The thermal conductivity (TC) of graphene-based/metal composites is currently not satisfactory because of the existence of large interfacial thermal resistance between graphene and metal originating from the strong scattering of phonons. In this work, 6063Al-alloy-based reduced graphene oxide (rGO) composite with strong covalent bonds interface was prepared via self-assembly, reduction, and electrophoresis-deposition processes by using 3-aminopropyl triethoxysilane (APTS) as a link agent. Structural characterizations confirmed the successful construction of strong Al-O-Si-O-C covalent bonds in the as-prepared 6063Al-Ag-APTS-rGO composite, which can promote the transfer of phonons in the interface. Benefiting from the unique structure, 6063Al-Ag-APTS-rGO (214.1 W/mK) showed obviously higher cross-plane TC than 6063Al (195.6 W/mK). Comparative experiments showed that 6063Al-Ag-APTS-rGO has better cross-plane TC than 6063Al/Ag/ APTS/rGO (196.6 W/mK) prepared via physical mixing of stirring process, evidencing the significance of electrophoresisdeposition (EPD) process on constructing strong covalent bonds for improving the heat dissipation performance. Besides, the effects of different rGO contents and test temperature on the TC of the composites and their corrosion resistance were also discussed. This work demonstrated a feasible strategy for the construction of metal–carbon interface composite with improved thermal performance.

Hydrogen-bonded organic frameworks (HOFs) are a new type of porous crystalline material that are constructed by intermolecular hydrogen bonding of organic building blocks to form twodimensional (2D) and three-dimensional (3D) crystalline networks. High-quality HOF single crystals are easily grown for direct superstructure analysis using single crystal X-ray diffraction, which is essential for revealing the relationship between structure and properties. The unique advantages of HOF, such as high crystallinity, porosity and fast regeneration, have allowed it to be used in a variety of applications including catalysis and gas separation. Squaric acid (SQA) is a non-carboxylic, organic acid with proton donor and acceptor ability which is known to take on a variety of coordination modes with metal ions. Pyrazine is a six-membered aromatic heterocycle bearing two nitrogen atoms, which has sp2 hybridized C atoms with C-H hydrogen bonds. This work describes the synthesis and structural characteristics of HOF based on squaric acid and pyrazine. Based on single crystal X-ray diffraction data, this MOF crystallizes in the triclinic P-1 space group. Each asymmetric unit is composed of H2SQ and pyrazine. All squaric acid molecules share one H atom with the N atom of pyrazine molecules. The layer distance between nearby O atoms from squaric acid in different layers equals 5.29 Å. Also, our HOF showed high adsorption capacity the during experiments. The composition and comparative characteristics of HOF are given using SCXRD, PXRD, SEM and UV-vis.

A cold roll-bonding process is applied to fabricate an AA6061/AA5052/AA6061/AA5052 layered sheet. Two AA6061 and one AA5052 sheets of 2mm thickness, 40mm width and 300mm length are alternately stacked, then reduced to a thickness of 2.0 mm by multi-pass cold rolling after surface treatment such as degreasing and wire brushing. The rolling is performed at ambient temperature without lubricant using a 2-high mill with a roll diameter of 400 mm at a rolling speed of 6.0 m/sec. The roll-bonded AA6061/AA5052/AA6061/AA5052 layered sheet is then hardened by natural aging (T4) and artificial aging (T6) treatments. The microstructure of the as-roll bonded and the age-hardened Al sheets was revealed by SEM observation; the mechanical properties were investigated by tensile testing and hardness testing. After T4 and T6 aging treatment, the specimens had a recrystallization structure consisting of coarse equiaxed grains in both AA5052 and AA6061 regions. The as-roll-bonded specimen showed a clad structure in which the hardness of AA5052 regions was higher than that of AA6061 regions. However, after T4 and T6 aging treatment, specimens exhibited different structures, with hardness of AA6061 regions higher than that of AA5052 regions. Strengths of T6 and T4 age-treated specimens were found to increase by 1.55 and 1.36 times, respectively, compared to the value of the starting material.

A cold roll-bonding process using AA1050, AA5052 and AA6061 alloy sheets is performed without lubrication. The roll-bonded specimen is a multi-layer complex aluminum alloy sheet in which the AA1050, AA5052 and AA6061 sheets are alternately stacked. The microstructural evolution with the increase of annealing temperature for the roll-bonded aluminum sheet is investigated in detail. The roll-bonded aluminum sheet shows a typical deformation structure in which the grains are elongated in the rolling direction over all regions. However, microstructural evolution of the annealed specimen is different depending on the type of material, resulting in a heterogeneous microstructure in the thickness direction of the layered aluminum sheet. Complete recrystallization occurs at 250 oC in the AA5052 region, which is lower by 100K than that of the AA1050 region. Variation of the misorientation angle distribution and texture development with increase of annealing temperature also differ depending on the type of material. Differences of microstructural evolution between aluminum alloys with increase of annealing temperature can be mainly explained in terms of amounts of impurities and initial grain size.

