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        검색결과 9

        1.
        2023.03 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Core–shell ZIFs wrapped CuO hybrid materials (CuO@ZIF-67(Co)) were designed, synthesized, characterized, and employed as peroxymonosulfate (PMS) activators to degrade methylene blue (MB). It demonstrated outstanding catalytic activity on account of the unique structure and the synergistic effect between CuO cores and ZIF-67(Co) shells, resulting in complete degradation of MB (10 mg/L) in 1 min. Reactive oxygen species (ROSs) research showed that both SO4 − and OH were responsible for the removal of MB. The synergistic activation mechanisms in the CuO@ZIF-67(Co)/PMS system were investigated, which mainly involved the effective electron transfer of CuO and ZIF-67(Co) for accelerating the cycle of CuII/ CuI and CoIII/ CoII. This study broadens the application of MOF-derived materials for wastewater treatment.
        4,500원
        2.
        2022.02 KCI 등재 구독 인증기관 무료, 개인회원 유료
        일상적인 화학제품들의 사용량이 증가함에 따라 사용되었던 염료 폐기물 처리 또한 중요한 환경 적인 문제로 대두되었다. 이러한 염료폐기물은 광촉매를 이용하여 분해시킬 수 있는데, 졸-겔 기술을 활용 하면 매우 비용 효율적으로 광촉매를 합성할 수 있다. 졸-겔 기술은 나노스케일의 막 형성에도 상당히 유 용하며 간단하게 다층구조를 형성할 수도 있다. 본 연구에서는 다양한 염료 분해에 효과가 있는 산화아연 (ZnO) 이용하여 다중 회전도포 방법으로 다층구조(3층, 5층)를 가진 ZnO 막을 형성하였다. 성능비교를 위해 단일 회전도포 방법에 의한 단층구조를 가진 ZnO 막을 대조군으로 준비하였다. X선 회절분석기 및 에너지 분산 X선 분광계를 이용하여 ZnO의 구조 및 원소분석을 수행하였고, 주사전자현미경을 통해 나노 선같은 표면형상을 관찰할 수 있었다. 추가적으로 UV-Vis 분광광도계를 활용하여 자외선의 흡수도를 측정 하였다. 5층구조를 가진 ZnO 막이 단층 구조를 가진 ZnO 막에 비해 모의 메틸렌 블루를 49% 더 많이 분해하였다. 결론적으로, 다층구조를 가진 ZnO 는 메틸렌블루 염료를 더욱 효과적으로 분해하는 광촉매로 써 유용하다는 알 수 있었다.
        4,000원
        3.
        2021.10 KCI 등재후보 구독 인증기관 무료, 개인회원 유료
        단순 침전법으로 제조한 CdZnS/ZnO 광촉매를 이용하여 가시광선하에서 메틸렌블루의 광분해 반응에 대한 연구를 수행하였다. X선 회절분석법과 UV-vis 확산반사 분광법 등을 이용하여 제조된 촉매들의 물리화학적 특성을 분석하였다. 그리고 CdZnS/ZnO 광촉매의 활성을 조사하고 CdS 및 TiO2와 비교 검토하였다. CdZnS/ZnO 광촉매는 자외선뿐만 아니라 400nm에서 600nm 범위의 가시광선 영역에 있어서도 우수한 광흡수 특성을 나타내었다. 가시광선하에서 메틸렌 블루의 광분해 반응에 대해서 CdZnS/ZnO 광촉매는 CdS 와 TiO2 보다 우수한 광촉매 활성을 나타내는 것을 알 수 있었다. 그리고 가시광선하에서의 메틸렌블루의 광분해 반응에는 광촉매 반응뿐만 아니라 감광반응도 관여하고 있음을 확인할 수 있었다.
        4,000원
        5.
        2014.06 구독 인증기관 무료, 개인회원 유료
        Trametes versicolor showed the ability of degrading synthetic dyes such as congo red (CR) and methylene blue (MB) in solid and liquid culture conditions. The T. versicolor strains isolated in Korea degraded MB more efficiently than CR, differently most of other white mushrooms known to have difficulties in degrading MB than other dyes. Thus the Koren strains of T. versicolor showed the commercial potential to be used for cleaning dye-contaminated region without any patent-related problem. The main enzyme responsible for dye deradation was laccase. The manganese peroxidase (MnP) was also detected and supposed to be involved in the degradation process of synthetic dyes. However, no lignin peroxidase (LiP) was detected from degradation process, indicating LiP is not the enzyme T. versicolor use to degrade CR and MB.
        4,000원
        6.
