This study was conducted to simulate the lifetime of the membrane by analyzing the performance of the membrane degraded by chlorine. Chlorine exposure under several conditions caused the degradation of the membrane, resulting in the absence of any salts and an extreme increase in permeability. When the n value was calculated and compared through CnT analysis and CTn analysis, the p values were all less than 0.005, but CTn analysis, which had a higher R2 value, was adopted to simulate the membrane lifetime. Power coefficients take on values higher than 1, indicating that the exposure time to chlorine has a greater influence on membrane deterioration than the chlorine exposure concentration at 20℃ and 30℃. In particular, the process should be operated at less than 0.5 ppm at 30°C, and the chlorine exposure time of 1 cycle should be set to within 15 hours. In addition, the sensitivity to chlorine increased by 10.5 to 12.2 times when the chlorine exposure temperature increased by 10°C through the correlation between the chlorine exposure cycle and membrane lifetime. The membrane lifetime investigated in this study is only an estimated value, entirely because of chlorine membrane deterioration, excluding raw water characteristics and the type of detergent. Accordingly, it is considered that the membrane lifetime simulation can be applied by comparing the membrane performance with the actual process based on the filtration performance of membrane deterioration by chlorine.

In this study, various physical cleaning methods such as physical washing and osmotic backwash, were performed to understand membrane fouling characteristics by employing real secondary wastewater effluent (SWWE). In addition, microfiltration (MF) and ultrafiltration (UF) pretreatments were compared to maximize removal of organic matter and to control membrane fouling efficiently. Organic foulants deposited on the active layer of FO membrane were observed by fouling behavior test. The relationship between concentrations of natural organic matter and membrane fouling was also investigated from the bench-scale FO tests. Finally, by quantitative analysis of correlations between foulants and fouling reversibility with the modified fouling index (MFI), we identified the applicability of MFI in predicting FO intake water fouling potential.

In this research, the applicability of modified fouling index (MFI) on ultrapure water (UPW) production system was assessed to predict performance of reverse osmosis (RO) process. The practical study on MFI-UF was first performed at a pilot-scale UPW plant (Hwaseong-si, Gyeonggi-do, Korea), monitoring water quality parameters (i.e., conductivity, turbidity and TOC) as well as MFI-UF of pretreatment stage for 10 months. While water quality parameters were maintained in a stable manner, the MFI-UF was fluctuated implying the different propensity of RO influent. The increment of fouling potential was intimately related with RO performance, the aggravation of permeate quality. The sensitivity of MFI-UF was also verified by evaluating the fouling potential of reclaimed water in UPW production system.

본 연구에서는 베셀 후단의 생산수를 유입수와 혼합하는 신개념의 저에너지 역삼투 공정을 제안한다. 이 기술은 후단 생산수로 유입수를 희석하여 열역학적 요구 에너지를 낮추는 것에 착안하였다. 방법으로 역삼투 단일공정, 신공정, 부분 2차 공정의 생산수 염도 및 고유전력소비를 수치해석을 통해 비교하였다. 유입수의 다양한 수온 및 염도 조건 하에 신공정은 단일공정 대비 약 14% 생산수 염도를 감소시켰고, 0.04-0.09 kWh/m³의 고유전력소비를 추가로 필요하였다. 반면, 부분 2차 공정은 단일공정 대비 생산수 염도를 약 46% 감소시켰고, 0.08-0.21 kWh/m3의 고유전력소비를 추가로 필요로 하였다. 즉, 신공정은 부분 2차 공정 대비 저에너지를 소모하면서 단일공정 대비 고품질의 물을 생산해낸다.

We report on a unique fabrication technique, DSC for high performance PA TFC RO membranes. DSC allows the simultaneous and continuous spreading of two reactive monomer solutions to create an unsupported PA layer, which is then adhered onto a porous support to form a membrane. DSC facilitates the characterization of the PA layer structure by easily isolating it. The DSC-PA layer exhibits a thinner and smoother structure with a more wettable and less negatively charged surface than one prepared via conventional interfacial polymerization (IP). DSC enables the formation of an extremely thin (~9 nm) and dense PA layer using a very low MPD concentration, which is not feasible by conventional IP. Importantly, the DSC-assembled membrane shows the excellent water flux and NaCl rejection, exceeding both the IP control and commercial RO membranes.

역삼투 해수담수공정의 전처리로 CO2 가스하이드레이트를 이용한 급속동결담 수(HIID)공정의 가능성 평가를 목적으로 실험을 진행하였다. CO2 가스하이드레 이트는 가압된 CO2가스를 GUEST로 사용하여 만들어지는 얼음형태의 결정을 의미하며, 이때, 가압된 압력을 상압으로 감압하게 되면 흡열반응이 진행되어 온도가 급감하게 된다. HIID공정은 이 온도감소를 구동력으로 해수를 동결하였다. 이 전처리된 해수를 225psi로 역삼투막을 6시간 저압 운전시 수투과도가 14 LMH이상, 제거율이 98.5-99%로 관찰되었다. 이 실험으로 HIID공정이 역삼투공 정의 전처리로 사용가능함을 확인하였으며, 후단의 역삼투공정에서 운전하는 압력을 기수조건으로 가능하게 하였다. 이를 통해 저비용으로 해수담수가 가능함 을 확인하였다.

Seawater desalination market after global economic crisis has been stalled due to the market uncertainties and decreased demand in desalination. It is important to review the status of the market and to estimate the appropriate share of Forward osmosis-Reverse Osmosis (FO-RO) hybrid desalination technology by figuring out the outlook of the desalination market. Main part of the desalination market will still be MENA (Middle East and North Africa) in the near future due to the fast population increase and high dependency of fossil fuel in the region. The market for FO-RO hybrid technology, however, might be smaller than the conventional SWRO desalination market anyway because of aesthetic issues from using wastewater as raw water and higher costs associated with capex. Therefore, it is essential to improve FO membrane performance and system operation technologies in order to make the hybrid technology attractive compared to the conventional SWRO technology.

We report on a new fabrication method of polyamide thin film composite RO membranes, so called support-free interfacial polymerization (SFIP). In SFIP method, the PA layer is first formed at the interface without a porous support, and then adhered onto a support unlike conventional IP where the PA layer is in-situ formed directly on a support. We control the surface chemistry of a PAN support by adjusting hydrolysis to maximize adhesion of the PA layer with the support. The SFIP-assembled membrane showed higher performance and unique surface morphology compared to conventional IP-assembled one. It allows facile characterization of the PA layer and PA-support interface together with well-defining each component. Therefore, SFIP provide an promising material platform for the fabrication of RO membranes and fundament study.

본 연구에서는 현재 전량 폐기되는 정수기용 폐 카본블록 필터를 재활용하고자 폐 필터의 특성을 파악한 후 열 처리를 진행하였다. 성능 평가를 위해 실제 정수기에서 사용 후 폐기되는 카본블록 필터 (도레이 케미칼에서 제조)를 회수하여 활성탄의 흡착능을 측정하였다. 대조군으로써 새 필터도 같은 조건으로 진행하였다. 재활용을 위한 열처리의 온도는 400, 550, 및 700℃로 진행하였으며 최적 조건을 찾기 위해 새 필터에 먼저 열처리를 진행하였다. 또한 TGA, DSC, SEM 및 BET를 이용하여 폐 필터의 표면 특성을 분석하였다. 이러한 결과를 바탕으로, 폐 필터 표면에 막 오염(fouling)과 정도를 확인하였으며, 폐 카본블록 필터의 재활용 및 복원기술 연구를 통한 순환 활용 기술을 확보하고자 한다.