본 연구는 무금속프탈로시아닌 색소계를 이용한 전자사진 감광체의 개발에 관한 것이다. 전하발생물질로서는 각종 형태의 무금속프탈로시아닌을 사용했고, 결합제로서는 각종 폴리머를 사용했으며, 전하이동물질로서는 히드라존유도체나 아연착화합물을 사용했다. 전하발생물질로서 사용한 α-, β-, x형의 프탈로시아닌중에서는 x형의 무금속프탈로시아닌(x-H2Pc)의 경우가 가장 좋은 감도를 보였다. 전하발생물질로서는 x-H2Pc를, 전하수송물질로서는 히드라존유도체를 사용했을 때, 다른 감광체들과 비교하여 73.1%의 높은 1.50lux·sec의 좋은 감도를 보였다.

The symmetric benzoxazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in positive paper and negative film-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then all of solvents were stabilized sensitizer. The maximum absorption peak range in methanol, acetonitrile, acetone, DMF, dichloromethane, chloroform solvents was 501nm~511nm. But it was identified that only methanol can be used to photographic emulsion. The photographic characteristics have contrast of 2.8, speed of 50-55(lux·sec)-1, fog of 0.07-0.08, respectively.

사진식각 공정으로 종횡비가 매우 큰 유리 미세구조물을 제작하였다. 미세구조물의 제작에는 압축응력에 강하고 전기적 절연체인 감광성 유리를 사용하였다. 감광성 유리는 석영기판 위에 크롬이 패턴된 마스크를 사용하여 파장이 312nm인 자외선에 노광되었다. 500˚C 이상의 열처리공정을 거친 후 초음파 분위기에서 10%의 불산용액으로 식각함으로써 유리 미세구조물을 제작하였다. 미세구조물의 최종 형상은 감광성 유리의 두께, 마스크 패턴, 자외선 노광조건 및 식각조건에 크게 의존하였으며, 종횡비가 30이상인 스트라이프 구조의 유리 미세구조물을 제작할 수 있었다.

The hardening test of gelatin with 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt was studied at pH 5, 7, 8 and about increasing temperature, respectively. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The product was identified by elemental analyzer. IR spectrophotometer. Novel hardener can be used in photographic emulsion and showed very good hardening effect.

The symmetric naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. The stability on the solvents of naphthothiazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then all of solvents were stabilized sensitizer. The maximum absorption peak range in various solvents was 600nm~612nm. But it was identified that only methanol can be used to photographic emulsion.

The symmetric naphthothiazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, green-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, 1H-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 502nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

본 연구는기존의 보고에서 보다 감광화효율을 더욱 향상시키기 위하여 결정형이 다른 전하발생물질 (CGM:Charge Generation Material)과 전하수송물질(CTM:Charge Transport Material)을 사용하여 감광체를 만들었고, 이들의 정전특성을 비교검토하였다. 전하발생물질로서 결정형이 다른 α-, β-, x-형 무금속 프탈로시아닌 (H2Pc)을 사용한 결과, x-H2Pc를 사용한 감광체의 감도는 E12/의 값이 2.62 μJ/cm2로 가장 두수하게 나타났다. 전하발생층(CGL:Charge Generation Layer)에 첨가되는 CGM-CTM, CGM-CTM-ZnO로 구성된 감광체보다 전하발생층에 전하발생계만으로 구성된 감광체의 경우의 전하유지율 (80%) 및 감도(E12/=2.83μJ/cm2)면에서 우수함을 보여주었다. 한편 binder로서 PVB-co-PVA-co-PVAC[poly(viny1 butyral-co-viny1 alcohol-co-viny1 acetate)]를 사용했을 때는, CGM-CTM으로 구성된 감광체보다 CGL에 CGM-CTM으로 구성된 감광체의 경우의 전하유지율(71%) 및 감도(E12/=2.62μJ/cm2)면에서 우수함을 보여주었다.

