KEPCO KPS is the contractor for the full system decontamination (FSD) of Kori Unit 1 and under preparation such as modification, lay out for equipment installation, setting up tie-in/out point for chemical injection and way to pressurize the system, of its successful performance. In this research, KPS introduced how KPS has designed and prepared for the FSD project and how will the chemical decontamination process be implemented. As described in the previous research, chemical decontamination process is planned to be conducted for three cycles and each cycle is consisted of oxidation, reduction, decomposition, and purification. Oxidation and reduction process were conducted at 90°C. Chemical decomposition and purification process were conducted at 40°C due to the damage of IX by the heat. If the decontamination result does not meet the target DF and the dose rate, additional cycle can be conducted. Expected volume of process water for FSD is 200 m3. Three systems have been designated as decontamination targets: reactor coolant system (RCS), residual heat removal system (RHRS), chemical volume control system (CVCS). For the steady flow rate, existed plant equipment such as reactor coolant pump (RCP) will be operated and modifications on some components will be conducted. Due to the limited space for installation, decontamination equipment and other resources are distributed to three different places. KPS designed the layout of equipment installed inside the containment vessel. The layout contains the information of shielding for highly radiated equipment such as IX and filter skid.

The primary heat transport system consists mainly of the in-core fuel channels connected to the steam generators by a system of feeder pipes and headers. The feeders and headers are made of carbon steel. Feeders run vertically upwards from the fuel channels across the face of the reactor and horizontally over the refueling machine to the headers. Structural materials of the primary systems of nuclear power plants (NPPs) are exposed to high temperature and pressure conditions, so that the materials employed in these plants have to take into accounts a useful design life of at least 30 years. The corrosion products, mainly iron oxides, are generated from the carbon steel corrosion which is the main constituent of the feeder pipes and headers of this circuit. Typical film thickness on CANDU-PHWR surface is 75μm or 30mg/cm2. Deposits on PHWR tends to be much thicker than PWR due to use of carbon steel and also for the source of corrosion products available on the carbon steel surface. Degradation of carbon steel for the feeder pipes transferring the primary system coolant by flow-assisted corrosion in high temperature has been reported in CANDU reactors including Point Lapreau, Gentully-2, Darlington and Bruce NPPs. The formation of Fe3O4 film on a carbon steel surface reduces the dissolution rate of steel substantially. The protectiveness of the Fe3O4 film over the carbon steel is affected by the environmental factors and the operational parameters of the feeder pipes, including the velocity, wall shear stress, solution pH, temperature, concentration of dissolved iron, quality of solution, etc. For effective chemical decontamination of these thick oxides containing radionuclides such as Co-60, it is necessary to understand the corrosion behaviors of feeder pipes and the characteristics of oxide formed on it. In this work, we investigated the growth of oxide films that develop on type SA-107 Gr. B carbon steel in high temperature water and steam environment by scanning electron microscopy (SEM) and glow discharge optical emission spectrometry (GD-OES) for the quantification and the solidstate speciation of metal oxide films. This study was especially focused to set the experimental tests conditions how to increase the oxide thickness up to 50 m by changing the oxidation conditions, such as solution chemistry and thermo-hydraulic conditions both temperature and pressure and so on.

