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        검색결과 193

        1.
        2024.07 KCI 등재 구독 인증기관 무료, 개인회원 유료
        많은 연구에 따르면 Tenebrio molitor은 유충 단계에서 플라스틱을 섭취할 수 있다고 보고되었다. 이 연구의 목적은 T. molitor 유충의 성장과 발달에 발포폴리스티렌 섭취가 미치는 영향을 조사하는 것이다. 밀기울을 섭취한 유충의 성장률은 발포폴리스티렌을 섭취한 유충의 성장률보다 더 좋았고(p < 0.001) 발포폴리스티렌을 섭취한 유 충의 번데기로 전환되는 기간은 밀기울을 섭취한 유충의 번데기로 전환되는 기간보다 더 빨랐다(p < 0.001). 하지만 두 처리구간 생존율은 유의미한 차이가 없었다(p = 0.786). 이 결과에 따르면 발포폴리스티렌을 섭취한 유충은 체중 감소와 짧은 발육기간이 특징이지만 생존하는 것에는 문제가 없었다. 따라서 우리는 T. molitor가 플라스틱 폐기물 의 지속 가능하고 친환경적인 제거를 위한 주요 자원이라는 결론을 내렸다.
        4,000원
        2.
        2024.07 KCI 등재 구독 인증기관 무료, 개인회원 유료
        거저리는 식품으로 사용되기 때문에 유충기가 오래 지속되면 더 좋다. 반면에 거저리의 개체수 유지를 위 해 성장을 가속화하기 위해서는 유충이 빨리 성충이 되면 더 좋다. 이 연구에서는 개체군 밀도가 거저리의 발달 시 간에 미치는 영향을 구명하였다. 이를 위해 상단 7 cm, 하단 5 cm, 높이 3 cm 크기의 용기를 사용했다. 거저리는 용기 당 1, 2, 5, 10, 20마리의 밀도로 용기에서 서식하였다. 용기에 밀기울 1 g을 넣고 거저리의 먹이 여부에 따라 라벨을 붙였다. 실험은 세 번 반복되었다. 모든 실험에서 개체군 밀도가 높을수록 유충에서 번데기로의 변환 시간이 짧았 지만 번데기에서 성충으로 변환되는 시간은 크게 다르지 않았다. 또한 먹이가 있는 그룹에서 번데기로의 변환 시간 이 단축되었지만, 성충으로 변환되는 시간에는 차이가 없었다. 이 연구 결과는 유충기를 연장하기 위해 더 낮은 밀 도가 필요하고 더 빠른 속도로 성충이 필요하다면 밀도가 더 높아야 한다는 것을 보여주었다. 결론적으로 거저리의 발달 시간은 개체수 밀도에 의해 제어할 수 있을 것이다.
        4,000원
        3.
        2024.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        One of the key challenges for the commercialization of carbon nanotube fibers (CNTFs) is their large-scale economic production. Among CNTF spinning methods, surfactant-based wet spinning is one of the promising techniques for mass producing CNTFs. Here, we investigated how the coagulation bath composition affects the spinnability and the properties of CNTFs in surfactant-based wet spinning. We used acetone, DMAc, ethanol, and IPA as coagulants and analyzed the relationship between coagulation bath composition and the properties of CNTFs in terms of kinetic and thermodynamic coagulation parameters. From a kinetic perspective, we found that a low mass transfer rate difference (MTRD) is favorable for wet spinning. Based on this finding, we mixed the coagulant bath with solvent in a proper ratio to reduce the MTRD, which generally improved the wet spinning. We also showed that the coagulation strength, a thermodynamic parameter, should be considered. We believe that our research can contribute to establishment of surfactant-based wet spinning of CNTFs.
        4,500원
        6.