In this study, benzoxazolo carbocyanine dye was used as sensitizer for photographic emulsion, and the photographic characteristics were examined. The basic properties of sensitizer such as stability in various solvents were examined. The sensitizer was very stable in methanol, acetonitrile, acetone, dimethylformamide, and chloroform solution. Absorption spectra of benzoxazolo carbocyanine dye 2.5×10-6M and 5×10-6M concentrations in 10% aqueous methanol solutions containing 10-2M potassium chloride show the monomer-J-aggregation characteristics. Compared to the absorption peak of the monomer in pure methanol solution, the red shifts of the monomer-J-aggregate peaks of benzoxazolo carbocyanine dye of 2.5×10-6M and 5×10-6M concentrations in 10% aqueous methanol solutions containing 10-2M potassium chloride are 34nm respectively, and the sensitizing peak of benzoxazolo carbocyanine dye in photographic emulsion has red shift of 34nm. Therefore, if was concluded that benzoxazolo carbocyanine dye can be used as green sensitizing dye for the spectral sensitization of photographic emulsion.

We have developed a new device, Plate-to-CCD Convertor (PCC), to conveniently digitize photographic plates in a relatively short time without losing any plate information (Oh et al. 1995). Using this device we have performed surface photometry of 12 early type galaxies. We determined relative orientations and scales to analyze PCC images. We also determined an ellipticity, position angle of the major axis, and a4 a4 of each galaxy to quantify the distribution of surface brightness. We checked the performance and limitation of this device by comparing the PCC images with those digitized by the ST microdensitometer and those obtained with CCD observations.

In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, 1H-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

Optimum hypering conditions are found for IIIa-J, IIIa-F, 103a-O, 103a-D, and IIa-O plates using hypersensitization machine in KAO. For every experimental plate we get speed gain, fog increment, signal to noise ratio and relative DQE according to hypering time and temperature. The hypersensitization method is baking with 8% hydrogen mixed gas. For IIIa-J, 103a-O, and 103a-D plates treated 65∘C 65∘C , 3 hours baking, the speed gains arc increased by about 10 times, 2 times, and 2 times compared to untreated plates, respectively. The fogs are increased by 0.08, 0.10, and 0.08, respectively. For IIIa-F, IIa-O plates treated 65∘C 65∘C , 2 hours baking, the speed gains are increased by about 4.7 times and 1.8 times compared to untreated plates, respectively. The fogs are increased by 0.15 and 0.04, respectively.

Astronomical plates have a very large density range (dynamical range). Many exposed astronomical photographic plates do not provide detailed structures for very high densities, and some include hidden images for very low densities. The former can be fixed through 'Unsharp Masking' technique and the latter through 'Image Amplification' technique. Besides, we can find intrinsic colors of celestial bodies through 'Tri Color Composition' technique. Images of several plates which were observed from Sobaek Observatory with 61cm telescope are reproduced by the three kinds of image reproducing techniques. As reproduced image examples, we display an Orion nebula and a waxing crescent moon images through unsharp masking technique and an M81 image through image amplification technique. An Orion nebula and a Dumbbell nebula images are also given as results of tri color composition technique.

The Automated Eichner Iris Photometer(AEIP) at the Korea Basic Science Center was tested for its function and the proper procedure for photographic photometry. The AEIP requires about three hours for reaching the electrical stability. When the iris is controlled automatically, the repeatability of density unit (DU) is accurate in the uncertainty of (0.0028∼0.0048 0.0028∼0.0048 )DU. The iris reading is found to be accurate within the mean error of 0.m05 0.m05 , which could be reduced to 0.m02 0.m02 by the manual control. To check the applicability of the AEIP. each two photographic plates for UBV colors which were taken by Dupuy and Zukauskas(l976) for the open cluster Byur 2, were measured by using the AEIP. and the photographic magnitudes and colors of the stars in Byur 2 were determined. discussing the previous results.