PURPOSES : This study is conducted to evaluate the development of materials for extinguishing ESS(Energy Storage System) fires in electric vehicles using industrial byproducts. METHODS : Grout containing an appropriate amount of fly ash, silica fume, blast furnace slag powder, and ferronikel slag, which are industrial byproducts, was prepared. The fluidity, stress, and mechanical properties were evaluated in accordance with standard test methods. RESULTS : The fluidity of the materials used for the evolution of ESS fires differed depending on the material of the industrial byproducts. In the case of blast furnace slag, its fluidity is low owing to viscosity even when it content is high, and the use of ferronikelsrag is shown to be suitable for the evolution of ESS fires in fluidity and curing tests. CONCLUSIONS : Fire-extinguishing materials using industrial byproducts require a long curing time but exhibit the fluidity required for ESS fire extinguishment. In particular, the curing and fluidity of Peronikel slag and fly ash are suitable for ESS fire extinguishing.

PURPOSES : In this study, high-viscosity grout for increasing ground stiffness is developed using industrial byproducts. METHODS : Based on literature review, the viscosity and viscosity expression time of domestic and foreign anti-washout admixture underwater were evaluated. In addition, grout was prepared by mixing 5% to 40% of fly ash (FA) in a standard mixture. Flow, setting time, and compressive strength tests were conducted to evaluate the quality of the grout. RESULTS : Experimental results show that the viscosity required is 35,000 to 40,000 cps, whereas the viscosity expression time required exceeds 300 min. As the amount of FA used for grouting increases, the physical and mechanical performances deteriorate. The strength of a test specimen manufactured underwater is lower than that of a test specimen manufactured under air, and the decrease on day 28 is lower than that on day 3. The FA applied to the grout should be less than 20%. CONCLUSIONS : Although industrial byproducts, which exhibit high viscosity, offer excellent mechanical performance and are thus suitable as a solidifying agent for strengthening grout, their application in the field must be evaluated.

본 연구에서는 이산화탄소 고정화에 있어 이산화탄소 전환을 위해 MEA를 이용한 습식화학흡 수법의 셔틀메카니즘을 도입하였다. 또한 알칼리 무기물질을 다량 함유한 산업부산물을 습식탄산화법을 이용해 처리하고자 하였다. 즉, 산업부산물의 화학적 처리를 통해 칼슘이온을 용출하였다. 산성물질을 이용한 용출상징수를 ICP로 분석한 결과, 칼슘이온이 최대 17,900 ppm(1.79%)을 확보하였다. 또한 MEA를 이용한 습식 흡수공정을 통해 상온, 상압조건의 이산화탄소 분위기에서 94%의 전환률을 얻었 다. 슬러지의 액상탄산화를 통해 슬러지 mg 당 0.175 mg의 이산화탄소를 고정하였으며, 최종생성물의 XRD 분석결과 일반적인 탄산칼슘의 결정구조인 calcite 형상을 확인하였다.