Oysters are the most widely produced shellfish culture in Korea and 90% of their weight. Main component of oyster shell is CaCO3 and an appropriate calcination temperature was derived using thermo-gravimetric analysis. The difference in components for each calcination temperature was confirmed and the adsorbent was manufactured by activation. The oyster shell adsorbent surface area was 5.72m2/g with pores in the mesopore range. The adsorption amount was 37.44 mg/g. Therefore, the possibility of using oyster shell as an adsorbent was confirmed.

Starfish are creatures that destroy marine ecosystems due to their high reproductive rate and predatory nature. Instead of mass incineration, this study attempted to utilize them as functional adsorbents to control odorous organic compounds. This waste starfishbased adsorbent showed a high aldehyde capture efficiency of 91.1%. The maximum specific surface area of the prepared waste starfish adsorbent was 2.19m2/g, and the adsorption amount was 101.66mg/g. Therefore, it was confirmed that the waste starfish had the ability to perform well as an adsorbent.

This study presents a numerical modeling and a transient simulation of a desiccant coated heat exchanger (DCHE) that is employed for dehumidification in buildings. DCHE is fabricated by coating type RD silica gel on the fin surfaces of a fin tube heat exchanger. The latent cooling load, which is 25 to 45% of the total cooling load in most weather conditions is removed by adsorption of vapor using DCHE. The saturated adsorbent is then regenerated by using either low-temperature waste heat from industry and/or renewable energy such as solar energy and geothermal energy. A mathematical model is established and a transient simulation has been carried out so as to analyze its performance in terms of average humidity difference (AHD), moisture removal capacity (MRC), latent cooling capacity(QL), and COP. Comparison between the simulation results and the experimental data was carried out and showed good agreement and a similar trend with a maximum discrepancy of 5%. Key results revealed that MRC, AHD, QL, and COP are largely affected by both air dry-bulb temperate and air wet-bulb temperature while they are less affected by the frontal air velocity. Furthermore AHD, MRC and QL are largely improved by hot-water temperature while COP decreases as hot-water temperature increases due to high regeneration energy consumption.

The adsorption method that is widely used in the field of odor control generally utilizes activated carbon. However, the development of an economical and efficient adsorbent is required due to the increased use of activated carbon and the high cost of raw materials. Accordingly, the use of waste as a raw material for new adsorbents is attracting attention both in Korea and abroad. In this study, the current status of domestic and overseas waste generation, characteristics of adsorbents, and research trends were investigated, and through this, it was found that a waste-derived adsorbent was an adequate substitute in terms of adsorption capacity and price compared to activated carbon.

본 연구에서는 활성탄소를 이용하여 해양환경으로 유출된 침강 HNS를 현장에서 대응하기 위한 기술 개발을 목적으로, 활용 가능한 활성탄소의 조건을 검토하고 예상 소요량을 산출하였다. 입자 크기별 7종의 활성탄소들을 대상으로 침강 속도를 측정하였고, 침강 HNS로 분류된 클로로포름(CHCl3)에 대한 흡착용량을 실험실 규모 실험(lab-scale test)으로 측정하였다. 또한 7종 활성탄소들에 대하여 유해 물질함량과 용출 실험을 실시하여 용출된 유해물질 함량을 정량 분석하였다. 평균 침강속도(Mean particle-settling velocity)는 0.5~8 cm/sec의 범위로 8-20 mesh 경우를 제외하고 입자의 크기가 클수록 침강속도가 빨랐으며, 클로로포름에 대한 흡착효율은 대체로 입자가 작을수록 표면적이 넓어져 증가되었다. 또한 현장 투입 후 2차 오염가능성 확인을 위한 유해물질함량과 용출 실험 실험에서 >100 mesh의 활성탄소는 전함량분석결과가 아연(Zn)과 비소(As)가 수처리제기준보다 높고, 용출실험결과에서도 크롬(Cr), 아연(Zn), 비소(As)가 다른 활성탄소에 비해 높은 농도로 용출되었다. 흡착효율, 침강속도, 유해성분 용출량 등을 종합적으로 고려하여 현장 처리 적용 가능한 활성탄소는 20-60, 20-40, 2mm&down mesh 이었으며, 흡착용량을 최우선으로 판단하여 투입물량을 계산하면 최소 현장 투입 물량은 각각 0.82, 0.90, 1.28 ton/㎘ 이다.

To abate the problem of odor from restaurants, a hybrid adsorbent consisting of organic and inorganic materials was developed and evaluated using acetaldehyde as a model compound was deveioped and evaluated. Powders of activated carbon, bentonite, and calcium hydroxide were mixed and calcinated to form adsorbent structure. The surface area of the hybrid adsorbent was smaller than that of high-quality activated carbon, but its microscopic image showed that contours and pores were developed on its surface. To determine its adsorption capacity, both batch isotherm and continuous flow column experiments were performed, and these results were compared with those using commercially available activated carbon. The isotherm tests showed that the hybrid adsorbent had a capacity 40 times higher than that of the activated carbon. In addition, the column experiments revealed that breakthrough time of the hybrid adsorbent was 2.5 times longer than that of the activated carbon. These experimental results were fitted to numerical simulations by using a homogeneous surface diffusion model (HSDM); the model estimated that the hybrid adsorbent might be able to remove acetaldehyde at a concentration of 40 ppm for a 5-month period. Since various odor compounds are commonly emitted as a mixture when meat is barbecued, it is necessary to conduct a series of experiments and HSDM simulations under various conditions to obtain design parameters for a full-scale device using the hybrid adsorbent.

