The coating of conductive polypyrrole (Ppy) on nonconductive ceramic substrates was performed by polymerization of pyrrole (Py) in an aqueous solution. The Ppy film was characterized by scanning electron microscopy and conductivity measurements. Electrophoretic deposition of bimodal alumina suspension prepared with a phosphate ester was performed using Ppy film as a cathode. Fabrication of alumina ceramics with irregular shapes or complicated patterns were also attempted by sintering the deposits together with the Ppy coated substrates in air.
The mechanical properties of ceramics materials can be tailored by designing their microstructures. We have reported that development of texture can be controlled by slip casting in a strong magnetic field followed by heating even for diamagnetic ceramics such as alumina. A strong magnetic field of 12T was applied to the suspension indcuding alumina powder to rotate each particle during slip casting. The sintering was conducted at the desired temperature in air without a magnetic field. C-axis of alumina was parallel to the magnetic field. Bending strength of textured alumina depended on the direction of oriented microstructure.
We have demonstrated that textured nanocomposites can be fabricated by slip casting followed by partial oxidation. reaction sintering of mixed suspensions of and SiC powders in a high magnetic field. The sintered density was changed by the degree of oxidation at 1200C and 1300C. The degree of orientation of alumina in the nanocomposite was examined on the basis of the X-ray diffraction patterns and scanning electron micrographs. It is confirmed that aluminaoriented nanocomposites were fabricated. The three-point bending strength at room temperature was observed for the nanocomposites.
We have demonstrated that textured nanocomposites can be fabricated by slip casting followed by partial oxidation - reaction sintering of mixed suspensions of and SiC powders in a high magnetic field. The sintered density was changed by the degree of oxidation at 1200C and 1300C. The degree of orientation of alumina in the nanocomposite was examined on the basis of the X-ray diffraction patterns and scanning electron micrographs. It is confirmed that alumina-oriented nanocomposites were fabricated. The three-point bending strength at room temperature was observed for the nanocomposites.