막 분리 운전방식에 따른 음폐수 소화가스의 도시가스용 바이오메탄 생산연구를 상업용 시설을 대상으로 수행하였다. 연구결과 바이오메탄의 순도는 4SBR과 3SDR 모두 98.9%를 달성할 수 있었다. 소화가스 내 메탄 회수율은 4SBR 88.1%, 3SDR 79.4%이었고, 처리 소화가스량 대비 바이오메탄 생산율도 4SBR이 53.5%로 3SDR의 49.4%보다 높았다. 그러나 막 분리시설에 공급되는 가스 중 반송 가스의 비율은 4SBR이 56.5%로 3SDR 보다 두 배가량 컸으며, 이로 인해 최대 처리량에 있어서는 3SDR이 양호한 결과를 보였다. 따라서 소화가스 200 Nm3/day 이하는 4SBR, 240 Nm3/day 이상에서는 3SDR이 경제성이 좋은 것으로 판단되었다. 공정 운전변수들의 평균값 대비 운전 값들의 상대편차는 전반적으로 4SBR이 컸으며, 또한 주 운전조절 수단인 바이오메탄 인출압력 대비 주요 지표들의 상관관계에 있어서는 3SDR가 보다 직접적인 관계를 보여주었다.
Biogas is a gaseous mixture produced from the microbial digestion of organic materials in the absence of oxygen. Raw biogas, depending upon organic materials, digestion time and process conditions, contains about 45 ~ 75% methane, 30 ~ 50% carbon dioxide, 0.1% hydrogen sulfide gas, and a fractional percentage of water vapor. To achieve the standard composition of the biogas, treatment techniques like absorption or membrane separation are performed for the resourcing of biogas. In this paper, the experiments are performed using biogas produced in an environmental digestion facility for food waste. The membrane module was imported from overseas, its membrane process has achieved up to 98% of the methane and 99% of the carbon dioxide separated, and it has manufactured and stored pressurized carbon dioxide. The effects of the feed pressures on the separation of CO2-CH4 by the membrane are investigated. A chelate was utilized to purify the methane from the H2S concentration of 0.1%.
Biogas has been used to remove water content and hydrogen sulfide (H2S). Removing water requires a low temperature process; thus, our study investigated removing H2S under high pressure and low temperature. Several experiments were conducted to investigate removal of H2S from a biogas stream by optimizing chemical absorption and the chemical reaction with a Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance removal efficiency of H2S due to oxidization by Fe+3/EDTA. The objective of this study was to explore the feasibility of enhancing toxic gas treatment in a biogas facility. A biogas purification strategy affords many advantages. For example, the process can be performed under mild environmental conditions and at low temperature, and it removes H2S selectively. As the Fe-EDTA concentration increased, the H2S conversion rate increased because the Fe-EDTA complex was highly stable. The optimal pH to stabilize the chemical complex during oxidation of H2S was 9.0.
This study has cross checked the change of internal sludge-recycle in Anaerobic-Digestion, and researched about not only the improvement of Bio-gas production from the digested sludge but also the efficient method of sludge minimization. Ultimate object of the study is to reduce the amount of sludge by the improved efficiency of contact with the organic-matter and the microbes in Anaerobic-Digestion. The sludge-recycle fluidized sludge layer and raised the activity of the sludge, the optimal sludge-recycle ratio, VS and COD removal ratio were 1,000%, 28.2% and 27.7%, respectively. Through these results of this study, it may be of use to treat waste sludge by the sludge-recycle ratio in terms of minimization and circulation of resources.
The purpose of this study was to improve low digestibility in anaerobic digestion facility of the sewage treatment plant. To perform this research, sludge digestion and digestion gas purification facilities in sewage treatment plant was applied. In the result of this study, it was very effective for sludge reduction from the improvement of digestive efficiency. In addition, it was confirmed that high purity CH4 (methane) was produced. This results can be useful as basic data to improve the low digestibility in anaerobic digestion processes.