Supercross-linked polymers are widely used as carbon precursor materials due to their abundant carbon sources and low cost. In this paper, a supercross-linked polymer was prepared by the solvothermal method. The supercross-linked polymer as a precursor and the PPyC-800-A was synthesized by activating this with KOH. The microstructure, structure, and electrochemical performances of porous carbon PPyC-800-A were studied at different of temperature and carbon alkali ratio. According to the results, the porous carbon PPyC-800-1:2 is mainly composed of a stack of spherical particles with a high surface area of 1427.03 m2 g− 1, an average pore diameter of 2.32 nm, and a high specific capacitance of 217.7 F g− 1 at a current density of 1.0 A g− 1 in a 6 M KOH electrolyte. It’s retention rate is 97.58% after 5000 constant current charges and discharges. With a specific capacitance decay rate of 21.91 percent, an energy density of 11.96 Wh kg− 1, and a power density of 500.0 W kg− 1, the current density rises from 1.0 A g− 1 to 10.0 A g− 1, exhibiting remarkable electrochemical properties, cycling stability, and energy production performance This study contributes experimental ideas to the field of supercrosslinked polymer-derived carbon materials and energy storage.

Carbon nanodots (CNDs) are 0D quasi-spherical nanoparticles that are less than 10 nm in size. CNDs that possess surface functional groups such as hydroxyl, amino, and carboxyl groups have been demonstrated to scavenge free radicals efficiently and effectively, resulting in them being beneficial for cosmetic and cosmeceutical applications. In this study, we successfully prepared novel CNDs, namely black VC, using vitamin C (VC) as a promising precursor. Black VC was prepared by a facile one-step method based on short-time microwave irradiation. The properties of black VC were characterized by transmission electron microscopy (TEM) analysis, X-ray diffraction (XRD), high-resolution X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, and UV–vis spectrophotometry. Radical scavenging, cell viability, and anti-pollution activity assays were also conducted to demonstrate the functionalities of black VC. The developed black VC exhibited lower cytotoxicity and better antioxidant, metal chelating ability, and anti-pollution activities than its precursor. These results provide a new approach for developing advanced antioxidants for innovative cosmetic formulations using a simple microwave treatment method. However, black VC retained some problems of its precursor in the form of low stability, which is likely to be a challenge for its cosmeceutical application.

This experiment was conducted to confirm the possibility of preparing Sorghum×sudangrass hybrid artificial hay using far-infrared rays in Korea. The machine used in this experiment is a drying device based on far-infrared rays, and is designed to control temperature, air flow rate, far-infrared radiation amount, and air flow speed. The Sorghum×sudangrass hybrids harvested in late September were wilted in the field for one day, and a drying test was performed on them. Conditions for drying were performed by selecting a total of 7 conditions, and each condition induced a change in radiation amount in a single condition (42%) and two steps (4 treatments) and three steps (2 treatments). The speed of the air flow in the device was fixed at 60 m/s, and the run time was changed to 30, 60, and 90 minutes. The average dry matter (DM) content was 82.84%. The DM content was 59.94 and 76.91%, respectively, in drying conditions 1 and 3, which were not suitable for hay. In terms of drying rate, it was significantly higher than 80% in the 5, 6 and 7 treatment, and power consumption was slightly high with an average of 5.7 kw/h. As for the feed value according to each drying condition, the crude protein (CP) content increased as the drying time increased, and there was no significant difference between treatments in ADF, NDF, IVDMD and TDN content. In terms of RFV, treatment 1, which is a single condition, was significantly lower than the complex condition. Through the above results, it was determined that the drying conditions 4 and 5 were the most advantageous when considering the drying speed, power consumption, and quality.

Cracks are an inevitable problem during the use of materials, and flexible sensors with self-healing capability are of great importance for applications in wearable devices and skin-like electronic devices. This paper prepared self-healing flexible strain sensors by compounding self-healing polyurethane with carbon nanotubes. First, by changing the ratio of disulfide bonds, a good balance between mechanical properties and self-healing efficiency was achieved in the prepared self-healing polyurethane. The most balanced sample reached 12.28 MPa in tensile strength, after 24 h of self-repair at 30 °C, the tensile strength was 7.75 MPa, and the self-repair efficiency was 63.11%; after 24 h of self-repair at 80 °C, the tensile strength was 11.64 MPa, and the self-repair efficiency reached 94.79%. Then the sensors prepared by compounding with carbon nanotubes showed a good electrochemical response, and both slow and fast repeated bending of the finger wearing the sensors yielded significantly different electrical signal changes, and the sensors were cut off and still had the same function after self-repair at 30 °C, demonstrating their excellent potential for applications in soft robots, wearable devices, etc.

