Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated Ca(OH)2 solutions containing NaCl or Na2SO4. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.

Formation of disinfection by-products (DBPs) including trihalomethans (THMs) and haloacetic acids (HAAs) from chlorination of six different species (Chlorella vulgaris, Scenedesmus sp., Anabaena cylindrical, Microcystis aeruginosa, Asterionella formosa and Aulacoseira sp.) of algal extracellular organic matter (EOM). The EOM characteristics evaluation of six algal species reaching at the stationary phase in the growth curve showed most of its SUVA254 showed below 1 and this means hydrophilic organic matter is much higher than hydrophobic organic matter. Chloroform formation potential (CFFP), dichloroacetic acid formation potential (DCAAFP) and trichloroacetic acid formation potential (TCAAFP) were mainly composed of THMFP and HAAFP in the EOM of various algal species. In the case of THMFP/DOC and HAAFP/DOC values, EOM of blue-green algae has appeared highest and EOM of green algae and diatom in order. THMFP/DOC was higher than HAAFP/DOC in EOM of blue-green algae. In comparison of formation potential by unit DOC composed of HAAFP in algal species EOM, DCAAFP/DOC was 1.5 times to 7.5 time higher than TCAAFP/DOC in the EOM of blue-green algae, while DCAAFP/DOC was found to be relatively high compared to TCAAFP/DOC in the EOM of green algae and diatom.

본 연구에서는 콘크리트내로 침투하는 염소이온을 모니터링하기 위하여, 스크린프리트 기법으로 염소이온 반응형 부식센서를 개발하고, 센서의 세선 수가 부식반응도 및 민감도에 미치는 영향을 실험을 통하여 정량적으로 분석하였다. 개발된 부식센서를 이용하여 염소이온량에 따라 부식 반응도을 확인하였으며, 센서의 파괴정도에 따른 저항변화에서는 단선형 센서보다 다선형 센서에서 큰 저항 변화를 나타내었다. 또한, 부식센서는 NaCl 수용액의 농도가 높은 만큼 센서의 저항변화가 크고, 콘크리트 내에서 센서 종류에 따른 부식저항은 단선형보다 다선형에서 민감도가 높게 나타났으며, 센서의 매설깊이가 클수록 저항변화 사이클 (cycle)은 증가하였다. 이상의 결과로, 본 연구에서 개발된 부식센서는 염분에 대한 부식반응과 민감도, 저항의 변화를 감지할 수 있었으며, 특히 7세선이 우수한 결과를 나타내어, 염분의 침투정도를 모니터링 하는데 가장 적합하다고 판단된다.

Traditionally main driving force of chloride penetration in concrete have been regarded as diffusion, however, large construction such as tunnel elements and foundations for bridges can be placed on large sea water depths where the water pressure is fairly different from the pressure in the splash zone. Moreover, hydrostatic pressure increases in proportional to measured depth from the surface of water because of the increasing weight of water exerting downward force from above. In this study, new experiment method to estimate chloride penetration of concrete under water pressure is introduced. When the life length for such a concrete structure on a large sea water depth is estimated using the normally used models, the concrete test specimen

Chloride adsorption is very ambiguous in the mechanisms of deterioration of concrete exposed to marine environment. Author suggested that chloride adsorption with cement hydrates depends on pH value of pore solution. However, adsorbed chloride ions can be dissolved in concrete under the combined deterioration environment of carbonation and chloride penetration. In the condition, the most crucial issue is the amount of dissolved chloride ions in cement paste due to carbonation. In this study, dynamics experiment was designed to quantify the effect of CaCO3 on chloride adsorption. Based on the experiment results, the final goal of this study is to develop integrated system for predicting chloride adsorption /desorption behaviors.

