In this study, numerical analysis was performed on a type IV hydrogen storage tank to analyze the temperature change of hydrogen inside the tank and the filling performance by changing the inlet nozzle outlet angle and the number of outlets. Considering the residual state of charge (SOC) inside the initial tank, the initial pressure was 10 MPa, and the temperature of hydrogen inside the tank and the SOC results were analyzed when hydrogen with a temperature of 233 K was introduced under the conditions of liner, wrap, and outside temperature of 298 K. The results of the analysis showed that the charging completion rate reached the charging limit pressure. The analysis showed that time of filling completion, when the filling limit pressure is reached, the SOC result is about 94% for all geometry change conditions, and the filling completion time increases by 5s as the number of outlets decreases. The temperature change of the wrap area at the end of filling is up to 3.6K, which shows that the outside air temperature has a negligible effect on the hydrogen temperature change inside the tank.

In this study, numerical analysis was performed for the purpose of analyzing the flow characteristics and performance according to the change in the inflow hydrogen temperature and differential pressure of the receptacle of the hydrogen charging system. The pressure distribution and turbulent kinetic energy in the filter area were analyzed by changing the outlet pressure condition under the inlet hydrogen temperature condition, and the flow velocity change at the outlet was compared and analyzed. As a result of the analysis, as the differential pressure decreased, the flow rate at the outlet of the receptacle decreased by up to about 70% at the 2.86 MPa condition compared to the 1.86 MPa condition, and the mass flow rate decreased by about 56.5% at the maximum. It was found that the standard CV performance was not satisfied when the differential pressure at the inlet and outlet was 1.12 MPa or less under the 363K temperature condition.

Due to global warming and environmental pollution, environmental regulations are getting stronger, and the International Maritime Organization announced regulations to reduce CO2 emissions in 2018. In order to respond to this, interest in hydrogen energy is growing, and research on liquid hydrogen is spotlighted for storage and transport of large amounts of hydrogen. Hydrogen reduces in volume to 1/800 when liquefied, but its boiling point is close to absolute zero(-253°C), and hydrogen embrittlement that penetrates other materials and weakens mechanical properties. In this study, the change of mechanical properties under cryogenic conditions (-196 degrees below zero) was confirmed after charging hydrogen into existing cryogenic materials (Stainless steel, High Manganese steel, 9% Nickel steel). In Part I, hydrogen was charged using an electrochemical method and quantitative evaluation was performed. In all four materials, as the changing time increased, the diffusible hydrogen concentration increased. After 24 hours charging, the hydrogen loading of 20 wppm in 9% Ni steel and 15 wppm in high-Mn steel was confirmed. In a follow-up study, we plan to study the effect of hydrogen charging by comparing the results of the mechanical properties test with the above results.

High strength sheet steels for automobile are seriously compromised by hydrogen embrittlement. This issue has been continuously studied, but the field of interest, which lies between microstructural characteristics and hydrogen behavior with hydrogen charging, has not yet been thoroughly investigated. This study was done to investigate the behavior of hydrogen according to the hydrogen volume fraction on 590MPa grade DP steels, which are developed under hydrogen charging conditions as high strength sheet steels for automobiles. The penetration depths and the mechanical properties, according to charging conditions, were investigated through the distribution of micro-hardness and the microstructural observation of the subsurface zone. It was found that the amount of hydrogen trapping in 590MPa DP steels was related to the austenite volume fraction. It was confirmed that the distribution of micro-hardnesses according to the depth of the subsurface zone under the free surface showed the relationship of the depth of the hydrogen saturation between the charging conditions.