본 연구의 목적은 복층 배수성·저소음 아스팔트 포장의 공용수명 예측과 경제성 분석에 있다. 성능평가를 위한 현장시 험은 투수시험 및 소음 측정을 실시하였으며, 실내시험은 반사균열, 동탄성계수, 소성변형(FN) 시험을 진행하였다. 성능 평가 결과를 기반으로 포장설계 수명 예측 및 비용 편익 분석을 수행하였으며, 이를 일반 밀입도 포장의 비용 편익과 비 교·분석하여 복층 배수성·저소음 아스팔트 포장의 경제성을 확인하고자 하였다. 성능평가 결과 복층 배수성·저소음 포장 이 일반 밀입도 포장과 비교 시 소음 저감 성능에서 매우 우수한 결과를 나타내었다. 비용 편익 분석 결과 복층 배수성· 저소음 아스팔트 포장은 높은 초기비용에도 불구하고 설계기간동안 낮은 유지보수 비용을 가지며 안전 및 소음 측면에 서 일반 밀입도 포장과 비교 시 매우 경제적인 것으로 나타났다. 총 비용과 총 편익 비용을 편익 비용 비율(BCR)로 계 산한 결과 복층 배수성·저소음 아스팔트 포장이 단위 비용 당 편익 측면에서 방음벽이 있는 다른 포장에 비해 가장 우수 한 결과를 보였다.

Battery electrodes, essential for energy storage, possess pores that heavily influence their mechanical properties based on the level of porosity and the nature of the pores. The irregularities in pore shape, size, and distribution complicate the accurate determination of these properties. While stress-strain measurements can shed light on a material’s mechanical behavior and predict compression limits, the complex structure of the pores poses significant challenges for accurate measurements. In this research, we introduce a simulation-driven approach to derive stress-strain data that considers porosity. By calculating relative density and the rate of volume change under compression based on porosity, and applying pressure, we conducted a parametric study to identify the elastic modulus (E) in relation to the rate of volume change. This information was utilized within a material modeling equation, generating stress-strain (S-S) curves that were further analyzed to replicate the compression behavior of the electrode material. The outcomes of this study are expected to improve the prediction accuracy of mechanical properties for porous electrode materials, potentially enhancing battery performance and refining manufacturing processes.

A substantial quantity of discarded tires has inflicted harm on the environment. Microwave pyrolysis of discarded tires emerges as an efficient and environmentally friendly method for their recycling. This research innovatively utilizes the characteristics of microwave rapid and selective heating to pyrolyze waste tires into porous graphene under the catalysis of KOH etching. Moreover, this study comprehensively investigates the dielectric characteristics and heating behavior of waste tires and different proportions of waste tire–KOH mixtures. It validates the preparation of graphene through KOH-catalyzed microwave pyrolysis of waste tires, tracking morphological and structural changes under varying temperature conditions. The results indicate that optimal dielectric performance of the material is achieved at an apparent density of 0.68 g/cm3 at room temperature. As the temperature increases, the dielectric constant gradually rises, particularly reaching a notable increase around 700 °C, and then stabilizes around 750 °C. Additionally, the study investigates the penetration depth and reflection loss of mixtures with different proportions, revealing the waste tire–KOH mass ratio of 1:2 demonstrates favorable dielectric properties. This research highlights the impressive microwave responsiveness of the waste tire–KOH mixture, Upon the addition of KOH, the mixed material exhibits an augmented dielectric constant and relative dielectric constant, supporting the viability of KOH-catalyzed microwave pyrolysis for producing porous graphene from waste tires. This method is expected to provide a new method for the valuable reuse of waste tires and a technology for large-scale, efficient and environmentally friendly production of graphene.

For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ( NH4)2HPO4 and activator K2CO3. It was found that ( NH4)2HPO4 not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ( NH4)2HPO4 facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ( NH4)2HPO4. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by NaBH4. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × 10– 4 mmol mg− 1 min− 1, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts.