To predict the characteristics of chloride ion penetration in the concrete and rebar corrosion prediction for chloride ion permeation, it is important to understand the chloride ion diffusion coefficient. It is possible that the reinforced concrete structures can be predicted accurately by the profile of the position of the rebar chloride ions using a chloride ion diffusion coefficient. On this study, analysis of chloride ion diffusion coefficient experimented in Korea and the effect of changes in the surface chloride ions concentration on chloride attacked durability design was analyzed

콘크리트는 물시멘트비에 상응하는 공극을 가지게 되며, 공극을 통한 염소이온의 확산을 평가하기 위하여 해안가 폭로 및 해수 침지실험이 널리 사용된다. 이상의 실험은 경우에 따라서 다년간의 시간을 요하는 경우도 있어, 최근에는 전기 영동법에 기초한 급속 염소이온 확산시험을 실시하는 경우가 많으나, 그 값이 폭로 및 침지 시험에서 얻은 값과 상이한 경우가 많아 데이터의 실용성을 높이기 위하여 그 원인 규명이 절실한 실정이다. 본 연구에서는 평가 방법으로써 Nernst-Einstein의 식을 통한 염화물 이온 이동계수의 산정방법을 사용하였으며, NT BUILD 492법 및 해수 침지실험을 통한 확산 특성과 비교하여 값의 차이에 대하여 고찰하였다. 그 결과 실험인자의 변화가 염소이온 확산에 미치는 영향은 미비한 것으로 평가되어져 실험조건에서 발생하는 영향은 거의 없는 것으로 규명되었으며, NT BUILD 492법과도 거의 동일한 값이 구해졌다. 침지실험 결과와의 상이는 염소이온 확산에서 경계조건의 차이 및 염소이온의 시멘트 수화물과의 고정화에 의한 것으로 판단되어진다.

최근 고유동 콘크리트(High Fluidity Concrete 이하 HFC)에 대한 연구는 많은 시공사례와 함께 진행되고 있지만, 콘크리트의 내구성능을 평가하는 항목 중 하나인 염소이온 침투에 대한 연구는 미비하며, 기존의 내구성관련 연구는 고강도 이상(40MPa)연구됨에 따라 보통강도 고유동 콘크리트의 염소이온 침투에 관한 연구는 찾아보기 어려운 실정이다. 따라서 본 연구에서는 석회석 미분말을 혼합한 보통강도 HFC를 제조하여 콘크리트의 공극구조 및 염소이온 침투특성을 분석․고찰 하였다. 실험결과 석회석 미분말을 혼합한 2성분계 및 3성분계 고유동 콘크리트의 경우 콘크리트의 공극 크기는 0.005∼0.05 ㎛ 사이에서 가장 많이 분포 하고 있으며, 석회석 미분말의 혼합률이 증가할수록 평균 공극 직경은 커지는 것으로 나타났다. 또한 석회석 미분말의 혼합률이 증가할수록 염소이온 침투깊이 및 확산계수는 증가하는 경향이 나타나며, 확산계수는 압축강도 및 평균공극직경 사이의 상관관계에서 결정계수 0.90 이상의 양호한 상관성이 있었다.

염해는 구조물 열화의 원인이 되는 주요인자 중의 하나이다. 고속도로 교량에 있어서 제설제는 동결작용으로 인한 표면 스켈링을 매우 증가시킨다. 열화된 콘크리트는 염해환경에서 내구성이 저하된다. 본 연구에서는 147개 교량의 진단보고서를 조사하고 21개 교량 바닥판의 코어샘플에 대하여 실험과 분석을 실시하였다. 시험결과는 콘크리트 바닥판의 피복두께는 공용수명 30년 이상을 사용하려면 8cm이상이 필요하다는 것을 보여준다.

질산성질소와 염소이온은 지하수에서 흔히 나타나는 항목으로서 농약의 사용이나 도시화 등에 의하여 주로 발생한다. 일반적으로 동일 지점의 지하수 수질 자료는 관측망의 경우를 제외하고는 샘플의 수가 제한적이기 때문에 시계열 자료를 활용한 추세 평가에 한계가 있다. 본 연구에서는 제주도 수계의 분포 특성, 저지대의 낮은 지형 경사, 수리적 특성 및 다공질 지질 특성 등을 고려하여 간격의 격자를 작성하고 격자내에 포함된 수질검사 자료를 모두 취합하여 시계열 데

