주암호는 전라남도와 광주광역시에 약 1,180,000톤/일의 생활용수와 공업용수를 공급하는 상수원이다. 상수원수계의 생활하수, 축산폐수, 숙박업소, 식당 등 점오염원과 주거지, 농경지, 산림지역에서 우수와 함께 유출되는 비점오염원으로부터 발생하는 오염부하량으로 이들 상수원의 수질은 점점 악화되어 3급수로 전락할 우려가 높아지고 있다. 이들 상수원의 수질관리에 있어 중요한 인자의 파악과 인자들간 상호작용의 이해를 용이하게 해주는 수계수질관리 부분생태계모형을 제시하였으며 지리정보체계를 응용하여 수계의 점오염원과 비점오염원을 데이터베이스화하는 방법, 오염부하량 산출방법, 점원 및 비점오염원의 공간분석, 상수원 보호구역으로부터 완충구역분석, 위성자료 분석을통한 상수원 수계 토지이용분석과 비점오염원 부하량산출 응용 방법등을 연구하였다 분석결과 주암호수계의 BOD 부하량은 주거지. 생활하수, 축산폐수, 경작지, 식당이 차지하는 비율이 높으며 총질소 부하량은 경작지, 산림, 생활하수, 추간폐수가 높으며 그리고 총인 부하량은 생활하수, 축산폐수, 경작지가 높은 것으로 나타났다. 점오염원인 생활하수, 축산폐수, 식당 뿐만 아니라 비점오염원인 경작지도 수질오염에 상당한 영향을 미치고 있다.

Industrial emissions, mainly from industrial complexes, are important sources of ambient Volatile Organic Compounds (VOCs). Identification of the significant VOC sources from industrial complexes has practical significance for emission reduction. VOC samples were collected from July 2019 to June 2020. A Positive Matrix Factorization (PMF) receptor model was used to evaluate the VOC sources in the area. Four sources were identified by PMF analysis, including coating-1, coating-2, printing, and vehicle exhaust. The coating-1 source was revealed to have the highest contribution (41.5%), followed by coating-2 (23.9%), printing (23.1%), and vehicle exhaust (11.6%). The source showing the highest contribution was coating emissions, originating from the northwest to southwest of the sample site. It also relates to facilities that produce auto parts. The major components of VOC emissions from the coating facilities were toluene, m,p-xylene, ethylbenzene, o-xylene, and butyl acetate. Industrial emissions should be the top priority to meet the relevant control criteria, followed by vehicular emissions. This study provides a strategy for VOC source apportionment from an industrial complex, which is helpful in the development of targeted control strategies.

본 연구는 도시·산업지역의 넓은 불투수 지역뿐만 아니라 좁은 지역의 도로·교량이 통과되는 하천유역에서 발생되는 비점오염원을 초기우수로부 터 저감시킴으로써 하천수질의 오염을 줄일 수 있는 저감장치를 개발하여 실용화하고자 한다. 이를 위해 본 연구의 선행연구에서 취득한 자료를 기반으로 현장 성능시험용 저감장치를 개발하여 생화학적 산소요구량(BOD), 화학적 산소요구량(COD), 총질소(T-N)와 부유물질(SS)의 저감효율에 대한 성능시험을 실시하였다. 성능분석 결과는 시간구간별 시험항목의 분석에서 그 성능이 우수한 것으로 확인되었다. 그 결과는 국립환경 과학원에서 제안한 비점오염 저감시설의 요구 저감효율을 충족시키는 것으로 나타나 실무활용이 가능할 것이다.

In this study, the discharge loads of non-point pollution sources were analyzed using a Hydrologic Simulation Program-Fortran (HSPF) model for 46 sub-watersheds in order to guide the management plan for water and streams passing through the city. The results using HSPF showed good applicability in comparison to point measurements, which were based on BOD, TP, and TN. The mean value of the BOD loads was 4.08 kg/km2 per day, and the highest level of BOD was 17.75 kg/km2 per day at Namri. Three potential areas of high priority for the installment of constructed wetlands were selected in order to reduce non-point pollution sources based on BOD loads and on environmental and economic conditions. The results for these scenarios indicated a maximum rate of reduction in BOD of 39.12% within the proposed constructed wetlands.

The MFFn(Mass first flush), EMCs(Event mean concentrations) and runoff loads were analyzed for various rainy events(monitoring data from 2011 to 2012) in transportation area(rail road in station). The pollutant EMCs by volume of stormwater runoff showed the BOD5 9.6 ㎎/L, COD 29.9 ㎎/L, SS 16.7 ㎎/L, T-N 3.271 ㎎/L, T-P 0.269 ㎎/L in the transportation areas(Railroad in station). The average pollutant loading by unit area of stormwater runoff showed the BOD5 27.26 kg/㎢, COD 92.55 kg/㎢, SS 50.35 kg/㎢, T-N 10.13 kg/㎢ and T-P 10.13 kg/㎢ in the transportation areas. Estimated NCL-curve(Normalized cumulated-curve) was evaluated by comparison with observed MFFn. MFFn was estimated by varying n-value from 10% to 90% on the rainy events. The n-value increases, MFFn is closed to '1'. As time passed, the rainfall runoff was getting similar to ratio of pollutants accumulation. The result of a measure of the strength of the linear relationship between observed data and expected data under model was good.

This study analyzed the characteristics of stormwater runoff by rainfall type in orchard areas and transportation areas for 2 years(2010~2011year). Effluents were monitored to calculate the Event Mean Concentrations(EMCs) and runoff loads of each pollutant. The pollutant EMCs by volume of stormwater runoff showed the ranges of BOD 0.9~13.6 ㎎/L, COD 13.7~45.2 ㎎/L, SS 4.1~236.4 ㎎/L, T-N 2.123~21.111 ㎎/L, T-P 0.495~2.214 ㎎/L in the orchard areas, and was calculated as BOD 2.3~22.5㎎ /L, COD 4.4~91.1 ㎎/L, SS 4.3~138.3 ㎎/L, T-N 0.700~13.500 ㎎/L, T-P 0.082~1.345 ㎎/L in the transportation areas. The correlation coefficient of determination in the orchard area was investigated in the order of Total Rainfall(0.81) > Total Runoff(0.76) > Rainfall Intensity(0.56) > Rainfall Duration(0.46) > Antecedent Dry Days(0.27). Also, in the case of the transportation area was investigated in the order of Total Rainfall (0.55) > Total Runoff(0.54) > Rainfall Intensity(0.53) > Rainfall Duration(0.24) > Antecedent Dry Days(0.14). As the result, comparing valuables relating to runoff of non-pollutant source between orchard areas and transportation areas, orchard area(R2 ≥ 0.5 : X3, X4, X5) was investigated to have more influence of diverse independent valuables compared to the transportation area(R2 ≥ 0.5 : X3, X4) and the difference of discharge influence factor by the land characteristics appeared apparently.