도로 포장 기술이 발달함에 따라 내구성 확보 등의 구조성능 중심에서 이용자의 승차감 및 소음 저감 등의 기능성 중심으로 변화하 고 있다. 최근 도로 소음에 대한 민원이 증가하고 있고 도로 소음으로 인한 피해를 보상하라는 판결 사례도 증가하고 있다. 이러한 문 제를 해결하기 위해 차량 소음 저감 효과가 우수한 저소음 포장을 적용하고 있다. 본 연구에서는 저소음 배수성 포장과 저소음 비배 수성 포장의 내구성 및 공용성을 평가하였으며, 기대수명 예측을 위해 국내에 있는 배수성 8종, 비배수성 3종의 제품을 이용하여 실내 성능 평가를 수행하였다. 국토교통부의 "아스팔트 콘크리트 포장 시공 지침(2021)"의 배수성 포장 품질기준 및 비배수성 혼합물에 대 한 품질기준에 따라 시험을 진행하였다. 아스팔트 혼합물의 생산, 저장, 운반 및 포설 시 아스팔트의 흘러내리는 양이 적합한지를 평 가하기 위해 드레인다운 시험을 진행하였고, 배수성 혼합물의 골재 비산 저항성을 평가하기 위해 칸타브로 손실률 시험을 진행하였다. 또한 포장의 수분 저항성을 평가하기 위해 인장강도비(TSR) 시험과 소성변형 저항성을 평가하기 위해 동적안정도 시험을 진행하였다. 이후, 배수성 포장의 투수 성능을 평가하기 위한 실내투수계수 시험을 진행하였고, 저소음 포장의 소음 저감 성능을 평가하기 위해 임 피던스 관을 이용한 흡음률 시험을 진행하였다. 시험 결과 모든 종류의 혼합물이 품질기준을 통과하여 충분한 기초 성능을 가지고 있 는 것으로 나타났고, 흡음률 시험의 경우 배수성 혼합물이 평균 0.779, 비배수성 혼합물이 평균 0.638의 흡음계수를 나타내었다. 배수 성 혼합물과 비배수성 혼합물의 평균 공극률은 각각 19.3%, 3.2%로 배수성 혼합물이 비배수성 혼합물에 비해 많은 공극률을 가지고 있어 소음 저감 성능이 비배수성에 비해 우수한 것으로 판단하였다.

한국 고속도로 포장은 1970년 경부고속도로 건설을 시작으로 많은 발전을 이루었으며, 최근 도로이용자에게 쾌적한 도로를 제공할 수 있는 배수성 아스팔트 포장에 대한 관심이 높아지고 있다. 본 연구에서는 한국 고속도로 배수성 아스팔트 구간에 대한 시공목적별, 신설과 유지보수 등을 구분하여 배수성 아스팔트 포장 적용현황을 분석하였다. 또한, 적용된 배수성 아스팔트 포장의 교통량을 조사 분석하였으며, 효율적인 교통량 그룹 선정 방법을 제시하였다. 고속도로에 적용된 배수성 아스팔트 포장의 전주기 평가를 위해 평가항 목을 제시하였다. 내구성평가 항목으로는 포장상태평가지수와 표면조도를 선정하였다. 기능성 평가 항목으로는 내부 공극 막힘여부를 확인할 수 있는 현장투수, 미끄럼저항지수, 포장노면과 타이어에서 발생하는 도로소음원 평가를 위한 도로소음을 선정하였다. 그리고 조사 항목들에 대한 배수성 아스팔트 포장의 전주기 평가를 통해 각각 조사 항목에 대한 정량적 분석평가를 수행하여 도로소음도 예 측식을 제안하였다.

Using porous asphalt in order to reduce traffic noise and increase road safety specially in rainy weather is become a time demand now a days. Traditional dense asphalt can not provide a well mannered drain systems, adequate road capacity and noise friendly environment, which can make harm to roadway, property and ultimately to the life. In contrast, porous asphalt provides a environment friendly, cost effective, high skid resistive and well drains pavement with great durability. Additionally, the ability of porous to decrease the number of crashes both in sunny and wet-weather are up to the mark. In this context, investigate the ability of porous asphalt allows for deeper insights into all the mentioned factors, which help to make a durable, time demandable, more safer pavements in the field of pavement engineering. By combining some lab tests, field tests and analyzing the data, this research offers more accurate and reliable results to lead a pavement situation adaptable.