The formation characteristics of trihalomethanes (THMs) and haloacetic acids (HAAs) were investigated in chlorination of raw water of different organic mallet characteristics. The samples used in this study were hydrophobic (N-HPO) and hydrophilic fraction (N-HPI) (which were concentrated and separated from Nakdong river water), and humic acid (HA) (which is known as a strong hydrophobic acid) as a reference organic matter, the specific UV absorbance (SUVA) of which was 2.19, 1.15 and 7.92, respectively. With increasing chlorine contact time, THMFP and HAAFP (the formation potential of THMs and HAAs) increased, but their increase was different depending on the organic mallet characteristics (i.e., for N-HPI, THMFP was higher than HAAFP, but the inverse result was obtained for N-HPO and HA and the ratio between them was greater for HA), and the mainly formed chemical species were CHCI3 in case of THMs and dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA) in case of HAAs for N-HPO and HA (and the ratios of CHCI3 to total THMs and DCAA and TCAA to total HAAs for HA were higher than those for N-HPO), but for N-HPI, the ratio of brominated THMs was a little higher than that of CHCI3 and the ratio of DCAA and TCAA to total HAAs was lower than that of N-HPO, although they are main chemical species in case of HAAs. Comparing THMFP and HAAFP with the increase in bromide concentration added with those in not adding it, the former increased greatly and its increase was higher for the organic mallet with stronger hydrophobicity, but the latter was lower for N-HPO and N-HPI and was similar for HA. The main chemical species with increasing bromide concentration were CHBt3 in case of THMs regardless of organic matter characteristics, and dibromoacetic acid (DBAA) for N-HPO and N-HPI, DBAA and tribromoacetic acid (TBAA) for HA in case of HAAs. With increasing reaction temperature and pH, THMFP and HAAFP increased for the former, but for the latter, THMFP increased and HAAFP decreased, although the rate of increase or decrease was different with organic mallet characteristics.

In order to grasp a characterization of low boiling point chlorinated organic compounds, this study which were carried out at the 8 stations for precipitation samples in the Pusan area during the period from February to September 1995. As a result, low boiling chlorinated organic compounds were estimated that it was dissolved by a portion of precipitation, and it be able to shift at the surface of the each. Concentration of low boiling point chlorinated organic compounds in precipitation are increased with increase of temperature, and estimated that air pollution compounds of as a rule in atmosphere.

The regiospecific potential for the reductive dechlorination of 2-, 3-, 4-, 2,3-, 2,4-, and 3,4-chlorophenols (CPs) was studied in mono- and di-CP(DCP) adapted sediment slurries(10% solids). Freshwater sediments adapted to transform 2-CP dechlorinated all tested mono- and di-CPs except 4-CP without a lag period. Adaptation to 2-CP, thus, enhanced the onset of dechlorination of 3-CP and all ortho-substituted CPs tested. Sediment adapted to transform 3-CP dechlorinated all tested CPs, except 4-CP and 2,4-DCP, without a lag period. Sediments adapted lo individual DCPs (2,3-, 2,4-, and 3,4-DCP) exhibited dechlorination (no lag phase) of 2-CP, 2,3-, 2,4-, and 3.4-DCP. Interestingly, meta-cleavage of 3,4-DCP in all tested adapted sediment occurred, while para-cleavage occurred in 3,4-DCP adapted sediment. Sediments adapted to dechlorinate ortho and meta-chlorines exhibited a preference for meta following ortho-cleavage, but not for para-cleavage, while the preference for reductive dechlorination was ortho > meta > para for mono-CPs and ortho > para > meta for DCPs in unadapted freshwater anoxic sediments.

The COD values and chloride ion concentrations of the Taewha river flowing through Ulsan area were determined along the main stream and the relationships between CODs and chloride ion concentrations were described. The results showed that the middle-upper stream and downstream of the Taewha river were polluted deeply with municipal sewage and self-purification occured in the middle-downstream of the river. When domestic sewage is a main source of pollutants, and is especially the only source of chloride in the stream water, the ratio of COD/[Cl^-] will be utilizable as a measure of self-purification of the stream.