3D프린팅 기술은 산업적 응용을 넘어서 기계 설비 및 각종 장비의 부품생산뿐만 아니라 의료, 식품, 패션에 이르기까지 많은 시제품들의 개발 및 연구가 진행되고 있다. 3D 프린팅 기반 기술의 적용사례를 볼 때 정밀도와 제작 속도 측면에서도 다른 산업에 충분이 활용될 수 있는 기술의 개발이 보고되고 있으나, 아직까지는 시제품 위주로 이용되고 있으며, 향후 3D 프린팅 기술은 4차산업혁명과 관련하여 광범위한 분야에서 응용될 수 있는 완성품이나 부품제작에 이용될 것으로 예상된다. 본 연구에서는 탄소나노 재료중 대표적으로 많이 이용되는 환원그래핀 [rGO(reduced graphene oxide)]과 전도성 고분자중 생체 친화적인 특성을 갖는 폴리피롤[Ppy(Polypyrrole)]의 복합체를 생분해성 고분자인 폴리카프로락톤 [PCL(polycaprolactone)]과 혼합하여 3D 프린팅용 전도성 레진을 개발하고자 하였다. 결과로, 폴리피롤과 환원그래핀 각각 5 wt%, 0.75 wt% 에서 최적의 전기적 특성을 나타내었으며, 환원그래핀의 농도에 따른 표면분석에서도 이와 부합하는 결과를 확인 할 수 있었다. 본 연구를 통하여 제조된 전도성 레진은 3D 프린팅 뿐만 아니라, 다른 산업분야의 전자재료에도 적용이 가능할 것으로 사료된다.

This manuscript explains the effective determination of urea by redox cyclic voltammetric analysis, for which a modified polypyrrole-graphene oxide (PPY-GO, GO 20% w/w of PPY) nanocomposite electrode was developed. Cyclic voltammetry measurements revealed an effective electron transfer in 0.1 M KOH electrolytic solution in the potential window range of 0 to 0.6 V. This PPY-GO modified electrode exhibited a moderate electrocatalytic effect towards urea oxidation, thereby allowing its determination in an electrolytic solution. The linear dependence of the current vs. urea concentration was reached using square-wave voltammetry in the concentration range of urea between 0.5 to 3.0 μM with a relatively low limit of detection of 0.27 μM. The scanning electron microscopy was used to characterize the morphologies and properties of the nanocomposite layer, along with Fourier transform infrared spectroscopy. The results indicated that the nanocomposite film modified electrode exhibited a synergistic effect, including high conductivity, a fast electron-transfer rate, and an inherent catalytic ability.

White organic light-emitting diodes with a structure of indium-tin-oxide [ITO]/ N,N-diphenyl-N,N-bis-[4-(phenylm- tolvlamino)-phenyl]-biphenyl-4,4-diamine [DNTPD]/ [2,3-f:2, 2-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile [HATCN]/ 1,1- bis(di-4-poly-aminophenyl) cyclo -hexane [TAPC]/ emission layers doped with three color dopants/ 4,7-diphenyl-1,10- phenanthroline [Bphen]/ Cs2CO3/ Al were fabricated and evaluated. In the emission layer [EML], N,N-dicarbazolyl-3,5-benzene [mCP] was used as a single host and bis(2-phenyl quinolinato)-acetylacetonate iridium(III) [Ir(pq)2acac]/ fac-tris(2- phenylpyridinato) iridium(III) [Ir(ppy)3]/ iridium(III) bis[(4,6-di-fluoropheny)-pyridinato-N,C2] picolinate [FIrpic] were used as red/green/blue dopants, respectively. The fabricated devices were divided into five types (D1, D2, D3, D4, D5) according to the structure of the emission layer. The electroluminescence spectra showed three peak emissions at the wavelengths of blue (472~473 nm), green (495~500 nm), and red (589~595 nm). Among the fabricated devices, the device of D1 doped in a mixed fashion with a single emission layer showed the highest values of luminance and quantum efficiency at the given voltage. However, the emission color of D1 was not pure white but orange, with Commission Internationale de L'Eclairage [CIE] coordinates of (x = 0.41~0.45, y = 0.41) depending on the applied voltages. On the other hand, device D5, with a double emission layer of mCP:[Ir(pq)2acac(3%) +Ir(ppy)3(0.5%)]/ mCP:[FIrpic(10%)], showed a nearly pure white color with CIE coordinates of (x = 0.34~0.35, y = 0.35~0.37) under applied voltage in the range of 6~10 V. The luminance and quantum efficiency of D5 were 17,160 cd/m2 and 3.8% at 10 V, respectively.