Environmental treatment residues become valuable waste byproducts like biomass when an environmental infrastructure necessary for recycling is effectively developed. In this study, an environmentally friendly sewage sludge sorbent was developed in a sewage treatment plant by carefully processing the sewage sludge generated from sewage treatment plants. In order to increase the adsorption efficiency, coffee ground waste was added to the adsorbent as an additive and the adsorbate used in the adsorption experiments was acetaldehyde as organic waste. It could be found from the experiment that the adsorbent of the sewage sludge was adsorbed more easily at the carbonization temperature of 600℃. In addition, adsorption experiments showed that the breakthrough time reached to 85, 110, and 130 minutes at 3:1, 2:2, and 1:3, respectively, depending on the content ratio of the sewage sludge and coffee waste. Therefore, the amount of acetaldehyde adsorption increased with the increase in the amount of coffee grounds in the mixture. It could be also be found that the addition of the coffee grounds as an additive to increase the adsorption capacity of the sewage sludge adsorbent is advantageous for adsorption.

Mill scale, an iron waste, was used to separate magnetite particles for the adsorption of phosphate from aqueous solution. Mill scale has a layered structure composed of wustite (FeO), magnetite (Fe3O4), and hematite (Fe2O3). Because magnetite shows the highest magnetic property among these iron oxides, it can be easily separated from the crushed mill scale particles. Several techniques were employed to characterize the separated particles. Mill scale-derived magnetite particles exhibited a strong uptake affinity to phosphate in a wide pH range of 3-7, with the maximum adsorptive removal of 100%, at the dosage of 1 g/L, pH 3-5. Langmuir isotherm model well described the equilibrium data, exhibiting maximum adsorption capacities for phosphate up to 4.95 and 8.79 mg/g at 298 and 308 K, respectively. From continuous operation of the packed-bed column reactor operated with different EBCT (empty bed contact time) and adsorbent particle size, the breakthrough of phosphate started after 8-22 days of operation. After regeneration of the column reactor with 0.1N NaOH solution, 95-98% of adsorbed phosphate could be detached from the column reactor.

오염수로부터 자성분리가 가능하며, 방사성 세슘을 효율적으로 제거하기 위한 코발트 페로시아나이드(cobalt ferrocyanide, CoFC) 혹은 니켈 페로시아나이드(nickel ferrocyanide, NiFC)가 도입된 자성입자 흡착제를 제조하였다. Fe3O4 나노 입자는 공침법을 이용해 제조하였고, Co2+와 Ni2+ 이온을 입자 표면에 도입시키기 위해 금속이온과 금속 배위결합(metalcoordination) 을 하는 카르복실기를 포함한 숙신산(succinic acid, SA)을 자성나노입자(magnetic nanoparticles, MNPs) 표 면에 코팅하였다. CoFC와 NiFC는 자성나노입자 표면에 도입된 Co2+ 혹은 Ni2+ 이온이 hexacynoferrate와 결합하여 형성된 다. 제조된 CoFC-MNPs 그리고 NiFC-MNPs는 각각 43.2 emu·g-1, 47.7 emu·g-1의 우수한 포화자화 값을 보여주었다. X- 선 회절분석(XRD), 퓨리에 변환 적외선 분광분석(FT-IR), 나노입자 입도 분석기(DLS), 투과전자현미경(TEM) 등의 분석을 통해 흡착제의 물성을 파악하고, 세슘에 대한 흡착 성능을 알아보았다. 흡착실험을 평가하기 위해 Langmuir/Freundlich 등 온흡착식을 이용해 실험 결과 값을 곡선맞춤 하였고, CoFC-MNPs와 NiFC-MNPs의 최대흡착량(qm)은 각각 15.63 mg·g-1, 12.11 mg·g-1이다. CoFC-MNPs와 NiFC-MNPs는 방사성 세슘에 대해서도 최저 99.09%의 제거율을 가지며, 경쟁이온의 존재에도 방사성 세슘만을 선택적으로 흡착한다.

본 연구에서는 고염/고방사성 폐액 내 함유된 주요 고방사성핵종인 Cs 제거를 목적으로 고효율의 복합 흡착제(potassium cobalt ferrocyanide (PCFC)-loaded chabazite (CHA)) 합성 및 이의 적용성을 평가하였다. 복합 흡착제는 Cs을 비롯한 다 른 입자를 수용할 수 있는 CHA를 지지체로 선정하였으며, CoCl2 및 K4Fe(CN)6 용액의 단계적인 함침/침전을 통해 PCFC를 CHA 세공 내에 고정화함으로써 합성하였다. 복합 흡착제의 합성 시 평균 입자크기가 10 ㎛ 이상의 CHA를 지지체로 사용할 경우, PCFC 입자는 안정적인 형태로 고정화되었다. 또한, 합성 시 복합 흡착제의 정제를 증가시키는 세척 방법을 최적화함으로써, 복합 흡착제의 물리적 안정성이 향상되었다. 최적의 합성법을 통해 얻은 복합 흡착제에 의한 Cs 흡착 시, 담수(무염 조건) 및 해수(고염 조건)에서 모두 빠른 흡착 속도를 보였으며, 염 농도와 무관하게 비교적 높은 분배계수 값(104 mL·g-1 이상)을 나타내었다. 그러므로, 본 연구에서 합성한 복합 흡착제는 CHA 및 PCFC가 각각 가지고 있는 물리적 안정성과 Cs 에 높은 선택성 등을 고려하여 촤적화한 소재이며, 고염/고방사성폐액에 함유되어 있는 Cs을 고효율로 신속하게 제거할 수 있음을 알 수 있다.