The waste secondary battery contains a significant amount of valuable metals, making its recycling highly desirable. However, conventional chemical methods for recycling are environmentally unfriendly and cost-ineffective. Rather than the chemical method, this paper deals with a mechanical method for recovering electrode materials from waste secondary batteries by blowing pressurized air onto the interface area between the electrode and the separator. Especially, in this study, the effective blowing angle were searched by simulating the separation of the electrode material from the separator through 1-way fluid structure interaction analysis based on the Cohesive Zone Modeling technique.
본 연구에서는 분리막 생물반응기(membrane bioreactor, MBR)에서 발생되는 생물막오염 완화에 탁월한 효과를 가진 분리막을 개발할 목적으로, 친수성 산소 기능기가 많은 탄소나노구체(carbon nanosphere, CNS)를 합성한 뒤, 이를 첨가 제로 활용하여 친수성과 다공성 기공 구조를 갖는 고성능 한외여과막을 제조하였다. CNS는 막 표면에 초승달 모양의 기공을 형성하였고, CNS 함량을 4.6 wt%까지 증가시킴에 따라 최대기공 크기보다 큰 결함을 야기하지 않으면서 평균 표면 기공 크 기를 약 40% 증가시키는 것으로 나타났다. 또한, CNS 복합막의 다공성 기공 구조는 CNS의 등방성 형태와 상대적으로 낮은 입자 수밀도 덕분에 CNS 첨가에 따른 고분자 용액의 점도 급등이 방지됐기 때문이라고 판단된다. 그러나 너무 다공성이 커 지게 되면 기계적 물성이 저하되므로, 기공구조와 기계적 성질을 포함한 종합적인 고려를 했을 때 CNS2.3이 가장 우수하다 고 관측되었다. CNS2.3은 CNS0에 비해 수투과도가 2배 이상 높을 뿐만 아니라, MBR 공정에서 분리막 세정이 요구될 때까 지의 운전 시간도 5배 이상 연장시킨 것으로 확인되었다.
In this paper, among the various facilities used in marine farming, young bivalves of the Mytilus galloprovincialis of marine farming was placed on the deck of the fishing vessel to evaluate the environment conditions and drive shaft movement by rolling affecting the separator for the young bivalves and a clean process. There were a few studies on stress analysis of development facilities because it was difficult to access the fishing site due to the use of imported equipment and the lack of development of domestic equipment. In this study, stress analysis of the fixed part of separator for young bivalves and its adjacent part was performed on various phases when the vessel was tilted by rolling using the finite element method. In addition, the structural safety of the internal blade under the driving conditions according to the movement of the drive shaft by the hydraulic motor was confirmed through structural analysis. As a result, the connection part between the deck and the separator by rolling was confirmed to have higher stress than that of other parts due to stress concentration. In addition, it was confirmed that the maximum stress occurred on the connection part between blades. Even though the safety of the separator for marine farming was confirmed by structural analysis, it is necessary to comprehensively consider the age of vessels, the material of the deck, and the corrosion of the deck.
This study focuses on heat-induced gelation of pea (Pisum sativum L.) proteins to assess the potential of pea protein aggregates (PPA) as novel plant-based meat alternatives. The microstructural (SEM, CLSM), mechanical (TPA analysis), and rheological properties (G', G'') of heat-induced gels at pH 2 were systematically investigated as a function of a different pea protein concentration (7.5, 10, 12.5%) and a varying heating time (1, 3, 6, 16 h). The result showed that PPA formation at higher protein concentration and heating time contributed to a homogenous and compact heat-induced gel formation. Such gel network strengthened mechanical properties in terms of high gel hardness (40 g) and elastic texture (2.7 mm springiness). For the rheological studies, the storage modulus (G') showed an increase during both the heating and cooling phases and then stabilized during the cooled-holding phase. This suggested that the formation of durable and stable gel was induced due to the decreased mobility of protein aggregates at low temperatures. Therefore, the PPA is indicated as a potential additive for enhancing the food texture quality in the plant-based meat food industry.
공유결합 유기 구조체(COF)의 한 가지로서, 공유결합 트리아진 구조체(CTF)는 이온 열 삼량 체화 반응을 통해 제조된 반복되는 육각형 트리아진 고리의 네트워크로 구성되어 본질적으로 다공성 구조를 가진다. 또한 일부 화학 물질에 대한 친화성을 높이고 다른 화학 물질을 배제하는 많은 질소 작용기를 포함한다. 조절 가능한 특성 때문에 많은 연구자들이 기체 및 액체 분리 공정을 위한 CTF의 소재를 합성하고 테스트했다. 새로운 CTF, 혼합 CTF 복합재 및 CTF 멤브레인에 대한 다양한 연구가 기체흡착, 기체분리(예 : CO2, C2H2, H2 등) 및 담수화에 대해 연구되었다. 일부 CTF 연구는 고급 컴퓨터 시뮬레이션을 통해 한계와 잠재력을 결정했으며 후속 실험에서는 광촉매 특성에 대한 CTF를 테스트하여 더 큰 지속 가능성을 위한 재활용 가능성을 제안했다. 이 총설에서는 공유결합 트리아진 구조체 기반 분리막에 대해 설명할 예정이다.