        2024.04 구독 인증기관·개인회원 무료
        Haemaphysalis longicornis는 사람과 동물에게 여러 심각한 병원체를 전달하는 주요 매개체로, 한반도에 널리 분포하고 있다. H. longicornis는 Rickettsia spp., Borrelia spp., Francisella spp., Coxiella spp., 그리고 중증열성혈소판 감소증후군 바이러스 (SFTS virus) 등을 매개하는 것으로 알려져 있다. 국내에 서식하는 H. longicornis의 미생물 군집과 관련된 연구는 많이 진행되지 않은 것으로 확인되었다. 이 연구는 한반도 내 다양한 지역에서 채집된 H. longicornis의 미생물군집 다양성을 지역별, 성장 단계 및 성별에 따라 분석하였다. 2019년 6월부터 7월까지 질병관리청 권역별기후변화매개체감시거점센터 16개 지역에서 채집한 H. longicornis의 16S rRNA 유전자 V3-V4 영역을 PCR로 증폭 후 Illumina MiSeq 플랫폼으로 시퀀싱하였다. Qiime2를 활용한 미생물 다양성 분석을 통해 총 46개의 샘플에서 1,754,418개의 non-chimeric reads를 얻었으며, 평균 126개 의 operating taxonmic unit (OTU) 을 식별하여 총 1,398개의 OTU를 확인하였다. 대부분의 지역에서 Coxiella spp.가 우점종으로 나타났으며, 특히 Coxiella endosymbiont는 가장 높은 우점도를 보이며, Coxiella burnetii와 계통 발생 학적으로 유사한 것으로 확인되었다. 이 연구를 통해 분석된 결과는 각 지역의 H. longicornis 미생물군집 데이터 베이스 구축에 활용되었으며, 이를 통해 지역별 미생물군집의 특이성을 식별할 수 있게 하였다. 이는 한반도의 H. longicornis에 의한 질병 전파 연구와 이를 통한 공중보건 개선에 기여할 것으로 기대된다.
        7.
        2024.04 구독 인증기관·개인회원 무료
        The purpose of this study is to select various insect species for healing resources and develop a healing program in order to use insect as a healing agriculture. In this study, there are two kinds of breeding kit were developed, one for Gryllus bimaculatus and the other for Oxya chinensis sinuosa. Using these insect breeding kits, we conducted a survey of 60 children and the elderly. In the case of children, the results of the insect breeding satisfaction showed that 30.6% said that the sound of crickets was very good, and 11.1% said that it was good. In addition, the higher the child's awareness of insects, the higher the proportion of children who wanted to raise insects in the future. As a result of a survey of seniors, 45.2% do not like insects and 51.6% are not interested, meaning that most seniors are not very interested in insects. However, the emotions after breeding insects showed positive results, with 45.2% saying their personality became brighter, 48.4% reducing their anger, 48.4% relieving their irritation, 54.8% relieving loneliness, 58.1% feeling more responsible, and 51.6% developing intimacy.
        8.
        2023.12 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구는 환경교육용 보드게임 개발에 관한 연구다. 이를 위해 문헌 고찰과 전문가 인터뷰를 실시하여 핵심 메커니즘과 용어를 도출하였다. 또한, 타당도와 신뢰도 검증을 위하여 델파이 조사를 진행하였다. 연구 결과 9개 항목에 대하여 합의가 이뤄졌으며, 이를 기반으로 ‘수풀로 메이커’ 프로토타입을 제작하고 플레이테스트 를 진행하였다. 그 결과, 환경에 대한 관심, 생태복원의 개념, 탄소 중립에 대한 이해를 보여, 연구의 초기 목 적을 달성한 것으로 나타났다. 본 연구로 인해 개발된‘수풀로 메이커’는 아동과 청소년의 환경교육 교재의 역할 뿐만 아니라, 환경에 대한 깊이 있는 이해를 견인하고, 더 나아가 실천양식 변화의 잠재성을 키우는 역 할에 기여할 수 있을 것으로 기대한다.
        4,200원
        9.
