To reduce the environmental burden caused by the disposal of spent nuclear fuel and maximize the utilization of the repository facility, waste burden minimization technology is currently being developed at the Korea Atomic Energy Research Institute (KEARI). The technology includes a nuclide management process that can maximize disposal efficiency by selectively separating and collecting major nuclides in spent nuclear fuel. In addition, for efficient storage facility utilization, the short-term decay heat generated by spent nuclear fuel must be removed from the waste stream. To minimize the short-term thermal load on the repository facility, it is necessary to separate heat generating nuclides such as Cs-137 and Sr-90 from the spent fuel. In particular, Sr-90 must be separated because it generates high heat during the decay process. KAERI has developed a technology for separating Sr nuclides from Group II nuclides separated through the nuclide management process. In this study, we prepared Sr ceramic waste form, SrTiO3, by using the solid-state reaction method for long-term storage for the decay of separated Sr nuclides and evaluated the physicochemical properties of the waste form. Also, the radiological and thermal characteristics of the Sr waste form were evaluated by predicting the composition of Sr nuclides separated through the nuclide management process, and the estimation of centerline temperature was carried out using the experimental thermal data and steady state conduction equation in a long and solid cylinder type waste form. These results provided fundamental data for long-term storage and management of Sr waste.

The International Atomic Energy Agency recommends the deep geological disposal system as one of the disposal methods for high-level radioactive waste (HLW), such as spent nuclear fuel. The deep geological disposal system disposes of HLW in a deep and stable geological formation to isolate the HLW from the human biosphere and restrict the inflow of radionuclides into the ecosystem. It mainly consists of an engineered barrier and a natural barrier. Safety evaluation using a numerical model has been performed primarily to evaluate the buffer’s long-term stability. However, although the gas generation rate input for long-term stability evaluation is the critical factor that has the most significant influence on the long-term hydraulic-mechanical behavior of the buffer, in-depth research and experimental data are lacking. In this study, the gas generation rate on the interface between the disposal canister and the buffer material, a component of the engineered barrier, was mainly studied. Gas can be generated between the disposal canister and the buffer material due to various causes such as anaerobic corrosion of the disposal canister metal, organic matter decomposition, radiation decomposition, and steam generation due to high temperature. The generation of gas in such a disposal environment increases the pore gas pressure in the buffer and causes internal cracks. The occurred cracks increase the intrinsic permeability of the buffer, which leads to a decrease in the primary performance of the buffer. For this reason, it is essential to apply the appropriate gas generation rate according to the disposal condition and buffer material for accurate long-term stability analysis. Therefore, the theoretical models regarding the estimation of gas generation were summarized through a literature study. The amount of gas generated was estimated according to the disposal environment and material of the disposal canister. It is expected that estimated values might be used to estimate the long-term stability analysis of buffer performance according to the disposal condition.

Deep geologic disposal of high-level nuclear wastes (HLW) requires intensive monitoring instrumentations to ensure long-term security. Acoustic emission (AE) method is considered as an effective method to monitor the mechanical degradation of natural rock and man-made concrete structures. The objectives of this study are (a) to identify the AE characteristics emitted from concretes as concrete materials under different types of loading, (b) to suggest AE parametric criteria to determine loading types and estimate the failure stage, and finally (c) to examine the feasibility of using AE method for real-time monitoring of geologic disposal system of HLW. This study performs a series of the mechanical experiments on concrete samples simultaneously with AE monitoring, including the uniaxial compression test (UCT), Brazilian tensile test (BTT) and punch through shear test (PTST). These mechanical tests are chosen to explore the effect of loading types on the resulting AE characteristics. This study selects important AE parameters which includes the AE count, average frequency (AF) and RA value in the time domain, and the peak frequency (PF) and centroid frequency in the frequency domain. The result reveals that the cumulative AE counts, the maximum RA value and the moving average PF show their potentials as indicators to damage progress for a certain loading type. The observed trends in the cumulative AE counts and the maximum RA value show three unique stages with an increase in applied stress: the steady state stage (or crack initiation stage; < 70% of yield stress), the transition stage (or damage progression stage; 70–90% of yield stress) and the rising stage (or failure stage; > 90% of yield stress). In addition, the moving average PF of PTST in the early damage stage appears to be particularly lower than that of UCT and BTT. The loading in BTT renders distinctive responses in the slope of the maximum RA–cumulative AE count (or tan ). The slope value shows less than 0.25 when the stress is close to 30% of BTT, 60% of UCT and 75% of PTST and mostly after 90% of yield stress, the slope mostly decreases than 0.25 in all tests. This study advances our understanding on AE responses of concrete materials with well-controlled laboratoryscale experimental AE data, and provides insights into further development of AE-base real-time diagnostic monitoring of structures made of rocks and concretes.

As an example of research activities in decontamination for decommissioning, new data are presented on the options for corrosion layer dissolution during the decommissioning decontamination, or persulfate regeneration for decontamination solutions re-use. For the management of spent decontamination solutions, new method based on solvent extraction of radionuclides into ionic liquid followed by electrodeposition of the radionuclides has been developed. Fields of applications of composite inorganic-organic absorbers or solid extractants with polyacrylonitrile (PAN) binding matrix for the treatment of liquid radioactive waste are reviewed; a method for americium separation from the boric acid containing NPP evaporator concentrates based on the TODGA-PAN material is discussed in more detail. Performance of a model of radionuclide transport, developed and implemented within the GoldSim programming environment, for the safety studies of the LLW/ILW repository is demonstrated on the specific case of the Richard repository (Czech Republic). Continuation and even broadening of these activities are expected in connection with the approaching end of the lifespan of the first blocks of the Czech NPPs.

Numerical model was developed that simulates radionuclide (3 H and 14C) transport modeling at the 2nd phase facility at the Wolsong LILW Disposal Center. Four scenarios were simulated with different assumptions about the integrity of the components of the barrier system. For the design case, the multi-barrier system was shown to be effective in diverting infiltration water around the vaults containing radioactive waste. Nevertheless, the volatile radionuclide 14C migrates outside the containment system and through the unsaturated zone, driven by gas diffusion. 3 H is largely contained within the vaults where it decays, with small amounts being flushed out in the liquid state. Various scenarios were examined in which the integrity of the cover barrier system or that of the concrete were compromised. In the absence of any engineered barriers, 3 H is washed out to the water table within the first 20 years. The release of 14C by gas diffusion is suppressed if percolation fluxes through the facility are high after a cover failure. However, the high fluxes lead to advective transport of 14C dissolved in the liquid state. The concrete container is an effective barrier, with approximately the same effectiveness as the cover.