급냉응고방식으로 제조한 비정질 Z r62-xN i10C u20A l8 Tix (x=3, 6, 9at%) 합금을 사용하여 열적, 기계적 성질을 조사하였다. 시효온도에 따른 결정화 거동은 Ti 3at%에서는 비정질→비정질+Z r2A l3+Zr+(Ni,Ti)→Z r2Cu+Al+(Ni,Ti)의 결정화 거동을 나타내었으며, Ti 6at%에서는 비정질→비정질+Al→A l2Ti+NiZr+CuTi, Ti 9at%에서는 비정질→비정질+Zr+Al→Zr+A l2Zr+Al Ti3+CuTi의 결정화 거동을 보였다. 시효온도가 증가할수록 비정질 모상에 석출상의 체적율( Vf )이 증가하고 그에 따라 비커스 경도 ( Hv )간이 증가하였다. 파괴인장강도(σf )는 Vf 의 증가에 따라 증가하다가 Z r59A l10N i20C u8 Ti3은 Vf =38%에서 1219MPa의 최대값을 보이고, Z r56A l10N i20C u8 Ti6은 Vf =2%에서 1203MPa의 최대값을 보이고, Z r53A l10N i20C u8 Ti9 Vf =5%에서 1350MPa의 최대값을 나타낸 후 그 이상의 Vf 에서는 급격히 감소하였다. σf 가 급격히 감소하는 Vf 와 연성 파면에서 취성파면으로 천이되는 Vf 가 일치하였다.f/가 일치하였다.

Ti-50Ni(at%) and Ti-40Ni-10Cu(at%) alloy powders have been fabricated by ball milling method, and their microstructure and phase transformation behavior were investigated by means of scanning electron microscopy/energy dispersive spectrometry, differential scanning calorimetry (DSC), X-ray diffractions and transmission electron microscopy. In order to investigate the effect of ball milling conditions on transformation behavior, ball milling speed and time were varied. Ti-50Ni alloy powders fabricated with the milling speed more than 250 rpm were amorphous, while those done with the milling speed of 100rpm were crystalline. In contrast to Ti-50Ni alloy powders, Ti-40Ni-10Cu alloy powders were crystalline, irrespective of ball milling conditions. DSC peaks corresponding to martensitic transformation were almost discernable in alloy powders fabricated with the milling speed more than 250 rpm, while those were seen clearly in alloy powders fabricated with the milling speed of 100 rpm. This was attributed to the fact that a strain energy introduced during ball milling suppressed martensitic transformation.

Ti-Ni-Cu alloy powders were fabricated by ball milling, and the properties of these powders were characterized. Mixed 50Ti-(50-x)Ni-xCu powders of 5 to 10at.%Cu composition were milled for 100 hours using SUS 1/4" balls in argon atmosphere. Ball to powder ratio was 20:1 and rotating speed was 100 rpm. Tensile strength, microstructure and phase transformation of ball milled Ti-(50-x)Ni-xCu powders were studied. After 100 hours milling, Ti, Ni and Cu elements were alloyed completely and an amorphous phase was formed. Amorphous phase was crystallized to martensite(B 19') and austenite(B2) after heat treatment for 1 hour at . As the Cu contents were increased, tensile strength of extruded 6061Al/TiNiCu was decreased, and B19'martensite phases In the TiNi particles were the causes of high tensile stress of extruded 6061Al/TiNiCu.NiCu.

Ti-45.2at.%Ni-5at.%Cu and Ti-40.2at.%Ni-10atat.%Cu alloy powders were fabricated by gas atomization process. The microstructures, Shape, hardness and phase transformation behaviors of the powders were investigated by means of optical microscopy, scanning electron microscopy, micro-hardness measurement, x-ray diffraction analyses and differential scanning calorimetry. The hardness of the Ti-Ni-XCu alloy powders decreased as Cu-content increased. The x-ray diffraction analyses were carried out for powders without heat treatment, and those that treated at 85 for an hour in a vaccum state( torr) and then quenched into ice water. The intensity of B phase increased with heat treating. The monoclinic B martensite was formed in the Ti-Ni-XCu alloy powders during cooling.

In this work, we prepared a heterojunction anode with a surface layer of SnO2-Sb-Ni (SSN) on a Ti/IrO2 electrode by thermal decomposition to improve the electrochemical activity of the Ti/IrO2 electrode. The Ti/IrO2-SSN electrode showed significantly improved electrochemical activity compared with Ti/IrO2. For the 0.1 M NaCl and 0.1 M Na2SO4 electrolytes, the onset potential of the Ti/IrO2-SSN electrode shifted in the positive direction by 0.1 VSCE and 0.4 VSCE, respectively. In 2.0-2.5 V voltages, the concentration in Ti/IrO2-SSN was 2.59-214.6 mg/L Cl2, and Ti/IrO2 was 0.55-49.21 mg/L Cl2. Moreover, the generation of the reactive chlorine species and degradation of Eosin-Y increased by 3.79-7.60 times and 1.06-2.15 times compared with that of Ti/IrO2. Among these voltages, the generation of the reactive chlorine species and degradation of Eosin-Y were the most improved at 2.25 V. Accordingly, in the Ti/IrO2-SSN electrode, it can be assumed that the competitive reaction between chlorine ion oxidation and water oxidation is minimized at an applied voltage of 2.25V.