        2023.11 구독 인증기관·개인회원 무료
        The need for the development of sustainable, efficient, and green radioactive waste disposal methods is emerging with the saturation of spent nuclear waste storage facilities in the Republic of Korea. Conventional radioactive waste management methods like using cement or glass have drawbacks such as high porosity, less chemical stability, high energy consumption, carbon dioxide production, and the generation of secondary wastes, etc. To address this gigantic issue of the planet, we have designed a study to explore the potential of alternative materials having easy processability, low carbon emissions and more chemical stability such as ceramic (hydroxyapatite, HAP) and alkali-activated materials (geopolymers, GP) to capture the simulated radioactive cobalt ions from the contaminated water and directly solidify them at low temperatures. Physical and mechanical properties of HAP alone and 15wt% GP incorporated HAP (HAP-GP- 15) composite were studied and compared. The surface of both materials was fully sorbed with an excess amount of Co(II) ions in the aqueous system. Co(II) sorbed powders were separated from aqueous media using a centrifuge machine operating at 5,000 RPM for 10 minutes and dried at 100°C for 8 hours. The dried powders were then placed in stainless steel molds, and shaped into cylindrical pellets using a uniaxial press at a pressure of 1 metric ton for 1 minute. The pellets were sintered at 1,100°C for 2 hours at a heating rate of 10°C/min. Following this, the water absorption, density, porosity, and compressive strength of the polished pellets were measured using standard methods. Results showed that HAP has a greater potential for decontamination and solidification of Co(II) due to its higher density (2.65 g/cm3 > 1.90 g/cm3), less open porosity (16.2±2.9% < 42.4 ±0.9%) and high compressive strength (82.1±10.2 MPa > 6.9±0.8 MPa) values at 1,100°C compared to that of HAP-GP-15. Nevertheless, further study with different constituent ratio of HAP and GP at various temperatures is required to fully optimize the HAP-GP matrix for waste solidifications.
        10.
        2023.11 구독 인증기관·개인회원 무료
        Molten chloride salts have received considerable research attention as potential nuclear fuel and coolant candidates for molten salt reactors. However, there are several challenges, especially for structural materials due to the selective dissolution of chromium (Cr) in the molten chloride salts environment. Understanding the compatibility of uranium (U), which is used as nuclear fuel in molten salt reactors, with Cr in molten chloride salts is critical for designing the molten salt reactor structure. Therefore, in this study, the cyclic voltammetry (CV) was used to investigate the electrochemical behaviors of U and Cr. The diffusion coefficients and formal potentials were obtained. The electrochemical properties of uranium and chromium were investigated by CV in molten NaCl-MgCl2 salt at 600°C. Tungsten rods for working and counter electrode, and Ag/AgCl for reference electrode were utilized in this experiment. UCl3 made from the chemical dissolution of U rods and CrCl2 (Sigma-Aldrich, 99.99%) were used. Diffusion coefficients (D) of U and Cr were calculated by measuring reduction peak current of U3+/U and Cr2+/Cr from CV curves and using the Berzins-Delahay equation; D (U3+/U) = 3.0×10-5 cm2s-1 and D (Cr2+/Cr) = 3.3×10-5 cm2s-1. The formal potentials were also calculated by using the reduction peak potential obtained from CV results; E0’ (U3+/U) = -1.173 V and E0’ (Cr2+/Cr) = -0.321 V. The ionization tendency was investigated by comparing each reduction peak potential. The reduction peak potential Ep,c was increasing order of Ep,c (U3+/U) < Ep,c (Cr2+/Cr) < Ep,c (U4+/U3+). It can be seen that in the presence of U4+ and Cr metals, the Cr in the alloy can dissolve into Cr2+, but in the presence of U3+ and Cr metals, the Cr in the alloy does not dissolve into Cr2+. By analyzing the CV curve, diffusion coefficients and formal standard potentials were obtained. The result of comparing reduction peak potentials suggests that the nuclear fuel using U4+ should be inhibited to prevent the selective dissolution of Cr.
