Dispersions of non-soluble ceramic particles in a metallic matrix can enhance the strength and heat resistance of materials. With the advent of mechanical alloying it became possible to put the theoretical concept into practice by incorporating very fine particles in a flirty uniform distribution into often oxidation- and corrosion- resistant metal matrices. e.g. superalloys. The present paper will give an overview about the mechanical alloying technique as a dry, high energy ball milling process for producing composite metal powders with a fine controlled microstructure. The common way is milling of a mixture of metallic and nonmetallic powders (e.g. oxides. carbides, nitrides, borides) in a high energy ball mill. The heavy mechanical deformation during milling causes also fracture of the ceramic particles to be distributed homogeneously by further milling. The mechanisms of the process are described. To obtain a homogeneous distribution of nano-sized dispersoids in a more ductile matrix (e.g. aluminium-or copper based alloys) a reaction milling is suitable. Dispersoid can be formed in a solid state reaction by introducing materials that react with the matrix either during milling or during a subsequent heat treatment. The pre-conditions for obtaining high quality materials, which require a homogeneous distribution of small dis-persoids, are: milling behaviour of the ductile phase (Al, Cu) will be improved by the additives (e.g. graphite), homogeneous introduction of the additives into the granules is possible and the additive reacts with the matrix or an alloying element to form hard particles that are inert with respect to the matrix also at elevated temperatures. The mechanism of the in-situ formation of dispersoids is described using copper-based alloys as an example. A comparison between the in-situ formation of dispersoids (TiC) in the copper matrix and the milling of Cu-TiC mixtures is given with respect to the microstructure and properties, obtained.

Recent developments in nanocrystalline and nanocomposite rare earth-transition metal magnets are reviewed and emphasis is placed on research work at IFW Dresden. Principal synthesis methods include high energy ball milling, melt spinning, mold casting and hydrogen assisted methods such as reactive milling and hydrogenation-disproportionation-desorption-recombination. These techniques are applied to NdFeB-, PrFeB- and SmCo-type systems with the aim to produce high remanence magnets with high coercivity. Concepts of maximizing the energy density in nanostructured magnets by either inducing a texture via anisotropic HDDR or hot deformation or enhancing the remanence via magnetic exchange coupling are evaluated. With respect to high temperature applications melt spun ribbons were prepared, which showed coercivities of up to 0.53 T at 50. Partially amorphous alloys were prepared by copper mold casting. The effect of transition metal content on the glass-forming ability and the magnetic properties was investigated. The alloy exhibits an amorphous structure shown by the corresponding diffraction pattern. A small substitution of Co by 2.5 at.% Fe results In the formation of Fe-rich crystallites embedded in the Nd-rich amorphous matrix. The Fe-rich crystallites show hard magnetic behaviour at room temperature with a coercivity value of about 0.4 T, relatively low saturation magnetization and a Curie temperature of 500 K.

Diphosphine dinuclear gold(I) complexes were synthesized from the reaction of bridged diphosphines and gold ions. As a bridged diphosphine, 1,2-bis(diphenylphosphino)metbane (dppm) or 1,1'-Bis(diphenylphosphino) ferrocene (dppf) was introduced. As anionic ligands, CI was first coordinated to Au, resulting in (diphosphine)(AuCl)2. Then, the ligand, SPh, was substituted for Cl in the chloride complex to give (diphosphine)(AuSPh)2. As a result, three digold complexes, (dppm)(AuCl)2. (I), (dppf)(AuCl)2. (II), and (dppf)(AuSPh2. (III) were prepared in this study. The thermal properties were investigated at first hand to confirm that the gold complexes were in fact formed. The digold complexes were decomposed above 200℃ while the ligand, dppm or dppf, melts under 180℃ The photoluminescence (PL) spectra of the spin-coated thin films showed the maximum peak at 590, 595, and 540nm for the complex, I, II, and III, respectively. These complexes were found to give the orange color phosphorescence. Therefore, these digold complexes can be candidates for orange-red phosphorescent materials in organic electroluminescent devices (OELD). Further studies on application of the complexes as a dopant in an emitting layer are in progress in our laboratory.

Recently social demand to achieve low fuel consumption and clean emission requires the development of new generation vehicle beyond the conventional vehicle concept. In this point, new generation vehicle is newly designed as electric vehicle, hybrid electric vehicle, fuel cell electric vehicle or 3 liter car etc. In order to develop new generation vehicle, it is very important to develop new materials and process technologies now. In this paper these new technologies are presented focusing on weight reduction specially. Steel body can be achieved 20-25% weight reduction by adoption of high strength steel and new process technologies, i.e tailored blank and hydroforming. Aluminium body can be achieved 40-50% weigt down by use of all aluminium monocoque body or aluminium space frame with aluminium panel. Plasitic composite body can be achieved 30% weight reduction comparing with conventional steel body.

To investigate the fabrication possibility of a polymer particle dispersed metal matrix composite, polytetrafluorothylene (PTFE) particles were incorporated into the Al by the powder metallurgy process. The characteristics of a PTFE/Al composite were evaluated by measuring the density and hardness, and analysis of XRD, FT-Raman and microstructure. And wear properties of these composites were evaluated under the dry wear condition. It was possible to obtain the PTFE particles stably dispersed Al matrix composites by the hot press process at the sintering temperature of . The wear coefficient of a PTFE/Al compoite decreased with increasing of the volume fraction of PTFE. The wear weight of a PTFE/Al composite increased with increasing of the volume fractionof PTFE in the range of 0~10 vol.%PTFE, and showed maximum value at 10 vol.%PTFE, and then decreased at 20vol.%PTFE.

Two way grid single-layer domes are of great advantage in fabrication and construction because of the simple fact that they have only four members at each junction. But, from a point of view of mechanics, the rectangular latticed pattern gives rise to a nonuniform rigidity-distribution in the circumferential direction. If the equivalent rigidity is considered in the axial direction of members, the in-plane equivalent shearing rigidity depends only on the in-plane bending rigidity of members and its value is very small in comparison to that of the in-plane equivalent stretching rigidity. It has a tendency to decrease buckling -strength of dome considerably by external force. But it is possible to increase buckling strength by the use of roofing covering materials connected to framework. In a case like this, shearing rigidity of roofing material increases buckling strength of the overall structure and can be designed economically from the viewpoint of practice. Therefore, the purpose of this paper, in Lamella dome and rectangular latticed dome that are a set of 2-way grid dome, is to clarify the effects of roofing covering materials for increasing of buckling strength of overall dome. Analysis method is based on FEM dealing with the geometrically nonlinear deflection problems. The conclusion were given as follows: 1. In case of Lamella domes which have nearly equal rigidity in the direction of circumference, the rigidity of roofing covering materials does not have a great influence on buckling-strength, but in rectangular latticed domes that has a clear periodicity of rigidity, the value of its buckling strength has a tendency to increase considerably with increasing rigidity of roofing covering materials 2. In case of rectangular latticed domes, as rise-span-ratio increases, models which is subjected to pressure -type-uniform loading than vertical-type-uniform loading are higher in the aspects of the increasing rate of buckling- strength according to the rate of shear reinforcement rigidity, but in case of Lamella dome, the condition of loading and rise-span-ratio do not have a great influence on the increasing rate of buckling strength according to the rate of shear reinforcement rigidity.