program, we have gained a comprehensive understanding of the selective solvent extraction of actinides. Specifically, uranium has been effectively separated from the aqueous phase into the organic phase using a combination of tributyl phosphate (TBP) and dodecane. Subsequently, samples containing U(VI), Eu(III), and Sr(II) underwent thorough analysis utilizing LSC and HPGe detectors. Our radiation measurements have firmly established that the concentration of nitric acid enhances the selective separation of uranium within the process.

Due to the saturation of spent fuel pool of nuclear power plant in Korea, temporary storage for spent fuel will be installed, and spent fuel will be stored and managed in dry cask for a considerable period of time. Since spent nuclear fuel must withstand continuous decay heat, radiation and high internal pressure of the fuel rod in the cask, behavior of spent nuclear fuel is needed to be reviewed. Spent nuclear fuel used in Pressurized Water Reactor (PWR) in Korea is stored in a wet storage currently, but it is going to store a temporary dry-storage facility on Kori site. Therefore, it is very important and meaningful to evaluate the behavior of nuclear fuel with realistic modeling. Also, domestic PWR nuclear fuel has various burn-up. In the past, the burn-up of nuclear fuel in light water reactors was low, but in order to increase power generation efficiency, the concentration of uranium was increased and the number of new fuel was increased. Therefore, a large amount of nuclear fuel with burn-up of 45,000 MWD/MTU or higher, generally called high burn-up, is also stored in the spent fuel pool (SFP). Therefore, it is necessary to evaluate by dividing three different burn-up such as, low, medium, and high burn-up. Thus, this study will review the behavior of nuclear fuel at different burn-up during the temporary storage period with FALCON (EPRI), computational code and analyze the factors affecting the integrity of nuclear fuel, including when the temporary storage is extended its additional lifetime. And this evaluation will contribute developing the spent fuel management plan in Korea.

To broaden the utilization of nuclear energy, uranium as a fuel should be mined indispensably. Mining accounts for the largest portion of the cost of producing the uranium assembly. Therefore, this study analyzes the trends of uranium prices, which have a significant impacts on the mining cost. Uranium production contributing to the price fluctuations is explained in five periods from 1945 to the present. Moreover, the series of events affecting uranium prices from the 1970s until the present are verified. Among them, the most recent incidents considered in this study are the following: COVID-19 pandemic, Kazakhstan unrest, and Russia-Ukraine war. European countries have started to reconsider the transition to nuclear power to reduce their dependence on Russian oil and gas, which has contributed to the surge in uranium prices. Based on the results of this study, various international issues have been closely associated with the nuclear power industry and uranium, affecting the production of uranium and its price.

The current storage capacity of the spent nuclear fuel at the Kori unit 2 has reached approximately 94% saturation, excluding emergency core capacity. As South Korea has not yet constructed any interim storage facilities to store spent nuclear fuel, one of possible options is to install high density storage racks in spent fuel pool at the reactor site to increase its capacity. The high density storage rack is a technology developed to allow the storage to have more spent nuclear fuel than originally planned, while still ensuring safety. It achieves this by reducing the storage gap between the spent nuclear fuel. The purpose of this study is to investigate an appropriate storage capacity for spent fuel pool in the Kori unit 2 and the factors to be considered during the high density storage rack installation. Given that the Kori unit 2 is planning continued operation and Korea Hydro & Nuclear Power (KHNP) is preparing to install a temporary storage facility for spent nuclear fuel at the Kori nuclear site, it is reasonable to consider the installation of high density storage racks in the spent fuel pool as a storage solution for these issues. When evaluating the capacity of the spent fuel pool, the amount of spent nuclear fuel generated by other reactors in Kori nuclear site and the amount of spent nuclear fuel generated by continued operation of the Kori unit 2 should be taken into account. This study aims to consider these factors and evaluate the capacity of the spent fuel pool. Furthermore, when installing high density storage rack for the spent nuclear fuel, it should be noted that the existing storage racks at the Kori unit 2 are welded to the liner plate, which may require additional cutting work. Therefore, it is necessary to review the suitable method for the cutting work. Additionally, assuming that divers need to access the area near the storage racks or cutting & welding devices require radiation protection in the area, it is essential to analyze the expected radiation level with computational code and propose appropriate measures to limit work time or establish a work zone. Thus, this study evaluates appropriate capacity of spent fuel pool and work methods for the installation of high density storage rack in the spent fuel pool at the Kori unit 2. It is expected that this paper contributes to install high density storage racks in SFP safely.

The design of nuclear fuel storage and handling area includes the activities related to the storage and inspection before fuel loading, transfer into the reactor, removal of irradiated fuel to the spent fuel storage rack, underwater handling and storage, and handling into a shipping cask. The purpose of this study is to provide the design requirements for the spent fuel pool to be prevented from the loss of cooling water and for heavy load control to prevent any load drop resulting in damage to safetyrelated systems during heavy load handling in accordance with the regulatory guidelines. And another purpose is to review the sizing of minimum wet storage capacity in the spent fuel pool based on the maximum refueling batch from the core during refueling plus a full core off-load of fuel assemblies and the minimum discharge burnup spent fuel storage during the design life of plant requested by the utility. As the results of this study, the current general arrangement for the spent fuel storage and handling area and the minimum storage capacity are evaluated. These can be good recommendations to enhance more safe and efficient if implemented to the new nuclear power plants.

This study provides technical information about the nuclear fuel handling process, which consists of various subprocesses starting from new fuel receipt to spent fuel shipment at a nuclear power plant and the design requirements of fuel handling equipment. The fuel handling system is an integrated system of equipment, tools, and procedures that allow refueling, handling and storage of fuel assemblies, which comprise the fuel handling process. The understanding and reaffirming of detailed code requirements are requested for application to the design of the fuel handling and storage facility. We reviewed the design requirements of the fuel handling equipment for its adequate cooling, prevention of criticality, its operability and maintainability, and for the prevention of fuel damage and radiological release. Furthermore, we discussed additional technical issues related to upgrading the current code requirements based on the modification of the fuel handling equipment. The suggested information provided in this paper would be beneficial to enhance the safety and the reliability of the fuel handling equipment during the handling of new and spent fuel.