Volatile organic compounds (VOCs) are commonly produced in the combustion of fossil fuels and in chemical industries such as detergents and paints. VOCs in atmosphere cause different degrees of harm to human bodies and environments. Adsorption has become one of the most concerned methods to remove VOCs in atmosphere due to its high efficiency, simple operation and low energy consumption. Biomass-based porous carbon (BPC) has been considered as the most promising adsorption material because of the low cost and high absorption rate. In this paper, the key characteristic (e.g., specific surface area, pore structure, surface functional groups and basic composition) of BPC affecting the adsorption of VOCs in atmosphere were analyzed. The improvement of adsorption capacity of BPC by common modification methods, such as surface oxidation, surface reduction, surface loading and other modification methods, were discussed. Examples of BPC adsorption on different types of VOCs including aldehydes, ketones, aromatic VOCs, and halogenated hydrocarbons, were also reviewed. The specific adsorption mechanism was discussed. Finally, some unsolved problems and future research directions about BPC for adsorbing VOCs were propounded. This review can serve as a valuable reference for future developing effective biomass-based porous carbon VOCs adsorption technology.

In this study, we report significant improvements in lithium-ion battery anodes cost and performance, by fabricating nano porous silicon (Si) particles from Si wafer sludge using the metal-assisted chemical etching (MACE) process. To solve the problem of volume expansion of Si during alloying/de-alloying with lithium ions, a layer was formed through nitric acid treatment, and Ag particles were removed at the same time. This layer acts as a core-shell structure that suppresses Si volume expansion. Additionally, the specific surface area of Si increased by controlling the etching time, which corresponds to the volume expansion of Si, showing a synergistic effect with the core-shell. This development not only contributes to the development of high-capacity anode materials, but also highlights the possibility of reducing manufacturing costs by utilizing waste Si wafer sludge. In addition, this method enhances the capacity retention rate of lithium-ion batteries by up to 38 %, marking a significant step forward in performance improvements.

We successfully synthesized a porous carbon material with abundant hexagonal boron nitride (h-BN) dispersed on a carbon matrix (p-BN-C) as efficient electrocatalysts for two-electron oxygen reduction reaction ( 2e− ORR) to produce hydrogen peroxide ( H2O2). This catalyst was fabricated via ball-milling-assisted h-BN exfoliation and subsequent growth of carbon structure. In alkaline solutions, the h-BN/carbon heterostructure exhibited superior electrocatalytic activity for H2O2 generation measured by a rotating ring-disk electrode (RRDE), with a remarkable selectivity of up to 90–97% in the potential range of 0.3–0.6 V vs reversible hydrogen electrode (RHE), superior to most of the reported carbon-based electrocatalysts. Density functional theory (DFT) simulations indicated that the B atoms at the h-BN heterostructure interface were crucial active sites. These results underscore the remarkable catalytic activity of heterostructure and provide a novel approach for tailoring carbon-based catalysts, enhancing the selectivity and activity in the production of H2O2 through heterostructure engineering.

Carbon nanomaterials (CNMs) have been the subject of extensive research for their potential applications in various fields, including photovoltaics and medicine. In recent years, researchers have focused their attention on CNMs as their high electrical conductivity, low cost, and large surface area are promising in replacing traditional platinum-based counter electrodes in dye-sensitized solar cells (DSSC). In addition to their electrical properties, CNMs have also displayed antibacterial activity, making them an attractive option for medical applications. The combination of CNMs with metal oxides to form composite materials represents a promising approach with significant potential in various fields, including energy and biology. Here, we introduce porous carbon nanospheres (PCNS) derived from Cocos nucifera L. and its ZnO composite (PCNS/ZnO) as an alternative material, which opens up new research insights for platinum-free counter electrodes. Bifacial DSSCs produced using PCNS-based counter electrodes achieved power conversion efficiencies (PCE) of 3.98% and 2.02% for front and rear illumination, respectively. However, with PCNS/ZnO composite-based counter electrodes, the efficiency of the device increased significantly, producing approximately 5.18% and 4.26% for front and rear illumination, respectively. Moreover, these CNMs have shown potential as antibacterial agents. Compared to PCNS, PCNS/ZnO composites exhibited slightly superior antibacterial activity against tested bacterial strains, including gram-positive Bacillus cereus (B. cereus) and Staphylococcus aureus (S. aureus), and gram-negative Vibrio harveyi (V. harveyi) and Escherichia coli (E. coli) with MIC values of 125, 250, 125, and 62.5 μg/ml, respectively. It is plausible that the outcomes observed were influenced by the synergistic effects of the composite material.

