Zr-Nb-Sn 의 3원계 합금에서 Sn 함량 변화가 부식에 미치는 영향과 석출물 특성에 미치는 영향을 평가하여 신합금 개발을 위한 Sn의 최적 함유량을 도출하고자 Zr-0.4Nb-xSn(x=0.4,0.8, 1.2, 1.6)계의 4종 합금을 제조하여 여러 가지 특성시험을 실시하였다. 부식특성은 420˚C steam(1500psi)조건의 autoclave를 이용하여 시험하였으며 부식과정에서 발생하는 무게증가량을 측정하였고 산화막 특성은 X-ray를 이용하여 조사하였다. 부식관점에서 Sn량이 적을수록 내식성은 증가하는 경향을 보였다. 즉, 0.4Sn합금에서 가장 낮은 무게증가량과 1.6Sn 합금에서 가장 높은 무게 증가량을 보였다. 그러나 수소흡수성면에서는 Sn량이 많을수록 수소흡수율이 작아지는 경향을 보였다. 산화막내에서 tetra-ZrO2량은 Sn량이 많을수록 적게 나타나는데, 이같은 결과로부터 Sn량이 많을수록 tetra-ZuO2에서 mono-ZrO2로의 상변태가 가속되어 Sn이 많이 함유된 합금에서 부식 저항성은 저하된다고 사료된다. Sn량이 증가함에 따라 강도는 점차적으로 증가하는 경향을 보였다. Sn량 변화에 따른 석출물의 특성을 조사한 결과, Zr-0.4Nb-xSn계 합금에서는 Sn이 석출물 형성에 거의 영향을 미치지 않으며, 또한 석출물 크기도 내식성에 커다란 영향을 미치지 않는 것을 확인하였다.

The component materials threatened by cavitation include ship propellers as well as turbine runners, pump impellers, pipe lines and radiators. Today it is known that cavitation damage takes place on many other components including on the coding water side of the cylinder liners of diesel engines. Cavitation erosion - corrosion implies damage to materials due to the shock pressure or shock wave that results when bubbles form and collapse at a metal surface within a liquid. To suppress cavitation erosion as well as cavitation erosion - corrosion to hydraulic equipment, innovations such as the improvement in the geometric design of the equipment or the selection of suitably resistant construction materials are necessary. In this study, we investigated that the cavitation erosion - corrosion damage under vibratory cavitation can be reduced by adding of side now velocity to the cavitation bubble group in order to eliminate bubbles formed in sea water environment.

Recently with the rapid development in the industries such as an iron mill and chemical plants, these are enlarged by the use of the piping. This piping was encountered the stress corrosion cracking(SCC) because of stress by water pressure and residual stress of welding etc. under industrial water. In this paper, the behaviour of stress corrosion cracking on the weld zone of steel pipe piping water(SPPW) were investigated according to pre-heat before welding in natural seawater(specific resistance : 25Ω-cm). The main results obtained are as follows :1) The stress corrosion cracking for SPPW and SB 41 is most ready to propagate in heat affected zone of weldment. 2) The SCC sensitivity of SPPW on weldment is more susceptible than that of SB 41. 3) The stress corrosion cracking growth of heat affected zone is delayed by the preheat and dry of base metal and electrode before welding.

Cavitation erosion-corrosion implies damage to materials due to the shock pressure or shock wave that results when bubbles form and collapse at a metal surface within a liquid. If the liquids corrosive to the material, a condition typically encountered in industry, the component materials may suffer serious damage by a combination of mechanical and electrochemical attack. To suppress cavitation erosion as well as cavitation erosion-corrosion to hydraulic equipments, innovations such as the improvement in the geometric design of the equipment or the selection of suitably resistant construction materials are necessary. This study was tested by using the piezoelectric vibrator with 20kHz, 24μm for cavitation generation. And also, the vibratory cavitation erosion-corrosion tests on commercial mild steel SS41were carried out. We carefully observed the erosion pattern and surface photography. The geometrical mechanism of pit growth, which is to be likely these processing; shallow typelongrightarrowundercut typelongrightarrowwide shallow type.

