본 연구에서는 PEN 수지 안전관리를 위하여 HPLC-UV검출기를 이용한 2,6-NDC 및 2,6-NDA 분석법을 확립하였다. 분석법 검증 결과, 2,6-NDC 및 2,6-NDA 모두 0.002μg/mL 검출한계, 0.005 μg/mL 정량한계 및 0.05~1 μg/mL의 농도 범위에서 r2= 0.999 이상의 직선성을 확인할 수있었다. 또한 회수율도 90~110%임을 확인할 수 있었다.

In order to prove that perchlorate-laden resins could be bio-regenerated through direct contact with anaerobic microorganisms, two bio-regeneration systems, internal and external, were tested. Anaerobic digestion was demonstrated to be very efficient in degrading perchlorate that had been adsorbed onto A520E resin. The internal bio-regeneration test showed that the fully exhausted resins recovered about 80% of the perchlorate-exchange capacity after 4 weeks of bio-treatment in the anaerobic digester. The bio-regeneration efficiency of the external system increased with the amount of flow passed through the column. Comparison of two perchlorate breakthrough curves obtained from column test, one with virgin resin and the other with bio-regenerated resin, proved that the bio-regenerated resin could be used repeatedly to treat perchlorate in spent or waste brine. The A520E resin was very stable in the anaerobic digester and its perchlorate-exchange capacity was barely changed during 26 weeks of incubation. The most significant contribution of this research is to develop the concept of direct bio-regeneration of exhausted resins by combining physicochemical ion-exchange and biological reduction technology, especially for the removal of perchlorate.

혼탁매질에서 산란체와 흡수체의 영향은 빛산란에 의해 파장에 대한 산란세기로 설명된다. New Austria Tunnel Method의 수지에 대한 산란의 분자특성들은 연구하기 위해 Monte Carlo Simulation하였다. 이는 산란매질에서 광학적 파라미터들(μs, μa, μt)에 의해 조사되어 그들의 영향을 알 수 있었다. 산란매질에서 광자에 대한 빛분포에 의한 결과는 광원에서 검출기까지 거리가 가까우면 산란이 증가하여 산란세기가 크게 나타났다. 이는 강구조물의 내구성을 위한 코팅과 부식에서 좋은 모델을 디자인하는데 도움이 될 것이다.

Most of the plastics products have been manufactured by injection molding. Molding trouble in injection-molded parts is caused by changing a molding product and molding process condition, etc. In this study, warpage in the injection molded part have been studied. specimens are rectangular flat shape with and without ribs. Non-crystalline resins (PC) and crystalline resins (PA66) were used for material and 30% glass fiber reinforced-resins(PC, PA66). Flat shape ribs showed higher warpage than flat shape without rib by 10 to 41%. the specimens with ribs that are located parallel to flow direction has higher warpage than the specimens with rib that are located perpendicular to flow direction by 11 to 50%. crystalline resins have higher warpage than non-crystalline resins by 22 to 78%.

The existing study on fiber reinforced of the reinforced concrete columns are mainly used to thermosetting resin for evaluate the seismic performance. as compared with thermoplastic resin, thermosetting resin is the advantage of greater strength and stand in high temperature. but, thermosetting resin has many environmental problems about recycling. In this study, better toughness, recyclability and the advantage of rapid construction than thermosetting resin used to the seismic performance evaluation. The existing unreinforced and Superex reinforced concrete compression test specimens experimented with 4 kinds about reinforced repeat. (unreinforced, 1 layer, 3 layers, 5 layers) The test results appear to be increased the maximum load of 98.37% that 5 layers reinforced repeat when compared to unreinforced

본 연구에서는 도심지 열섬현상을 완화 시킬 수 있는 아크릴 수지와 차열안료를 혼합한 차열성 포장을 개발하였다. 태양 복사열에 의한 포장체의 온도상승을 모사한 실내 시험으로부터 60℃의 포장 온도에서 차열성 포장이 12℃ 이상의 온도 저감 효과를 나타냈다. 이러한 온도 감소 효과는 차열안료의 배합비가 증가함에 따라 증가하였고, 반면에 점도의 증가로 인하여 작업성은 떨어졌다. 이러한 결과로부터 아크릴 수지 대비 차열안료의 최적혼합비율을 15%로 결정하였다. 차열성 포장의 칸타브로 손실률은 일반 배수성 포장의 손실률 1/4 수준으로 골재 비산 저항성이 우수하게 나타났다. 휠트랙킹 시험결과 차열성 포장의 동적안정도가 일반 배수성 포장에 비해 두 배 증가하였다. 차열성 포장재의 높은 부착력으로 인하여 탈리에 의한 손상 가능성은 낮은 것으로 나타났다. 시험 시공 구간에서의 소음도 측정 시험 결과 일반 배수성 포장에 비하여 평균 3.7dB의 소음저감 효과가 있었고, 미끄럼 저항치는 일반 배수성 포장에 비해서 평균 30% 정도 높아 우수한 미끄럼 저항성을 가지는 것으로 판단된다. 투수 시험 결과 차열성 포장의 투수성은 일반 배수성 포장보다 다소 작았으나 국내 배수성 포장 기준을 만족하는 것으로 나타났다.

In this study we experimented that how polyurethane effect to acrylic-polyurethane resin in Full-Grain leather coatings. First of all, we consummated waterborne acrylic emulsion and waterborne polyurethane resin, Than we prepared F.G leathers which were coated by acrylic resin and acrylic-polyurethane resins. According to measured data for solvent resistance, acrylic resin and acrylic-polyurethane resins had good property. Sample a(WAC) had most low strength(2.10kgf/mm2) and sample d(WAC 93 : WPU 7) had most high strength(3.41kgf/mm2). Also we knew that most good property of abrasion is d(47.4 mg). In elongation case, a(WAC) had most good result(645 %) in this experiment.