마에는 다양한 기능성 성분이 함유되어 있어서 식용 및 약용으로 다양하게 이용되고 있다. 특히 allantoin은 대표적인 마의 2차 대사산물로서 의약품 및 기능성 화장품 제조에도 활용되는 고부가가치 산물이다. 본 연구에서는 아미노 결합 정지상 HPLC 컬럼을 이용하여 마의 속과 껍질의 allantoin 함량을 분석하였다. Allantoin 표준용액의 검량 선의 결정계수(R2)값은 0.9999로 높은 직진성을 보였으며, 검출한계(LOD)와 정량한계(LOQ)는 각각 0.0229 mg/mL 및 0.0694 mg/mL로 설정되었다. 마 속과 껍질의 건조중량 기준 allantoin 함량은 각각 3.09±0.02 mg/g, 3.91±0.11 mg/g으로 속보다 껍질에 더 많은 allantoin이 함유되어있음을 확인하였다. 따라서 이러한 결과를 토대로 향후 농업부산물인 마껍질이 새로운 고부가가치 기능성 소재로 활용될 수 있음을 확인하였다.

The conversion of all carbon preforms to dense SiC by liquid infiltration can become a low-cost and reliable method to form SiC-Si composites of complex shape and high density. Reactive sintered silicon carbide (RBSC) is prepared by covering Si powder on top of 0.5-5.0 wt% Y2O3-added carbon preforms at 1,450 and 1,500°C for 2 hours; samples are analyzed to determine densification. Reactive sintering from the Y2O3-free carbon preform causes Si to be pushed to one side and cracking defects occur. However, when prepared from the Y2O3-added carbon preform, an SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C = SiC reaction, 3C and 6H of SiC, crystalline Si, and Y2O3 phases are detected by XRD analysis without the appearance of graphite. As the content of Y2O3 in the carbon preform increases, the prepared RBSC accelerates the SiC conversion reaction, increasing the density and decreasing the pores, resulting in densification. The dense RBSC obtained by reaction sintering at 1,500 oC for 2 hours from a carbon preform with 2.0 wt% Y2O3 added has 0.20% apparent porosity and 96.9% relative density.

The directed energy deposition (DED) process of metal 3D printing technologies has been treated as an effective method for welding, repairing, and even 3-dimensional building of machinery parts. In this study, stainless steel 316L (STS316L) and Inconel 625 (IN625) alloy powders are additively manufactured using the DED process, and the microstructure of the fabricated STS316L/IN625 sample is investigated. In particular, there are no secondary phases in the interface between STS316L and the IN625 alloy. The EDS and Vickers hardness results clearly show compositionally and mechanically transient layers a few tens of micrometers in thickness. Interestingly, several cracks are only observed in the STS 316L rather than in the IN625 alloy near the interface. In addition, small-sized voids 200– 400 nm in diameter that look like trapped pores are present in both materials. The cracks present near the interface are formed by tensile stress in STS316L caused by the difference in the CTE (coefficient of thermal expansion) between the two materials during the DED process. These results can provide fundamental information for the fabrication of machinery parts that require joining of two materials, such as valves.

본 연구에서는 CFRP판으로 보강된 콘크리트 보의 피로파괴 특성을 알아보기 위하여 보강재의 정착 길이, 보강재의 정착넓이, 보강재의 정착량을 실험변수로 반복 하중에 따른 역학적 거동과 파괴형태를 분석하고 CFRP판 사용에 대한 안전성과 타당성을 평가하도록 하였다. 반복하중의 범위는 극한하중의 10~70%를 취하고 3점 재하방식으로 sine파를 이용한 3Hz의 속도로 재하 하였다. 실험결과 보강길이가 작을수록 보강재 단부에서 박리파괴가 일어날 확률이 증가하였고 반복하중의 횟수도 현저히 감소되어 안정성은 다소 감소됨을 알 수 있다. 보강두께는 감소할수록 피로수명은 증가하지만 CFRP와 콘크리트사이의 부착력 이 저하되어 경계면에서 박리파괴가 일어나 최종파괴를 이루었다. 보강넓이는 감소할수록 피로 횟수는 현저하게 증가되었고 보강재의 이용률도 현저하게 증가되어 안정성도 증가함을 알 수 있다.

In this study, the experiments and analyses were carried out in order to investigate the fracture characteristics on the adhesive at the specimen bonded with aluminum and aluminum-foam. The same conditions were given for the experiments and analyses. The results are investigated by the graph of reaction force according to displacement. It was found that the experimental and the analytical data were very similar to each other. On the basis of the data, the reliability of the analysis data could be confirmed. The notches were produced at the distances of 40, 110, 150, and 190 mm from the front of the test specimen, and the maximum reaction force was compared accordingly. It was found that the highest reaction force was generated at the front end of the adhesive and the lowest reaction force was found at the middle of the adhesive interface. Finally, when the equivalent stress in the test specimen was examined, it was found that the highest stress was obtained at the distance of 110 mm. It can be deduced. As the notch formation point are similar to the point when stress is dispersed as the adhesive is peeled off, it is possible to infer the high stress compared to other test specimens.