각종 환경 조건에서 진동 캐비테이션 침식-부식 시험 장치에 의해 연강(SS41)의 캐비테이션 침식-부식 손상 거동에 관한 연구를 한 결과 다음과 같은 결론을 얻었다. 1) 해수 중에서 캐비테이션 침식-부식 손상 거동은 중앙부와 테두리 부에서 거의 비슷한 정도로 발생하여 성장되지만, 증류수 중에서는 테두리부에서 손상이 먼저 발생한 다음 중앙부에도 손상이 점차 일어난다. 2) 비저항이 낮은 수도수 중의 캐비테이션 침식-부식 손상은 초기에는 비저항이 높은 증류수중에서의 것보다 증가하지만 시간이 경과하면서 CaCO 하(3)의 피막 형성에 의해 둔화된다. 3) 케비테이션 침식-부식 손상 특성은 잠복기, 증가기, 감소기 및 안정기의 4단계로 구분된다.

응력부식균열(SCC) 감수성평가를 위한 여러 시험방법들중 저변형율시험방법은 비교적 ?은 시간내에 금속재료의 SCC감수성을 평가하기 위한 효과적인 시험방법이다. 그러나 저변형율 시험방법만으로 SCC과정의 미시적 파괴거동ㅇ르 분석하는 것은 매우 어렵다. 종래, 음향방출(AE)시험은 재료의 파괴과정시 미시균열의 개시 및 전파거동을 감시하는데 유효한 기법으로 잘 알려져 있다. 그러므로 본 논문에서는 저변형율시험과 음향방출시험을 이용하여 SCC의 전파과정과 AE신호 특성사이의 상호관계를 분석하였다. 실험결과, 재료의 미시파괴 과정에서 발생하는 AE신호들은 뚜렷히 시험환경에 의존하였으며, 인공해수중에서 SCC과정시 발생된 AE신호 특성은 Air상태 보다 상당히 크게 나타났다. 그리고 SCC거동은 AE신호의 진폭인자로서 명확하게 평가할 수 있다.

In this paper, the corrosion fatigue crack propagation behavior of structure rolled steel (SWS 41C) was investigated by changing the thickness, and this experiment was done by the three point bending corrosion fatigue tester. The main results obtained are as follows: 1) As the thickness of specimen becomes thicker, the corrosion sensitivity to initial stage crack becomes some sensitive, and that the fatigue life becomes more sensitive. 2) The crack growth rate to initial stage crack (da/dN) was retarded as the thickness of specimen becomes thicker. But after initial stage crack, as the thickness of specimen is more thicker, da/dN is more rapid. 3) As the corrosion fatigue crack length grows, the accelerative factor of thick specimen (t=12mm) is more higher than that of thin specimen (t=6mm). 4) As the corrosion fatigue crack length grows, the corroson potential of both thick specimen and thin specimen becomes more less noble potential, however thick specimen (t=12mm) tends to more less noble potential than that of thin specimen(t=6mm).

In this paper, the behaviour of cavitation erosion, influence of corrosion and corrosion control on slide bearing metals for internal combustion engine were investigated, and this experiment was done by the vibratory cavitation erosion tester. The main results obtained are as follows: 1. With decreasing the space between horn and specimen, the weight loss and its rate increased step by step. But the weight loss and its rate of 0.2mm space decreased conversely more than that of 0.4mm space at early stage. 2. The weight loss and its rate with change of pH were appeared to the order of pH2>pH12>pH7>pH4. And the weight loss and its rate at pH 4 decreased at best. 3. The weight loss and its rate by cavitation erosion for bearing metals were shown to the order of W.M7>W.M1>K.M4. 4. There appeared mainly small pit hole at pH2, and appeared the pit of netting thread type at pH12 by the results of the damaged surfaces at pH2 and pH12 environments that were sensitive to cavitation erosion. 5. With increasing the viscosity of lubricating oil, the weight loss rate by cavitation erosion became dull at the space below 0.5mm. 6. The protective efficiency of cavitation erosion-corrosion is superior inhibitor of chormate(25 ppm) to cathodic protection.

In this study, corrosion fatigue test of SAPH45 steel was performed by the use of plane bending fatigue tester in marine environment and investigated fracture surface growth behavior of base metal and heat affected zone corrosion fatigue. The main results obtained are as follows: 1) Fracture surface growth of heat affected zone (HAZ) is delayed more than that of base matel (BM), and they tend to faster in seawater than in air. 2) Corrosion sensitivity to corrosion fatigue life of HAZ is more susceptible than that of BM. 3)In the case of the corner crack by corrosion fatigue, the correlation between the propagation rate of fracture surface area(dA/dN) and stress intensity factor range(ΔK) for SAPH45 are applied to Paris rule as follows: dA/dN=C(ΔK) super(m) where m is the slope of the correlation, and is about 6.60-6.95 in air and about 6.33-6.41 in seawater respectively.