We have fabricated and evaluated newNew high high-efficiency green green-light light-emitting phosphorescent devices with an emission layer of [TCTA/TCTA1/3TAZ2/3/TAZ] : Ir(ppy)3 were fabricated and evaluated, and compared the electroluminescence characteristics of these devices were compared with the conventional phosphorescent devices with emission layers of (TCTA1/3TAZ2/3) : Ir(ppy)3 and (TCTA/TAZ) : Ir(ppy)3. The current density, luminance, and current efficiency of the a device with an emission layer of (80Å-TCTA/90˚Å-TCTA1/3TAZ2/3/130Å-TAZ) : 10%-Ir(ppy)3 were 95 mA/cm2, 25000 cd/m2, and 27 cd/A at an applied voltage of 10 V, respectively. The maximum current efficiency was 52 cd/A under the a luminance value of 400 cd/m2. The peak wavelength and FWHM (FWHM (full width at half maximum) in the electroluminescence spectral were 513 nm and 65 nm, respectively. The color coordinate was (0.30, 0.62) on the CIE (Commission Internationale de I'Eclairage) chart. Under the a luminance of 15000 cd/m2, the current efficiency of the a device with an emission layer of (80Å-TCTA/90Å-TCTA1/3TAZ2/3/130Å-TAZ) : 10%-Ir(ppy)3 was 34 cd/A, which has beenshowed an improvement of improved 1.7 and 1.4 times compared to those of the devices with emission layers of (300Å-TCTA1/3TAZ2/3) : 10%-Ir(ppy)3 and (100Å-TCTA/200Å-TAZ) : 10%-Ir(ppy)3, respectively.

High-efficiency phosphorescent organic light emitting diodes using TCTA-TAZ as a double host and Ir(ppy)3 as a dopant were fabricated and their electro-luminescence properties were evaluated. The fabricated devices have the multi-layered organic structure of 2-TNATA/NPB/(TCTA-TAZ) : Ir(ppy)3/BCP/SFC137 between an anode of ITO and a cathode of LiF/AL. In the device structure, 2-TNATA[4,4',4"-tris(2-naphthylphenyl-phenylamino)-triphenylamine] and NPB[N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] were used as a hole injection layer and a hole transport layer, respectively. BCP [2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline] was introduced as a hole blocking layer and an electron transport layer, respectively. TCTA [4,4',4"-tris(N-carbazolyl)-triphenylamine] and TAZ [3-phenyl-4-(1-naphthyl)-5-phenyl-1,2,4-triazole] were sequentially deposited, forming a double host doped with Ir(ppy)3 in the [TCTA-TAZ] : Ir(ppy)3 region. Among devices with different thickness combinations of TCTA (50 Å-200 Å) and TAZ (100 Å-250 Å) within the confines of the total host thickness of 300 Å and an Ir(ppy)3-doping concentration of 7%, the best electroluminescence characteristics were obtained in a device with 100 Å-think TCTA and 200 Å-thick TAZ. The Ir(ppy)3 concentration in the doping range of 4%-10% in devices with an emissive layer of [TCTA (100 Å)-TAZ (200 Å)] : Ir(ppy)3 gave rise to little difference in the luminance and current efficiency.

The effects of molecular structure on the redox properties of the organic electroluminescent materials (Ir(ppy)3 Ir(m-ppy)3 Ir(p-toly)3) were studied using cyclic voltammetry and spectroscopy. These iridium complexes show reversible oxidation and reduction on the electrode, which produce the symmetric cyclic voltammogram. It indicates that these materials are very stable under repetitive oxidation/reduction cycles. The electrochemically determined ionization potentia/electron affinity values are 5.4OeV/3.02eV for Ir(ppy)3, 5.36eV/2.96eV for Ir(m-ppy)3, and 5.35eV/2.97eV for Ir(p-toly)3 from the SCE(Standard Calomel Electrode). The electrically determined band gaps are 2.38eV (521nm), Ir(ppy)3, 2.4OeV (517nm), Ir(m-ppy)3, and 2.38eV (521nm). Ir(p-toly)3, which are similar with the optical band gaps. The position of methyl group on 2-phenylpyridine (ppy) effects do not influence much on the ionization potential, electron affinity, and band gap of Ir(ppy)3 derivatives.