Graphene oxide/Iron III oxide (GO: Fe2O3) nanocomposites (NCs) have been topical in recent times owing to the enhanced properties they exhibit. GO acting as a graphene derivative has demonstrated superior features as obtainable in a graphene sheet. Furthermore, the attachment of oxygen functional groups at its basal and edge planes of graphene has allowed for easy metal/oxide functionalization for improved properties harvesting. Fe2O3 nanoparticles (NPs) on the other hand have polymorphic property enabling the degeneracy of Fe2O3 in different phases, thereby resulting in different physical and crystalline properties when used to functionalize GO. The properties of GO: Fe2O3 have been applied to supercapacitor energy harvesting, Li-ion batteries, and biomedicine. The enhanced properties are attributed to the adsorption and electronic structure properties of Fe atoms. In this review, the various synthesis used in the preparation of reduced/graphene oxide: Fe2O3 is discussed. As indicated in the considered literature, the XPS analysis suggests electronic bond interactions between C–C, C–O, C–Fe and Fe–C. The available report on UPS measurements further suggests the formation of mixed states emanating from and bonds. The discussed reports further suggest that the various applications based on the harvesting of electronic, electrical, and magnetic properties are due to the ionic and exchange interactions between the different orbital states of carbon, oxygen and iron. The challenges and future prospects of the synthesis and application of GO/Fe2O3 are examined. Graphical abstract showing the process of exfoliation, reduction and functionalization of graphite to produce reduced graphene oxide (rGO).
Generation Y is becoming important to marketers. Since this consumer is disloyal, more value has to be offered to him. This value can be generated through “coolness” of a brand. By means of a mixed-method approach the German Generation Y consumer is characterized and his perception of cool brands elaborated.
is an extremely high alloyed PM material containing about 20 to 35 wt.% titanium based carbides. Such materials are designed to achieve a high wear resistance, but the high volume fraction of hard phases causes a comparable low ductility in case of tensile loading. In the present study the mechanical properties of different Ferro-Titanit grades (variations in chemical composition and in heat treatment) were investigated by means of tensile tests. The mechanical properties and the fracture behaviour will be related to the chemical composition, the heat treatment and the microstructure.