The objective of this study is to identify reasonable repair and reinforcement methods by performing an analysis and analysis and measurement of corrosion that occurred at the bridge support due to leakage from the expansion joint device.

In this study, Corrosion behavior in mortar was observed by the passage of time by using EIS method. As a result of EIS experiment, equivalent circuit and changes of Impedance parameter could be observed. In addition, it was confirmed that impedance of rebar in concrete and corrosion rate according to the amount of NaCl and LiNO2 were different.

To ensure the safety of weathering steel structures, it is important to evaluate the time-dependent corrosion behavior. Thus, progress and effect of corrosion damage on weathering steel members should be evaluated, but predicted corrosion depth do not go far enough until now, which is affected by the corrosion environment. In this study, the corrosion resistant of weathering steel was examined to quantifiably investigate and compare the corrosion depth of carbon and weathering steel.

To ensure the safety of weathering steel structures, it is important to evaluate the time-dependent corrosion behavior. Thus, progress and effect of corrosion damage on weathering steel members should be evaluated, but predicted corrosion depth do not go far enough until now, which is affected by the corrosion environment. In this study, the corrosion resistant of weathering steel was examined to quantifiably investigate and compare the corrosion depth of carbon and weathering steel.

NaCl과 LiNO2의 첨가량에 따른 콘크리트에 매립된 철근의 부식거동을 전기화학적 임피던스 분광법을 이용하여 고찰하였다. 부식 가속 방법중 하나인 건습반복법을 이용하여 단기간 내에 부식현상을 촉진하였으며, 측정된 임피던스 값을 통해 등가회로를 제안할 수 있었다. NaCl 1.2 kg/m3이 첨가된 콘크리트에 매립된 철근의 부동태 피막이 빠르게 파괴되는 것을 확인할 수 있었으며, 염화물 첨가량 대비 0.6M의 LiNO2를 첨가한 경우 부식진행속도가 크게 저하하는 것을 확인할 수 있었다. 또한 염화물 첨가량 대비 1.2M의 LiNO2를 첨가한 경우 부동태 피 막이 부식가속시간이 지나도 파괴되지 않고 성능이 유지되는 것을 확인할 수 있었다.

In this study, Corrosion behavior in mortar was observed by the passage of time by using EIS method. As a result of EIS experiment, equivalent circuit and changes of Impedance parameter could be observed. In addition, it was confirmed that impedance of rebar in mortar and corrosion rate according to the amount of NaCl were different.

In this study, shear buckling behaviors of a web panel with local corrosion in a plate girder bridge were numerically examined because severe corrosion damage has been reported in plate girder bridges. The web corroded condition and boundary condition were changed to evaluate the effect of corrosion condition on the shear buckling behaviors of the web panel.

Severe corrosion damage on the deck surface of a orthotropic bridge deck with bulb rib has been reported in Japan. Therefore, in this study, structural behaviors of a orthotropic bridge deck was numerically examined using FE analysis program MARCment2010. Thus, its deck thickness was decreased according to corrosion damage level of the deck. The deformations and the stress distributions of a orthotropic bridge deck with bulb rib were compared and evaluated.

시멘트 대체 재료로서 플라이애쉬의 사용은 시멘트 생산비용을 절감시키는 효과를 창출하였다. 반면에 플라이애쉬 혼입콘크리트는 OPC에 비해 상대적으로 긴 양생시간과 초기강도의 발현 저하를 들 수 있어 이의 해결을 위해 물리적 방법, 온도 및 화학적 방법 등과 같은 다양한 활성화 기술의 적용을 통하여 플라이애쉬 혼입 콘크리트의 수화를 가속시킬 수 있고, 콘크리트의 부식 저항성을 향상시킬 수가 있다. 본 연구에서는 10～40%의 치환률을 가진 활성화된 플라이애쉬 시편을 통해 개방 회로형 전위측정(Open circuit potential measurement)을 수행하였고, 투수시험, 급속염화물침투시험 및 SEM(Scanning electron microscopy)촬영을 통해 OPC 콘크리트와 비교․분석 하였다. 또한, 치환률의 임계범위 20～30%의 경우에 있어서 활성화된 플라이애쉬를 사용한 콘크리트가 열화저항성에 있어서 개선효과가 나타나고 있음을 확인하였다. 또한 플라이애쉬를 화학적으로 활성화시킨 경우가 본 연구에서 수행된 다른 활성화 방법들에 비해 더욱 좋은 결과를 나타나고 있음도 확인하였다.