        11.
        2023.11 구독 인증기관·개인회원 무료
        The ultimate objective of deep geological repositories is to achieve complete segregation of hazardous radioactive waste from the biosphere. Thus, given the possibility of leaks in the distant future, it is crucial to evaluate the capability of clay minerals to fulfill their promising role as both engineered and natural barriers. Selenium-79, a long-lived fission product originating from uranium- 235, holds significant importance due to its high mobility resulting from the predominant anionic form of selenium. To investigate the retardation behaviors of Se(IV) in clay media by sorption, a series of batch sorption experiments were conducted. The batch samples consisted of Se(IV) ions dissolved in 0.1 M NaCl solutions, along with clay minerals including kaolinite, montmorillonite, and illite-smectite mixed layers. The pH of the samples was also varied, reflecting the shift in the predominant selenium species from selenious acid to selenite ion as the environment can shift from slightly acidic to alkaline conditions. This alteration in pH concurrently promotes the competition of hydroxide ions for Se(IV) sorption on the mineral surface as the pH increases and impedes the selective attachment of selenium. The acquired experimental data were fitted through Langmuir and Freundlich sorption isotherms. From the Freundlich fit data, the distribution coefficient values of Se(IV) for kaolinite, montmorillonite, and illite-smectite mixed layer were derived, which exhibited a clear decrease from 91, 110, 62 L/kg at a pH of 3.2 to 16, 6.3, 12 L/kg at a pH of 7.5, respectively. These values derived over the pH range provide quantitative guidance essential for the safety assessment of clay mineral barriers, contributing to a more informed site selection process for deep geological repositories.
        12.
        2023.11 구독 인증기관·개인회원 무료
        This program aims to build a specialized and converged educational platform for the training of students in the back-end nuclear fuel cycle and cultivate integrated human resources encompassing majors, generations, and fields. To achieve this, we have established an infrastructure for integrated education and training in the radiochemistry and back-end nuclear fuel cycle and operated specialized educational courses linked with special lectures, experimental practices, and field trips. Firstly, to construct an integrated educational and training infrastructure for the back-end nuclear fuel cycle, we formed a committee of experts from both inside and outside the institution and built an advanced radiochemistry laboratory equipped with physical and chemical analysis instruments. Through a comprehensive educational program involving theory, experiments, and discussions, we have established an integrated curriculum across adjacent majors and interdisciplinary studies. We also operate short-term education and experimental training programs (e.g., summer and winter schools for the back-end nuclear fuel cycle). Secondly, the program has connected leading researchers domestically and internationally, as well as the next generation of scholars. The program offers long-term educational opportunities and internships targeting both undergraduate and graduate students. To support this, we continuously offer expert colloquiums and individual research internships. Through regular committee meetings and workshops, we focus on nurturing the integrated talents necessary for the back-end nuclear fuel cycle. Through this program, students from various fields are being trained as competent integrated human resources capable of addressing various issues in the back-end nuclear fuel cycle. It is expected that this will enable us to supply specialized technical personnel in the back-end nuclear field in line with mid-to-long-term demands.
        13.