본 연구는 낙동강 하구역의 사주지형 변화를 예측하기 위한 기초적 연구로서 하천유량의 변화에 따른 부유사의 물질수지에 대하여 검토하였다. 낙동강 하구역의 부유사 물질수지는 갈수기시 60,708 kg/day가 유입하고, 홍수기는 306,892 kg/day가 외해를 통하여 유출하는 것으로 산정되었다. 낙동강 하구역은 전반적으로 갈수기 및 평수기에 부유사의 유입, 홍수기에 부유사의 유출이 반복 되지만, 사주지형 주변에서는 부유사의 유입과 유출 거동이 복잡하게 나타나 장기 지형변동 모니터링이 필요한 것으로 나타났다.

In this study we experimented that how chain extension influences to waterborne urethane-acrylic hybrid resin for leather garment coatings. We knew that polyurethane-acrylic hybrid resins had 5 grades of solvent resistance. Tensile strength measured in the polyurethane-acrylic resin(EDA 5.37 g, 1.928 kgf/mm2) had the most strong strength. Also polyurethane-acylic hybrid resin(EDA 5.37 g. 30.2 mg. loss) had better result than other hybrid resins. EDA contents higher, we obtained low elongation and low flexibility. In this result, chain extension of waterborne polyurethane-acrylic hybrid resin showed the effect in leather coating with ratio of EDA.

In this study, energy budget was estimated to produce an efficient artificial seed. And it needs to enhance fisheries productivity of sandfish, A. japonicus. In order to estimate energy budget of the sandfish, A. japonicus juvenile fed on nonriched Artemia nauplii (NA) and the enriched Artemia nauplii (EA), of sandfish were reared at constant condition of seawater temperature of natural temperature (NT) and heated temperature (HT). During the reared period, energy used by the reared juveniles were calculated from estimates of data on ingestion, growth, oxygen consumption, nitrogen excretion and energy content. Energy budget of NT-NA, NT-EA, HT-NA and HT-EA were represented as 100C=66.49G+21.28M+0.78F+1.44U, 100C=67.54G+21.40M+9.39F+1.67U, 100C=66.86G+22.66M+8.01F+2.47U and 100C=67.06G+22.96M+7.70F+2.28U. The assimilation efficiency estimated NT-NA, NT-EA, HT-NA and HTEA were represented as 87.78%, 88.94%, 89.52% and 90.02%. Gross growth efficiency estimated NT-NA, NT-EA, HT-NA and HT-EA were represented as 66.49%, 67.54%, 66.86% and 67.06%. Net growth efficiency estimated NT-NA, NT-EA, HT-NA and HT-EA were represented as 75.75%, 75.94%, 74.68% and 74.49%. In this results, two ways could be considered to produce an efficient artificial seed of sandfish. To hasten the growth of sandfish juvenile, heated seawater (HT) and enriched Artemia nauplii (EA) should be inputted to reared condition. And to increase the energy efficiency, natural seawater (NT) and enriched Artemia nauplii (EA) should be inputted to reared condition.

In this study, we experimented that how influence chain extension to waterborne urethane-epoxy hybrid resin for leather garment coatings. First of all, We had analyzed datas by FT-IR, SEM and machanical properties. By instruments analysis measurement we confirmed that synthesis of epoxy and hybrid resin. In this experiment we knew that polyurethane-epoxy hybrid resin have 5 grades of solvent resistance. Tensile strength measured in the polyurethane-epoxy resin(EDA 5.37g, 2.386 kgf/mm2) had the most strong strength.. Also polyurethane-epoxy hybrid resin had better result(EDA 5.37g. 37.4 mg. loss) than other hybrid resins. As hight proportion of EDA in hybid resin, we obtained low elongation and low flexibility. In this result, chain extension of waterborne polyurethane-epoxy hybrid resin showed that how effect in leather coating by ratio of EDA.

For the synthesis of water soluble acrylic modified epoxyester resin, fatty acid/epoxy ratio of 50/50 was used, and introduced maleic anhydride. Ratio of styrene/acrylic acid of acrylic monomers was fixed 85/15 and ratio of epoxyester/acrylic monomer was controlled 80/20, 75/25, 70/30, 65/35, and degree of neutralization were changed 65%, 80%, to 100%. As a result, 40% solids acrylic modified epoxyester resins were synthesized. Resins were evaluated water soluble stability, drying time, water resistant, storage stability and physical properties. And the white paints were prepared, and were evaluated viscosity, drying time, water resistance, adhesion, sagging, spray workability, gloss, salt spray resistance, skinning, whiteness and flash rust. As a result, the degree of neutralization of 100% and the ratio of epoxyester/acrylic monomer of 75/25 showed the best properties.

The relative viscosity was measured at different filler loadings for a cycloaliphatic epoxy resin and hexahydro-4-methylphthalic anhydride hardener system filled with micro/nano hybrid silica. Various empirical models were fitted to the experimental data and a fitting parameter such as critical filler fractions (φmax) was estimated. Among the models, the Zhang-Evans model gave the best fit to the viscosity data. For all the silica loadings used, ln (relative viscosity) varied linearly with filler loadings. Using the Zhang-Evans model and the linearity characteristics of the viscosity change, simple methods to predict the relative viscosity below φmax are presented in this work. The predicted viscosity values from the two methods at hybrid silica fractions of φ = 0.086 and 0.1506 were confirmed for a micro:nano = 1:1 hybrid filler. As a result, the difference between measured and predicted values was less than 11%, indicating that the proposed predicting methods are in good agreement with the experiment.