The sampling bag is used as a storage container for odor gas samples. It is known that the substances recovery rate of odor bags decreases during storage time, and the degree of recovery varies depending on the characteristics of the gas sample and the material of the bag. This study investigated the recovery rate of VFA (ACA, PPA, BTA, VLA) in PEA bags during storage time. In addition, a model was developed to estimate the recovery rate of each substance as a function of time. Standard gas (ACA, PPA, BTA, VLA mixed) recovery rate was used for the model development. The concentration of the compound in the bag was measured by SIFT-MS at intervals of 1 to 2 hours. The recovery rate according to the storage time was calculated as the ratio to the initial concentration. The recovery rate of each substance according to the storage period (12h, 24h, 36h, 48h) was ACA (66.2%, 62.8%, 55.6%, 52.0%), PPA (77.6%, 72.1%, 63.0%, 58.1%, 86.6%), BTA (86.6%, 81.3%, 71.6%, 66.9%), VLA (94.8%, 89.0%, 76.6%, 71.7%). The recovery rate continued to decrease over the course of 48 hours of storage time. ACA, PPA, and BTA showed the greatest decrease within the initial 12 hours, which is form of exponential decrease. Therefore, we considered a 1~3 degree polynomial regression model and a 1~2 degree exponential decay model. Each developed model was evaluated by r², RMSE, MAPE, AIC, and then a model for each substance was selected. Selected models were tested with recovery rate data from swine farm odor samples. Only the ACA model exhibited a good performance (r² = 0.76).
Environmental fundamental facilities have different odor emission characteristics depending on the type of treatment facilities. To overcome the limitations of the olfactometry method, research needs to be conducted on how to calculate the dilution factor from the individual odor concentrations. The aim of this study was to determine the air dilution factor estimated from manually measured concentration data of individual odor substances (22 specified odor species) in three environmental treatment facilities. In order to calculate the optimum algorism for each environmental fundamental facility, three types of facilities were selected, the concentration of odor substances in the exhaust gas was measured, and the contribution of the overall dilution factor was evaluated. To estimate the dilution factor, four to six algorism were induced and evaluated by correlation analysis between substance concentration and complex odor data. Dilution factors from O municipal water treatment (MWT) and Y livestock wastewater treatment (LWT) facilities showed high level of dilution factors, because concentration levels of hydrogen sulfide and methylmercaptan, which had low odor threshold concentrations, were high. In S food waste treatment (FWT) facility, the aldehyde group strongly influenced dilution the factor (dominant substance: acetaldehyde, i-valeraldhyde and methylmercaptan). In the evaluation of four to six algorism to estimate the dilution factor, the vector algorism (described in the text) was optimum for O MWT and Y LWT, while the algorism using the sum of the top-three dominant substances showed the best outcome for S FWT. In further studies, estimation of the dilution factor from simultaneously monitored data by odor sensors will be developed and integrated with the results in this study.
This study aimed to estimate the odor emission rate from swine nursery facilities (naturally and mechanically ventilated) using probability distribution. Odor occurrence trends in the study facilities were very different; odor concentration and gas flow had a lognormal distribution. Monte Carlo simulation was used to carry out the uncertainty analysis. Odor emission rate was found to range from 18.05 OU/sec (10th percentile) to 621.88 OU/ sec (90th percentile), and odor emission rate per head ranged from 0.02 OU/sec · head (10th percentile) to 0.64 OU/ sec · head (90th percentile).
In this study, leachate treatment facility (outlet, facility inside) and landfill sections (vent systems, landfill surface)of nine landfills is being buried in korea were studied emission characteristics of odor compounds. Air dilutionvalue in ventpipes of landfill section was generally highest and was more 3 times higher than emission standard(air dilution value of facilities outlet : 500) in Daejeon, Tongyeong, and Busan landfill. Outlet of leachate treatmentfacilities in Tongyeong and Daegu landfill, in case, was higher respectively 20 times, 6 times than other landfills,commonly show that a large contribution to the odor of hydrogen sulfide. In case of ordor emission rate, ammoniaand hydrogen sulfide were surveyed to comprise a high rate for odor emission rate. Odor emissions based onlandfill scale, large landfill (Sudokwon) and small landfills (Yeosu, Chuncheon, Chungju) is low in odor emissionsper unit area, whereas medium landfill (Busan, Daejeon, Daegu) was estimated to be high odor emissions. In caseof large landfill, leachate treatment facilities is management in good condition and discharged odor emission oflandfill sections was low into ambient air. In case of small landfill, decay gases and leachate is few. Thereforeodor emissions is fewer than estimated medium landfill. In case of medium landfill, management condition ofleachate treatment facility was in poor and landfill sections was under not stabilization stage. Thus, mediumlandfills was identified that needs to be intensive care.