Dry storage of nuclear fuel is compromised by threats to the cladding integrity, such as creep and hydride reorientation. To predict these phenomena, spent fuel simulation codes have been developed. In spent fuel simulation, temperature information is the most influential factor for creep and hydride formation. Traditional fuel simulation codes required a user-defined temperature history input which is given by separate thermal analysis. Moreover, geometric changes in nuclear fuel, such as creep, can alter the cask’s internal subchannels, thereby changing the thermal analysis. This necessitates the development of a coupled thermal and nuclear fuel analysis code. In this study, we integrated the 2D FDM nuclear fuel code GIFT developed at SNU with COBRA -SFS. Using this, we analyzed spent nuclear stored in TN-24P dry storage cask over several decades and identified conditions posing threats due to phenomena like creep and hydrogen reorientation, represented by the burnup and peak cladding temperature at the start of dry storage. We also investigated the safety zone of spent nuclear fuel based on burnup and wet storage duration using decay heat.

Hydride reorientation is widely known as one of the major degradation mechanisms in Zirconium cladding during dry storage. Some previous theoretical models for hydride reorientation used assumption of an ideal radial basal pole orientation for HCP structure of Zirconium cladding. Under this assumption, circumferential hydride was considered to precipitate in the basal plane while radial hydride was considered to precipitate in the prismatic plane, thereby giving energetical penalty on thermodynamical precipitation of radial hydrides. However, in reality, reactor-grade Zirconium cladding exhibits average 30° tilted texture, adding complexity to the hydride precipitation mechanism. In this study, reactor-grade Zirconium cladding was charged with hydrogen and hydride reorientation -treated specimens were fabricated. Microstructural characterization of hydrides was conducted via following three methods in terms of interface and stored energy. And this study aimed to compare these characteristics between circumferential and radial hydrides. Using Electron Back Scattered Diffraction (EBSD), the interface was investigated assuming that interface lies parallel to the axial axis of the tube. These were further validated with Transmission Electron Microscope (TEM). In addition, Differential Scanning Calorimetry (DSC) analysis was conducted to calculate the stored energy. This investigation is expected to establish fundamental understanding of how hydrides precipitate in Zirconium cladding with different orientations. And it will also increase the predictability of radial hydride formation and help understanding the mechanical behavior of Zirconium cladding with radial hydrides.

As the zircaloy cladding absorbs an excessive amount of hydrogen and cooled down under hoop stress, radial hydride may be precipitated by hydride reorientation phenomenon. There have been many previous studies about the threshold stress of the reorientation, but it is known that the quantitative degree of hydride reorientation rather than the threshold is important for the prediction of mechanical properties. A thermodynamic model for Radial Hydride Fraction (RHF) prediction has been developed in this study. The model calculates RHF with respect to temperature, cooling rate, hydrogen content, and applied stresses. Once the cooling rate is given, the solid solution concentration at each temperature is determined by Hydrogen-Nucleation-Growth-Dissolution model. Subsequently, the increment of radial hydride is derived by nucleation and growth theory. The code based on the thermodynamic theory can provide the prediction of RHF under hoop stress, as well as a change in precipitation behavior over time. RHF of the zircaloy cladding in long-term dry storage can be obtained by the implementation of the code and the degradation of the cladding is directly estimated according to the correlation between RHF and mechanical properties. Ongoing experimental validation of the developed model is discussed.

This study reassess safety margin of the current Peak Cladding Temperature (PCT) limit of dry storage in terms of hydrogen migration by predicting axial hydrogen diffusion throughout dry storage with respect to wet storage time and average burnup. Applying the hydride nucleation, growth, and dissolution model, an axial finite difference method code for thermal diffusion of hydrogen in zirconium alloy was developed and validated against past experiments. The developed model has been implemented in GIFT – a nuclear fuel analysis code developed by Seoul National University. Various discharge burnups and wet storage time relevant to spent fuel characteristics of Korea were simulated. The result shows that that the amount of hydrogen migrated towards the axial end during dry storage for reference PWR spent fuel is limited to ~50 wppm. This result demonstrates that the current PCT margin is sufficient in terms of hydrogen migration.

Since SMR’s reduced reactor radius results in higher neutron leakage, SMR operates at a relatively lower discharge burnup level than traditional Light Water Reactors (LWRs). It may result in larger spent fuel amounts for SMRs. Furthermore, recent studies demonstrated that NuScale reactor will generate a significantly higher volume of low- and intermediate-level waste owing to components located near the active core including the core barrel and the neutron reflector. For spent nuclear fuel simulation, FRAPCON-4.0 was updated. Major modifications were made for fission and decay gas release, pellet swelling, cladding creep, axial temperature distribution, corrosion, and extended simulation time covering from steady-state to dry storage. In this study, typical 17×17 PWR fuel (60 MWd/kgU) and NuScale Power Module (36 MWd/kgU) was compared. NuFuel-HTP2™ fuel assembly, which has a half-length of proven LWR fuel, was employed. Owing to the lower discharge burnup and operating temperature, the maximum hydrogen pickup was 73 wppm and the maximum hoop stress was ~25 MPa. Therefore, hydride reorientation issue is irrelevant to SMR spent fuel. In this context, the current regulatory limit for dry storage (i.e. 400°C and 90 MPa) can be significantly alleviated for LWR-based SMRs. The increased safety margin for SMR spent fuel may compensate high spent fuel management cost of SMRs incurred by an increased amount. The comprehensive analysis on SMR spent fuel management implications are discussed based on simulated SMR fuel characteristics.

Hydride reorientation is one of the major concerns for cladding integrity during dry storage. In this study, mechanical property of post-reorientation cladding was investigated according to the morphology and amount of the hydrides. Cladding peak temperature limit 400°C was suggested by U.S. NRC in concern of cladding creep and hydride reorientation. In line with this regulatory limit, hydride reorientation was conducted during cool-down process from the maximum temperature of 400°C, using constant internal pressurization method. The specimens were charged for hydrogen from 100 to 1,000 wppm, and various pressures range of 7.5-18.5 MPa were applied. The morphology was examined by optical microscopy. Radial hydride fraction (RHF) and radial hydride continuous path (RHCP) were calculated using image analysis software PROPHET. Finally, strain energy density (SED) was investigated via ring compress tests and the hydrogen concentration was analyzed. The result shows that when RHF is higher than 5%, SED exponentially decreases with RHF. For RHF less than 5%, SED was primarily affected by the total amount of hydrogen. Shortened length of radial hydrides with the presence of circumferential hydrides may block the radial propagation of crack. The result implies that lower burnup spent fuel with lower hydrogen concentration may be more vulnerable in terms of radial hydride compared to higher burnup fuel.

이 연구는 융합교육 프로그램을 활용하여 중학교 2학년 168명을 대상으로 기술·가정교육의 필요성, 이해도, 흥미도, 참여도와 모둠협동학습에 의한 발표력, 리더십 향상도, 교육효과를 그리고, 융합교육과 융합교육의 효과에 대하여 사전 실태조사를 하여 기술·가정 교과수업에 학생들이 가장 원하는 수업형태를 조사하고 다른 교과와 연계시켜 지도함으로써 융합적 사고와 스스로 문제를 해결할 수 있는 능력인 자기주도적 학습 마인드를 기르는데 목적이 있다.