Dust samples were collected from 17 middle and high schools in the Jeonju-city. Heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cr, Cu, Ni, Pb and Zn in indoor's dusts were highly concentrated. Also heavy metal concentrations in outdoor's dusts were similar to that of indoor's dusts. Concentrations of Cd, Cu and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools located at Kangseo-gu and Yangchon-gu, Seoul. Playground dusts in 6 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) greater than 1.0. Most indoor and outdoor dusts exhibited the enhanced heavy metal pollution with a pollution index (by Culbard et al.) greater than 1.0.

In order to examine the availability and effectiveness of crab shell for the removal of heavy metals in aqueous solution, the crab shell was compared with cation exchange resin (CER), zeolite, granular activated carbon (GAC) and powdered activated carbon (PAC) on aspects of heavy metal removal capacity, rate and efficiency. In the removal of Pb, Cd and Cr, the heavy metal removal capacity of crab shell was higher than those of any other sorbents (CER, zeolite, GAC, PAC), and the order of heavy metal removal capacity was crab shell > CER > zeolite > PAC =～GAC. However, in the removal of Cu, the result of crab shell was slightly lower than that of CER. The initial heavy metal removal rate was affected by the sorts of sorbents and metals. In all heavy metals, the heavy metal removal rate of crab shell was higher than those of any other sorbents. Under the heavy metal concentration of 1.0 mmole/ℓ, the heavy metal removal efficiency of crab shell was maintained as 93∼100 %, which was much higher than those of any other sorbents.

The hydroxyapatite (HAp) for the present study was prepared by precipitation method in semiconductor fabrication and the crystallized at ambient to950℃ for 30min in electric furnace. The ion-exchange characteristics of HAp for various heavy metal ions such as Cd2+, Cu2+, Mn2+, Zn2+, Fe3+, Pb2+, Al3+, and Cr6+ in aqueous solution has been investigated. The removal ratio of various metal ions for HAp were investigated with regard to reaction time, concentration of standard solution, amount of HAp and pH of solution. The order of the ions exchanged amount was as follows: Pb2+, Fe3+>Cu2+>Zn2+>Al3+>Cd2+>Mn2+>Cr6+. The Pb2+ ion was readily removed by the HAp, even in the strongly acidic region. The maximum amount of the ion-exchange equilibrium for Pb2+ ion was about 45 ㎎/gram of HAp. The HAp would seem to be possible agent for the removal of heavy metal ions in waste water by recycling of waste sludge in semiconductor fabrication.

To investigate size distribution and metallic elements of surface sediments in Hampyong Bay, the southwestern coast of Korea, sedimentological and geochemical studies on surface sediments are carried out. The surface sediments of Hampyong Bay are classified into gravel, muddy sandy gravel, gravelly muddy sand, gravelly sandy mud, mud facies in accordance with areal characteristics. The coarse sediments are distributed on the subtidal zone along the main tidal channel and southeast intertidal flat of Hampyong Bay. On the other hand, the fine sediments are dominated in northeast and west intertidal flat of Hampyong Bay. Most metallic elements except for Ba in the sediments are closely interrelated with fine sediments and mutually with each element. Ba is maybe related with sandy sediments and inversely related with carbonate contents. Normalized by Al content, the sediment do not show any remarkable metal enrichments influenced by resonable artificial or environmental factors.

In order to determine the changes of sediment facies and metal levels in surface sediments after the construction of Shiwha Lake, surface sediments were sampled at 8 sites located on the main channel monthly from June, 1995 to August, 1996 and analysed for 12 metals (Al, Fe, Mn, V, Cr, Co, Ni, Cu, Zn, Cd, As and Pb) by ICP/AES and ICP/MS. Two groups of sampling sites (the inner lake with 3 sites and the outer lake with 5 sites) are subdivided by the surface morphology; the inner lake is a shallow channel area with a gentle slope, while the outer lake is relatively deep and wide channel with a steep slope which has many small distributaries. After the construction of dam, fine terrestrial materials were deposited near the outer lake, which resulted in the change of major sediment facies from sandy silt to mud. With the deposition of fine sediments in the outer lake, anoxic water column induced the formation of sulfide compounds with Cu, Cd, Zn and part of Pb. Metal (Cr, Ni, Cu, Zn and Cd) contents in sediments increased up to twice within 2 years after the construction of dam. This is due to the direct input of industrial and municipal wastes into the lake and the accumulation of metals within the lake. In addition, frequent resuspension of contaminated sediments in a shallow part of the lake may make metal-enriched materials transport near the outer lake with fine terrestrial materials. As the enrichment of Cu, Zn, Cd and part of Pb in the Shiwha Lake may be related to the formation of unstable sulfide compounds by sulfate reduction in anoxic water or sediment column, the effect of mixing with open coastal seawater is discussed.