The raw material selected for this research was Brazil chestnut shells (BCs), which were utilized to gain porous carbon as a positive electrode for lithium–sulfur batteries (LSBs). The effects of N/S co-doped on the electrochemical properties of porous carbon materials were studied using thiourea as nitrogen and sulfur sources. The experimental results indicate that the N/S co-doped carbon materials have a higher mesopore ratio than the undoped porous carbon materials. The porous carbon material NSPC-2 has a lotus-like structure with uniform pore distribution. The N and S doping contents are 2.5% and 5.4%. The prepared N/S co-doped porous carbon materials were combined with S, respectively, and three kinds of sulfur carbon composites were obtained. Among them, the composite NSPC-2/S can achieve the initial specific discharge capacity of 1018.6 mAh g− 1 at 0.2 C rate. At 1 C rate, the initial discharge capacity of the material is 730.6 mAh g− 1, and the coulomb efficiency is 98.6% and the capacity retention rate is 71.5% after 400 charge–discharge cycles.

In this paper, iron ore tailings (IOT) were separated from the tailings field and used to prepare cement stabilized macadam (CSM) with porous basalt aggregate. First, the basic properties of the raw materials were studied. Porous basalt was replaced by IOT at ratios of 0, 20 %, 40 %, 60 %, 80 %, and 100 % as fine aggregate to prepare CSM, and the effects of different cement dosage (4 %, 5 %, 6 %) on CSM performance were also investigated. CSM’s durability and mechanical performance with ages of 7 d, 28 d, and 90 d were studied with the unconfined compression strength test, splitting tensile strength test, compressive modulus test and freeze-thaw test, respectively. The changes in Ca2+ content in CSM of different ages and different IOT ratios were analyzed by the ethylene diamine tetraacetic acid (EDTA) titration method, and the micro-morphology of CSM with different ages and different IOT replaced ratio were observed by scanning electron microscopy (SEM). It was found that with the same cement dosage, the strengths of the IOT-replaced CSM were weaker than that of the porous basalt aggregate at early stage, and the strength was highest at the replaced ratio of 60 %. With a cement dosage of 4 %, the unconfined compressive strength of CSM without IOT was increased by 6.78 % at ages from 28 d to 90 d, while the splitting tensile strength increased by 7.89 %. However, once the IOT replaced ratio reached 100 %, the values increased by about 76.24 % and 17.78 %, which was better than 0 % IOT. The CSM-IOT performed better than the porous basalt CSM at 90 d age. This means IOT can replace porous basalt fine aggregate as a pavement base.

We have intended and preparation of hierarchically absorbent materials were covered with a NiMn2O4 and acts as a catalyst for azo dye degradation. The polyaromatic-based (PA) absorbent compounds were initially constructed by bromomethylated aromatic hydrocarbons which undergo self-polymerization in presence of ZnBr as a reagent and cross linker is bromomethyl methyl ether. The absorbent black materials with a 3D network were prepared by direct carbonization and activation of the as-prepared PA. The hydrothermal method was adapted for the preparation of carbon hybrid material C@NiMn2O4 powder's catalytic activity is effective in reducing p-nitrophenol to p-aminophenol and decolorizing carbon-based dyes like methyl orange (MO), methyl yellow (MY), and Congo red (CR) in aqueous media at 25 °C when NaBH4 is added. UV–visible spectroscopy was used to analyze the dyes' breakdown at regular interval.