본 연구는 간호대학생을 대상으로 강점인식과 셀프리더십이 진로준비행동에 미치는 영향을 규 명하기 위하여 시행된 서술적 조사연구로 G시의 간호학과 학생을 대상으로 하였다. 자료의 분석을 위해 기 술적 통계, t검증, ANOVA, Pearson 상관계수, 통제적 회귀분석을 실시하였다. 연구결과는 다음과 같다. 강점인식(β=.464, p<.001)과 셀프리더십(β=.512, p<.001) 모두 진로준비행동에 정적인 영향을 나타냈으 며, 연구모형은 진로준비행동을 34.1% 설명하는 것으로 확인되었다. 이러한 연구 결과는 간호대학생의 진 로준비행동 증진을 위해 감정인식과 셀프리더십을 증진시키기 위한 방안들이 필요함을 시사한다.

N-doped Na2Ti6O13@TiO2 (denoted as N-NTO@TiO2) composites are successfully synthesized using a simple two-step process: 1) ball-milling of TiO2 with Na2CO3 followed by heat treatment at 900oC; 2) mixing of the prepared Na2Ti6O13 with titanium isopropoxide and calcining with urea at 500oC. The prepared composites are characterized using XRD, SEM, TEM, FTIR, and BET. The N-NTO@TiO2 composites exhibit well-defined crystalline and anatase TiO2 with exposed {101} facets on the external surface. Moreover, dopant N atoms are uniformly distributed over a relatively large area in the lattice of the composites. Under visible light irradiation, ~51% of the aqueous methylene blue is photodegraded by N-NTO@TiO2 composites, which is higher than the values shown by other samples because of the coupling effects of the hybridization of NTO and TiO2, N-doping, and presence of anatase TiO2 with exposed {101} facets.

본 시험은 우리나라에서 원적외선을 이용한 이탈리안 라이그 라스 인공건초 조제 가능성을 확인하기 위해 수행되었다. 본 시험 에 사용된 기계는 온도, 송풍량, 원적외선 방사량을 조절할 수 있 는 원적외선 건조기로 5월에 수확한 이탈리안 라이그라스를 대상 으로 실시하였다. 건조를 위한 조건은 전체 9개의 조건을 선택하 여 수행하였으며 각각의 조건은 방사율 42∼45 %로 설정을 하였 으며 내부 온도는 65℃로 설정하였다. 기기내의 기류의 속도는 40 ∼60m/s로 하였으며, 전체적인 건조시간은 방사량 42%는 30분, 43%는 25분 그리고 45%는 20분으로 하여 수행하였다. 각각의 건조조건에 따른 최종 건물함량은 평균 88.5%로 나타났으며 전 처리에서 건초에 적합한 건물함량을 나타내었다. 건조 조건에 따 른 전력 소비량을 보면 45% 방사량에서 20분간을 건조한 처리구 에서 가장 낮게 나타났다. 건조율에 있어서는 1∼5번 건조 조건에 서는 차이가 없었으나 6∼7조건에서는 유의적으로 낮은 경향을 보였다. 사료가치에 있어서는 대부분의 건조조건에서 원물보다 CP, IVDMD는 높았고 ADF, NDF 함량은 낮게 나타났으며 대체 적으로 4, 7 및 8번 건조 조건에서 높은 경향을 보였다. 이상의 결과를 통하여 건조속도, 전력량, 품질 등을 고려할 때 7 및 8번 건조조건이 가장 유리한 것으로 판단되었다.

목적 : 반응성 청색광차단 염료를 하이드로겔 콘택트렌즈에 화학적으로 고정시켰고, 제조된 콘택트렌즈의 청색 광차단 기능의 분석 및 첨가된 염료를 정량하고자 한다. 방법 : Vinyl sulfone-기반의 반응성 염료인 Reactive Orange 16 Dye를 다량의 알콜 작용기를 함유하는 하 이드로겔 콘택트렌즈에 화학적으로 결합시켰다. 콘택트렌즈의 청색광차단 특성 및 염료의 정량은 UV-vis spectrophotometer를 이용하여 확인하였다. 결과 : 청색광차단기능의 Reactive Orange 16 Dye가 성공적으로 하이드로겔 콘택트렌즈에 결합되었다. UV-vis spectra 분석을 통해 염료를 함유한 콘택트렌즈들이 우수한 청색광차단 기능을 보임을 확인하였다. Beer-Lambert의 법칙을 이용하여, 콘택트렌즈에 첨가된 Reactive Orange 16 Dye를 정량하였으며, 반응 염료 의 농도 조절을 통해, 콘택트렌즈의 청색광차단율을 조절할 수 있었다. 결론 : 본 연구에서는 청색광차단 기능의 반응성 염료를 하이드로겔 콘택트렌즈에 화학적 결합을 통해 고정시 키고, 청색광차단 기능을 분석하였다. 화학적 반응에서 청색광차단 염료의 농도가 증가할수록, 380~500 nm 사 이의 청색광 파장 영역에서의 차단 세기와 첨가된 염료의 양이 같이 증가함을 확인하였다. 대량생산이 가능한 청 색광차단 콘택트렌즈의 개발은 기능성 안광학의료기기 개발에 큰 역할을 할 것으로 기대된다.