        2023.11 구독 인증기관·개인회원 무료
        The domestic Pressurized Heavy Water Reactor (PWHR) nuclear power plant, Wolsong Unit 1, was permanently shut down on December 24, 2019. However, research on decommissioning has mainly focused on Pressurized Water Reactors (PWRs), with a notable absence of both domestic and international experience in the decommissioning of PHWRs. If proper business management such as radiation safety and waste is not performed, it can lead to increased business risks and costs in decommissioning. Therefore, the assessment of waste volume and cost, which provide fundamental data for the nuclear decommissioning process, is a crucial technical requirement before initiating the actual decommissioning of Wolsong Unit 1. Decommissioning radiation-contaminated structures and facilities presents significant challenges due to high radiation levels, making it difficult for workers to access these areas. Therefore, technology development should precede decommissioning process assessments and safety evaluations, facilitating the derivation of optimal decommissioning procedures and ensuring worker safety while enhancing the efficiency of decommissioning operations. In this study, we have developed a program to estimate decommissioning waste amounts for PHWRs, building upon prior research on PWR decommissioning projects while accounting for the specific design characteristics of PHWRs. To evaluate the amount of radioactive waste generated during decommissioning, we considered the characteristics of radioactive waste, disposal methods, packaging container specifications, and the criteria for the transfer of radioactive waste to disposal operators. Based on the derived algorithm, we conducted a detailed design and implemented the program. The proposed program is based on 3D modeling of the decommissioning components and the calculation of the Work Difficulty Factor (WDF), which is used to determine the time weighting factors for each task. Program users can select the cutting and packaging conditions for decommissioning components, estimate waste amount based on the chosen decommissioning method, and calculate costs using time weighting factors. It can be applied not only to PHWRs, but also to PWRs and non-nuclear fields, providing a flexible tool for optimizing decommissioning process.
        14.
        2023.11 구독 인증기관·개인회원 무료
        The sustainability of the nuclear power industry hinges increasingly on the safe, long-term disposal of radioactive waste. Despite significant innovations and advancements in nuclear fuel and reactor design, the quest for a permanent solution to handle accumulating radioactive waste has received comparatively less attention. Conventionally, two widely recognized solidification methods, namely cementation for low and intermediate-level waste and vitrification for high-level waste, have been favored due to their simplicity, affordability, and availability. Recently, geopolymers have emerged as an appealing alternative, gaining attention for their minimal carbon footprint, robust chemical and mechanical properties, cost-effectiveness, and capacity to immobilize a broad spectrum of radionuclides, including radioactive organic compounds. This study delves into the synthesis of metakaolin-based geopolymers tailored for the immobilization of fission products like cesium (Cs) and molybdenum (Mo). The investigation unfolded in two key steps. In the initial step, we optimized the alkali content to prevent the occurrence of efflorescence, a potential issue. Remarkably, as the Na2O/Al2O3 ratio increased from 0.82 to 1.54, we observed significant enhancements in both compressive strength (11.45 to 27.07 MPa) and density (up to 2.23 g/cm3). This suggests the importance of careful adjustment in achieving the desired geopolymer characteristics. The second phase involved the incorporation of 2wt% of Cs and Mo, both individually and as a mixture, into the geopolymer matrix. We prepared the GP paste, which was poured into cylindrical molds and cured at 60°C for one week. To scrutinize the crystallinity, phase purity, and bonding type of the developed matrix, we employed XRD and FTIR techniques. Additionally, we conducted standard compressive strength tests (following ASTM C39/C39M-17b) to assess the stacking durability and robustness of the developed waste form, vital for storage, handling, transportation, and disposal in a deep geological repository. Furthermore, to evaluate the chemical durability, diffusivity and leaching of the GP waste matrix, we employed the ASTM standard Product Consistency Test (PCT: C 1285-02) and American nuclear society’s devised leaching test (ANS 16.1). It is noteworthy that the introduction of Cs and Cs/Mo in the GP matrix led to a reduction of more than 50% and 60% in compressive strength, respectively. This outcome may be attributed to the interference of Cs and Mo with the geopolymerization process, potentially causing the formation of new phases. However, it is crucial to emphasize that both developed matrices exhibited an acceptable normalized leaching rate of less than 10-5 g·m-2·d-1. This finding underscores the promising potential of the GP matrix for the immobilization of cationic and anionic radioactive species, paving the way for more sustainable nuclear waste management practices.
        15.
