This study aimed to assess the impact of livestock excreta discharged from an Intensive Livestock Farming Area (ILFA) on river water quality during a rainfall event. The Bangcho River, which is one of the 7 tributaries in the Cheongmi River watershed, was the study site. The Cheongmi River watershed is the second largest area for livestock excreta discharge in Korea. Our results clearly showed that, during the rainfall event, the water quality of the Bangcho River was severely deteriorated due to the COD, NH4-N, T-N, PO4-P, T-P, and heavy metals (Cu, Zn, and Mn) in the run-off from nearby farmlands, where the soil comprised composted manure and unmanaged livestock excreta. In addition, stable isotope analysis revealed that most of nitrogen (NH4-N and NO3-N) in the run-off was from the ammonium and nitrate in the livestock excreta. The values of δ15NNH4 and δ15NNO3 for the Bangcho River water sample, which was obtained from the downstream of mixing zone for run-off water, were lower than those for the run-off water. This indicates that there were other nitrogen sources upstream river in the river. It was assumed from δ15NNH4 and δ15NNO3 stable isotope analyses that these other nitrogen sources were naturally occurring soil nitrogen, nitrogen from chemical fertilizers, sewage, and livestock excreta. Therefore, the use of physicochemical characteristics and nitrogen stable isotopes in the water quality impact assessment enabled more effective analysis of nitrogen pollution from an ILFA during rainfall events.

The objective of this study was to estimate air quality trends in the study area by surveying monthly and seasonal concentration trends. To do this, the mass concentration of PM10 samples and the metals, ions, and total carbon in the PM10 were analyzed. The mean concentration of PM10 was 33.9 ㎍/㎥. The composition of PM10 was 39.2% ionic species, 5.1% metallic species, and 26.6% carbonic species (EC and OC). Ionic species, especially sulfate, ammonium, and nitrate, were the most abundant in the PM10 and had a high correlation coefficient with PM10. Seasonal variation of PM10 showed a similar pattern to those of ionic and metallic species. with high concentration during the winter and spring seasons. PM10 showed high correlation with the ionic species NO3 - and NH4 +. In addition, NH4 + was highly correlated with SO4 2- and NO3 -. We obtained four factors through factor analysis and determined the pollution sources using the United States Environmental Protection Agency(U.S. EPA) pollution profile. The first factor accounted for 51.1% of PM10 from complex sources, that is, soil, motor vehicles, and secondary particles: the second factor indicated marine sources; the third factor, industry-related sources; and the last factor, heating-related sources. However, the pollution profile used in this study may be somewhat different from the actual situation in Korea because it was from US EPA. Therefore, to more accurately estimate the pollutants present, it is necessary to create a pollution profile for Korea.