In this study, we investigated the properties of adhesive materials with different lightweight materials such as CFRP and Al-foam. The specimens were tested and analyzed using DCB (Double Cantilever Beam) specimens. In order to secure the reliability of the finite element method, the test and analysis were carried out, and the reliability of the finite element method was secured by using the graph of reaction force to displacement based on the experiment and analysis. The study on the adhesive failure characteristics according to the position of notch hole proceeded. Notch holes were generated at the locations of 40, 110, 150 and 190 mm from the beginning of the specimen near the bonding interface, and the analysis conditions used were the same as those used for securing reliability. The obtained study results are compared with reaction force and equivalent stress. In the case of reaction force, the overall tendency is similar but the difference in maximum reaction force is found. It was found that higher reaction forces appeared at the beginning than at the end of the bonding interface. When the equivalent stresses in the specimens were examined, the value of CFRP was seen to be 30 times higher as much as that of Al-foam.

In this paper, the experimental study and finite elements analysis were conducted on homogeneous and dissimilar metals single lap-shear bonded joints to investigate the factor that affect the joint failure load. It was found that factors which have the significant effects on the failure load of the joint was stiffness of the adherends. And from experimental results, it can be confirmed that the failure load increases linearly with overlap length increases. And the failure load of dissimilar metal joints is approximately 1KN(10 ～17%) larger than homogeneous metal joints. In order to confirm this phenomenon, the stress distribution and strain distribution of the specimens were analyzed through the finite element analysis. The difference between homogeneous metals joints and dissimilar metals joints is that stress and strain in adhesive are concentrated at the end of the overlap zone close to aluminium which has lower rigidity than aluminium in case of dissimilar metals joints. From high rigidity of steel, the stress concentration in bonds are decreased and it cause increase of the failure strength at dissimilar metal joints.

전통적인 FRP 선체 제작에는 mould가 요구되며, mould의 높은 제작비용은 FRP 선박 제작자에게 비용부담을 주고 있다. 이를 극복하기 위한 방안으로 강선 건조에서 사용되는 블록 혹은 모듈 방식의 제작기법에 착안한 modular construction 방안이 제시되었다. 이 제작방안을 FRP 선체에 효율적으로 적용하기 위해서는 설계 및 제작 측면에서 간략하면서도 구조적 안정성을 갖는 접합 이음부 개발이 이루어져야 한다. 따라서, 본 논문에서는 모듈방식의 FRP 선체 제작을 위해 moulding-in 개념을 기반으로 한 경제적인 접합 이음부 개발에 관한 연구를 수행하였다. FRP 샌드위치 판을 대상으로 step, scarf-step 그리고 scarf 이음부 형상을 갖는 moulded-in을 수지주입식진공성형 공정에 도입하여 성공적으로 접합된 FRP 샌드위치판 을 제작하였다. 이에 대해 구조적 안정성 평가를 목적으로 인장 및 4점 굽힘 시험 그리고 유한요소해석을 수행하였다. 시험과 해석결과에 대한 비교 연구를 통해 본 연구에서 개발된 접합 이음 내용이 모듈방식의 FRP 선체 제작에 적용 가능함을 확인할 수 있었다.

Reaction-bonded silicon carbide (RBSC) is a SiC-based composite ceramic fabricated by the infiltration of molten silicon into a skeleton of SiC particles and carbon, in order to manufacture a ceramic body with full density. RBSC has been widely used and studied for many years in the SiC field, because of its relatively low processing temperature for fabrication, easy use in forming components with a near-net shape, and high density, compared with other sintering methods for SiC. A radiant tube is one of the most commonly employed ceramics components when using RBSC materials in industrial fields. In this study, the mechanical strengths of commercial RBSC tubes with different sizes are evaluated using 3-point flexural and C-ring tests. The size scaling law is applied to the obtained mechanical strength values for specimens with different sizes. The discrepancy between the flexural and C-ring strengths is also discussed.

The durability degradation of concrete pavement by winter deicer is brought up as a significant risk, and its maintenance brings a high expense. Therefore, a proper repair materials for such concrete pavement are required. In this study, the properties of compressive strength, ability to resist chloride ion penetration, and dry shrinkage of Chemically bonded ceramics(CBC) and Calcium Sulfo Aluminate based ultra rapid harding cement(CSA) were assessed to evaluate its applicability as a repair material of concrete pavement road. As a result, the CBC mortar flow showed a 220㎜, and the initial setting time of CBC was 18 minutes. The compressive strength of CBC mortar was 31.3㎫ in 2 hours, 56.6㎫ in 24 hours, and 79.1㎫ in 28 days, showing a significant level. And the ability to resist chloride ion penetrations of CBC showed 433 Coulombs, which fell under very low level. The drying shrinkage of CBC mortar until 56 days was between 150 × 10-6 with -100 × 10-6, showing a significant very low level. As above, CBC has excellent compressive strength, chloride ion penetration resistance, and volume stability, and showed better performance than CSA. Therefore, CBC in the future could be used in repair of concrete pavement.