        2023.10 구독 인증기관·개인회원 무료
        금번 연구를 통해 외래산림해충 확산 분석 플랫폼 K-SDM (K-SDM)의 해충 분포 기능이 개발되었다. 해충 분포를 보여주는 기능은 2가지로 구현되며, 조사 자료를 바탕으로 현재 국내의 해충 분포를 나타내는 “외래산림 해충분포”기능과 데이터를 분석하여 예측되는 미래의 해충 분포를 제공하는 “외래산림해충예측”기능이 있다. “외래산림해충분포”는 조사자에 의해 현장에서 구축된 DB 현황을 지도상에 수치로 나타내며, 입력 기간, 해충 종 별로 구분이 가능하여 원하는 해충종의 분포를 선택하여 볼 수 있다. 지도 좌측에는 각 도별로 조사된 해충 개체수의 통계를 도표로 제공하여 수치상으로도 해충 분포를 파악할 수 있다. “외래산림해충예측”은 DB를 분석 하고 미래 기후 시나리오를 적용하여 도출한 미래의 해충 예측 분포도를 사용자에게 제공되며, 미리보기 이미지 와 함께 원본자료가 첨부되어 좀 더 자세한 정보를 열람할 수 있다. 본 플랫폼의 해충 분포 기능은 최근 기후변화 등으로 외래산림해충의 발생이 증가하는 추세에 맞춰 이들의 현재 분포와 미래의 분포양상을 조기 파악하여 이를 통한 추후 조기 방제 및 대응책 마련 등에 크게 기여할 것으로 기대된다.
        16.
        2023.10 구독 인증기관·개인회원 무료
        최근 국내에서는 꿀벌 대량소실 현상이 2022년부터 전국적으로 발생하고 있다. 우리나라 뿐 만 아니라, 전세계 적으로 양봉산업에 큰 위협이 되고 있는 봉군붕괴현상은 2016년 미국에서 세계 최초로 보고되었다. 국내에서는 2022년 민관 합동조사 결과, 이상기온, 응애, 말벌 등이 주요 원인으로 지목되었다. 대량소실 현상을 보인 양봉농 가와 정상 농가의 병원체 검출 비교 결과, 유의성있게 검출이 증가되는 병원체는 발견되지 않았다. 그러나, Tyrophagus mite, Trypanosome, Lake Sinai virus, Apis mellifera filamentous virus 등의 신종 응애, 원충 및 바이러 스 감염이 추가로 확인되었다. 국내에서 새롭게 감염이 확인된 기생충과 병원체가 대량소실, 나아가 봉군붕괴현 상에 직간접적으로 영향을 주었을 것으로 사료되며, 지속적인 조사와 연구개발을 통해 기후등 환경변화에 따른 신종 질병 검색과 대책을 마련해야 할 것이다.
        17.
        2023.09 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        Studies on automatic scoring systems in writing assessments have also evaluated the relationship between human and machine scores for the reliability of automated essay scoring systems. This study investigated the magnitudes of indices for inter-rater agreement and discrepancy, especially regarding human and machine scoring, in writing assessment. The mean of the overall population correlation between automated and human scoring in essay writing was .78. The overall common d effect size was 0.001. Results from this meta-analysis indicated a strong relationship with no discrepancies between automated and human scoring. Both the I2 and Q values suggested that the population correlation values studied seemed to be heterogeneous, in contrast to homogenous d effect sizes. Therefore, it is necessary to investigate the sources of the between-studies variations for r correlations. Practical implications for ways of reporting results of automatic-scoring systems research and limitations of the study are also discussed.
        5,500원
        18.
        2023.06 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        To ensure radiological safety margin in the transport and storage of spent nuclear fuel, it is crucial to perform source term and shielding analyses in advance from the perspective of conservation. When performing source term analysis on UO2 fuel, which is mostly used in commercial nuclear power plants, uranium and oxygen are basically considered to be the initial materials of the new fuel. However, the presence of impurities in the fuel and structural materials of the fuel assembly may influence the source term and shielding analyses. The impurities could be radioactive materials or the stable materials that are activated by irradiation during reactor power operation. As measuring the impurity concentration levels in the fuel and structural materials can be challenging, publicly available information on impurity concentration levels is used as a reference in this evaluation. To assess the effect of impurities, the results of the source term and shielding analyses were compared depending on whether the assumed impurity concentration is considered. For the shielding analysis, generic cask design data developed by KEPCO-E&C was utilized.
