To improve photocatalytic performance, a PbS/ZnO/TiO2 nanotube catalyst was synthesized, and its surface characteristics and photocatalytic efficiency were investigated. The hybrid photocatalysts were produced by anodic oxidation and successive ionic layer adsorption and reaction(SILAR). The photocatalytic efficiency was evaluated using the dye degradation rate. The PbS/ZnO/TiO2 photocatalyst significantly enhanced the photocatalytic activity for dye degradation, which was ascribed to the synergistic effect of their better absorption of solar light and a decrease in the rate of excited electron-hole recombination.

HMDS를 리간드로 하는 PbS 콜로이드 양자점 물질을 만들었다. 양자점 물질의 전자광학적 밴드갭 의 크기는 UV/VIS과 IR 스펙트럼을 측정하여 알아낼 수 있었다. PbS 콜로이드 양자점 물질을 합성할 때 만 들어 지는 입자의 크기를 조절하기 위하여 반응온도를 100~160℃ 사이에서 변화시켰으며 이에 따라 흡수스펙 트럼의 피크위치에 변화가 있음을 관찰할 수 있었다. HOMO와 LUMO 사이에 해당하는 밴드갭은 800~1200nm 에서의 피크 위치변화를 보였으며 피크위치의 변화량은 반응물질을 섞었을 때 반응용기 온도에 선형적으로 변화하는 관계를 얻을 수 있었다.

Swelling of the heat-treated netting for gillnet was estimated through the netting height in square acrylic tank. Experimental Nylon netting and PBSAT netting were heat-treated by using the high-degree vacuum method in hot water after net making. Heat-treatment temperatures were conducted with Nylon netting 105°C and PBSAT netting 62°C, 65°C, 66°C, 67°C. The swelling measurement method of a netting using the square tank was capable of the reduction measurement errors comparing with measurement methods of a mesh inner angle and the shortening rate of a mesh size. In addition, this method was available to comparison evaluation for each netting more easily. Wet type heat-treatment apparatus with high-degree vacuum was shown higher 7∼8°C inner side temperature than a setting temperature. The tensile strength and elongation of Nylon netting and PBSAT netting were shown higher wet condition than dry condition. The tensile strengths of PBSAT monofilaments in dry and wet condition were sharply decreased at heat-treatment temp. 75°C than heat-treatment temp. 74°C

The monofilament with 0.304mm of diameter was produced using a polybutylene succinate (PBS) resin, and a gill net was made by it. We investigated the impact of heat setting temperature on the mechanical properties, knot state and height of gill net. Heat treatment was carried out using the high pressure steam machine for 20 minutes at temperature of 55℃, 60℃, 70℃ and 75℃. Before heat treatment, the strength and elongation of PBS monofilament were estimated to be 48.1kg/mm2, 23.8% at unknot, 37.6kg/mm2, 18.8% at single knot, 26.6kg/mm2, 22.9% at double knot in dry condition, respectively. The strength and elongation of PBS monofilament with double knot were decreased as heat setting temperature increased, and the decreasing rate of strength was showed to be higher than that of elongation. It was not found any differences in strength and elongation of PBS monofilament yarn with double knot at the 65℃ and 70℃ of heat setting temperature by 5% significance of T-test, but there was a significant difference at the 70℃ and 75℃ of heat setting temperature. The net's height and length from leg to leg appeared no differences at the 70℃ and 75℃ of heat setting temperature. In results, it was investigated that the PBS monofilament gill net with the maximized physical properties could be manufactured at 70℃ of heat setting temperature using a high pressure steam machine for 20 minutes.

In order to improve the breaking strength and elongation of Polybutylene succinate (PBS) monofilament, the monofilament was produced by blending PBS and Polybutlyne adipate-co-terephthalate (PBAT). The PBS/PBAT blend monofilament was prepared by the melt spinning system, and the weight ratios of the compositions of PBS/PBAT was 100/0, 95/5, 90/10 and 85/15, respectively. The breaking strength, elongation, softness and crystallization of PBS/PBAT blend monofilament were analyzed by using a tensionmeter, softness measurement, X-ray diffractometer in the both dry and wet conditions. The PBS/PBAT blend monofilaments were spun in the take-up velocity of 1.19m/sec under the drawing ratio of 6.8:1 condition. The production volumes of PBS/PBAT blend monofilaments showed 20% less than that of Nylon. The breaking strength of PBS/PBAT blend monofilaments were decreased as PBAT contents increased, while elongation and softness were increased. In case of PBAT content were over 5%, the breaking strength, elongation and softness of PBS/PBAT blend monofilaments were not shown to increase in spite of increasing in PBAT contents. Based on these results, it was possible to make the monofilaments with the maximized physical properties when the PBAT contents at 5%.

Biodegradable polybutylene succinate(PBS) is an environment friendly plastics for fisheries, because it can mitigate the ghost fishing problem caused by gill-net and trap fisheries. To evaluate photodegradability of PBS monofilament in comparison with polyamide(PA) and polyethylene(PE) monofilament, these 3 types of monofilaments were spun and exposed to ultraviolet light(UV) of weather-ometer for 900 hours, and then their modification, crystal structure, strength, and extensibility were analysed. PBS monofilament did not show any crack and maintained its crystal structure after 900 hour exposure to UV whereas PE monofilament began showing cracks and structure modification after 600 hour exposure. Under UV exposure, the strength and extensibility decreased more rapidly in PBS than in PA and PE. We estimate that gill nets made of PBS monofilament can endure for about 1 year. The breaking strength and elongation decreased linearly with the exposure time for the 3 types of monofilaments. The derived regression equations of the residual tenacity(RT, kg/mm2) and the residual extensibility(RE, %) with the exposure time in year(Y) for each monofilament were; PBS : RT=48.598 - 8.6437Y(R2=0.93), RE=28.165 - 7.3233Y(R2=0.98), P A : RT=59.771 - 8.6437Y(R2=0.98), RE=32.198 - 5.2772Y(R2=0.92), P E : RT=60.898 - 5.6528Y(R2=0.98), RE=11.887 - 0.7188Y(R2=0.98).

This study is a case of construction after bridge demolition due to the aging of bridges operating the railway. Due to the influence of the pier vibration on the railway, the influence of the railway line, the construction period, etc., the P.B.S technique was applied to the coping pile foundation. It was completed in 5 days per 1 bridge pier by the PBS method. Since it is constructed in the dry season (from October to April) without vibration and noise, it can be installed safely on the rail rail of the pier of the bridge .