        2010.01 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        Methylene blue (MB) was degraded by TiO2 and ZnO deposited on an activated carbon fiber (ACF) surface under UV light. The ACF/TiO2 and ACF/ZnO composites were characterized by BET, SEM, XRD, and EDX. The BET surface area was related to the adsorption capacity for composites. The SEM results showed that titanium dioxide and zinc oxide are distributed on the ACF surface. The XRD results showed that the ACF/TiO2 and ACF/ZnO composites contained a unique anatase structure for TiO2 and a typical hexagonal phase for ZnO respectively. These EDX spectra showed the presence of peaks of Ti element on ACF/TiO2 composite and peaks of Zn element on the ACF/ZnO composite. The blank experiments for either illuminating the MB solution or the suspension containing ACF/TiO2 or ACF/ZnO in the dark showed that both illumination and the catalyst were necessary for the mineralization of organic dye. Additionally, the ACF/TiO2 composites proved to be efficient photocatalysts due to degradation of MB at higher reaction rates. The addition of an oxidant ([NH4]2S2O8) led to an increase of the degradation rate of MB for ACF/TiO2 and ACF/ZnO composites.
        4,000원
        7.
        2009.03 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        In this paper, non-treated ACF (Activated Carbon Fiber) /TiO2 and Zn-treated ACF/TiO2 were prepared. The prepared composites were characterized in terms of their structural crystallinity, elemental identification and photocatalytic activity. XRD patterns of the composites showed that the non-treated ACF/TiO2 composite contained only typical single and clear anatase forms while the Zn-treated ACF/TiO2 contained a mixed anatase and rutile phase with a unique ZnO peak. SEM results show that the titanium complex particles are uniformly distributed on and around the fiber and that the titanium complex particles are more regularly distributed on and around the ACF surfaces upon an increase of the ZnCl2 concentration. These EDX spectra show the presence of peaks from the C, O and Ti elements. Moreover, peaks of the Zn element were observed in the Zn-treated ACF/TiO2 composites. The prominent photocatalytic activity of the Zn-treated ACF/TiO2 can be attributed to the three different effects of photo-degradation: doping, absorptivity by an electron transfer, and adsorptivity of porous ACFs between the Zn-TiO2 and Zn-ACF.
        4,000원
        8.
        2006.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        The photocatalytic degradation of methylene blue(MB) was investigated using TiO2 as photocatalyst and UV radiation. TiO2 supported with activated carbon(AC) was prepared by SOL-GEL method and depended on several parameters such as the mass ratio of TiO2/AC, pH and experimental time. The presence of the anatase and rutile crystal phase was determined by XRD analyses of the prepared TiO2. The degradation of MB with TiO2/AC was about 20% higher than that of AC alone. A variation of photodegradation was negligible under UV radiation conditions ( ≥ 40W). It was experimentally showed that the photodegradation rate was increased with increasing the amount of photocatalyst. The optimal catalyst was prepared by impregmation of 5wt%-TiO2 with AC and was calcined at 300℃, and showed about 99% removal efficiency for 3hrs.
        4,000원
        9.
        2018.10 서비스 종료(열람 제한)
        Background : For the green approach of nanoparticles synthesizing, plant based technology has been considered as cost-effective and eco-friendly mass production. The oriental medicinal crop, Kalopanax septemlobus (Thunb.) Koidz. (Korean name: 음나무), the deciduous tree and a family of Araliaceae. Endemic tree of Asian countries, K. septemlobus being used for the treatment of various diseases. Phytochemicals of K. septemlobus such as polyphenols has highly probability of reducing agent for biosynthesizing nanoparticles. Methods and Results : In this study, we applied K. septemlobus ZnO nanoparticles (Ks-ZnO NPs) with procedures including green approach one-pot synthesis. For the characterization of nanoparticles, UV–Vis, FTIR, XRD, SEM and TEM were used. The formation of ZnO nanoparticles, the aurface plasmon resonance were observed at 372 ㎚ in UV-Vis spectroscopy. The presence of functional groups which as a capping agent and formation of ZnO nanoparticles were confirmed in FTIR result. The crystallization and morphology showed by XRD, TEM and SEM respectively. The photocatalytic activity of ZnO nanoparticles, was determined using Methylene blue (MB) dye degradation under UV irradiation (365 ㎚) which resulted rate constant is (−k) 0.1215 with 97.5% of degradation in 30 min. Conclusion : The result shows that phytochemicals in K. septemlobus extract have a potential as a reducing agent to form ZnO nanoparticles. The ZnO NPs are capable to degrade MB with in brief time.