        4,300원
        19.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        주방세제의 진딧물 살충효과와 분국화 생육에 미치는 영향 을 알아보기 위해 실험을 수행하였다. 복숭아혹진딧물과 목화 진딧물을 대상으로 주방세제 100, 200, 400배액 단용처리와 주방세제 400배액 100mL에 소주 10mL 또는 20mL를 혼용 하여 분무 처리하였다. 그 결과 주방세제 400배 이하의 모든 농도에서 복숭아혹진딧물은 85%, 목화진딧물은 90%의 살충 률을 보였다. 주방세제와 소주 혼용처리에 의한 살충효과 상 승은 보이지 않았다. 하우스안에서 진딧물이 많이 발생한 분 국화 잎에 400배액 이하의 농도로 3일 간격으로 2회 처리함 으로써 90% 이상의 진딧물이 감소되는 효과를 얻을 수 있었 다. 또한 분국화를 재배하면서 3~4일 간격으로 5주간 지속적 으로 주방세제를 처리했을 때, 대조구에서는 90% 잎에서 진 딧물이 발생한데 비해, 모든 주방세제 단독 처리구에서는 발 생율이 15% 이하로 낮게 유지되었다. 또한 국화의 생체중, 초 장, 엽수는 주방세제 농도가 높아질수록 조금씩 낮아지는 경 향이었으나, 초폭이나 분지수에서는 차이가 없었다. 그러나 주방세제 200배 이하의 농도에서는 국화의 잎이 갈변되거나 꽃잎 끝이 백화되는 약해가 관찰되었다.
        4,000원
        20.
        2023.05 구독 인증기관·개인회원 무료
        Th(IV) is a stable actinide that can act as a chemical analogue of U(IV) and Pu(IV), which are important radionuclides in safety assessments of deep geological repositories (DGR). Therefore, to understand the geochemical behaviour of U(IV) and Pu(IV), batch sorption of Th(IV) onto crystalline rocks were performed in oxidising conditions. The distribution coefficients (Kd) of Th(IV) were of particular interest. Gyeongju fresh groundwater (GF) and Gyeongju brackish groundwater (GB) were obtained at the Gyeongju Low and Intermediate Level Radioactive Waste (LILW) Disposal Facility. Crystalline granite (gr) and biotite gneiss (bg) were collected in Gyeongju and Gwacheon respectively and were grounded to a particle size smaller than 150 μm. Sorption samples were continuously shaken for 7 days under 200 rpm at 25°C. The liquid-to-solid ratio (V/m) was 200 L·kg-1. Th(IV) concentrations of the sorption samples were determined by UV-Vis-NIR absorption colorimetry from the formation of Th(IV)-arsenazo III complexes. Although the method allowed the initial Th(IV) concentrations to be determined, the final Th(IV) concentrations fell below the limit of detection (LOD), 6.27×10-9 mol·L-1. Taking the LOD as the final concentrations, conservative Kd were calculated to be 4,410 L·kg-1 for GF-gr and GF-bg, and 7,830 L·kg-1 for GB-gr and GB-bg. The result indicates a strong sorption affinity of Th(IV) onto granite and biotite gneiss within Gyeongju groundwater, suggesting a similar behaviour for U(IV) and Pu(IV). Furthermore, comparison of the conservative Kd obtained from the experiment were compared with existing Kd values of Th(IV). Such analysis and comparison of Th(IV) Kd in various types of groundwater could help locate the optimal site for a DGR in South Korea.
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