Economical radioactive soil treatment technology is essential to safely and efficiently treat of high-concentration radioactive areas and contaminated sites during operation of nuclear power plants at home and abroad. This study is to determine the performance of BERAD (Beautiful Environmental construction’s RAdioactive soil Decontamination system) before applying magnetic nanoparticles and adsorbents developed by the KAERI (Korea Atomic Energy Research Institute) which will be used in the national funded project to a large-capacity radioactive soil decontamination system. BERAD uses Soil Washing Process by US EPA (402-R-007-004 (2007)) and can decontaminate 0.5 tons of radioactive soil per hour through water washing and/or chemical washing with particle size separation. When contaminated soil is input to BERAD, the soil is selected and washed, and after going through a rinse stage and particle size separation stage, it discharges decontaminated soil separated by sludge of less than 0.075 mm. In this experiment, the concentrations of four general isotopes (A, B, C, and D which are important radioisotopes when soil is contaminated by them.) were analyzed by using ICP-MS to compare before and after decontamination by BERAD. Since BERAD is the commercial-scale pilot system that decontaminates relatively large amount of soil, so it is difficult to test using radioactive isotopes. So important general elements such as A, B, C, and D in soil were analyzed. In the study, BERAD decontaminated soil by using water washing. And the particle size of soil was divided into a total of six particle size sections with five sieves: 4 mm, 2 mm, 0.850 mm, 0.212 mm, and 0.075 mm. Concentrations of A, B, C, and D in the soil particles larger than 4 mm are almost the lowest regardless of before and after decontamination by BERAD. For soil particles less than 4 mm, the concentrations of C and D decreased constantly after BERAD decontamination. On the other hand, the decontamination efficiency of A and B decreased as the soil particle became smaller, but the concentrations of A and B increased for the soil particle below 0.075 mm. As a result, decontamination efficiency of one cycle using BERAD for all nuclides in soil particles between 4 mm and 0.075 mm is about 45% to 65 %.

Canada’s Pickering Unit 3 was performed a three-stage decontamination from June to August 1989 in preparation for pressure tube replacement. The first step was a reducing CAN-DECON treatment to dissolve the magnetic film inside the reactor, which was applied following partial defueling of the reactor core. The second step was an oxidative dilute alkaline permanganate treatment to remove the chromium-rich oxides of the stainless steel parts. And the final CAN-DECON step was applied continuously after completely removing fuel from the reactor core. In situ pipe gamma-ray spectroscopy techniques were applied to measure radioactivity within feeder piping during various stages of Pickering Unit 3 decontamination. Measurements were performed at a maximum dose rate of 5 mSv/h, and both the detector and the scanned feeder pipe were properly shielded from other neighboring pipes. 60Co was the dominant radionuclide in feeder piping prior to decontamination. And radionuclides 103Ru, 95Zr, 95Nb, 59Fe, 140La and 124Sb were detected. The Co-60 radioactivity was 2.09×105 Bq/cm2 before decontamination and 3.11×103 Bq/cm2 after decontamination in the inlet feeder pipe T18. And in the outlet feeder pipe P21, it is 2.56×104 Bq/cm2 before decontamination and 2.04×103 Bq/cm2 after decontamination.

It is reported that 48 pressurized heavy water reactors (PHWRs) are in operation, and 10 PHWRs including Wolsong-1 NPP have been permanently shut down in the world. In the case of PHWRs, which have been permanently ceased, they are managed through the delayed decommissioning method, but there are no cases of dismantling. Therefore, technology development is urgent for the effective decommissioning of PHWRs. Unlike PWRs, PHWRs are separated into coolant system and moderator system. Most of pipes and systems of coolant system are mainly composed of carbon steel, expect of the steam generator tubes which are composed of nickel alloy. On the other hand, the moderator system is composed of stainless steel. In the case of stainless steel, the inner layer of the oxide film is composed of chromium oxide, and the outer layer is composed of iron and nickel oxide in enriched. To remove two oxide layers, it is needs to different decontamination method, the coolant system can perform the system decontamination process through a reduction process, but in the case of the moderator system, the oxidation/reduction process is required because it has a material and oxide film similar to PWRs. In this study, this is evaluated the oxide film removal rate according to the type of stainless steel and temperature in order to remove the oxide film deposited in the moderator system. The experiments were carried out at temperatures of 60, 70, 80 and 90°C, with a concentration of 200 ppm of permanganic acid and nitric acid, and 2,000 ppm of oxalic acid, respectively. The results of the oxide film removal rate test for SUS304 showed 29% at 60°C, 38% at 70 and 80°C, and 41% at 90°C. For SUS403, the oxide film removal rate experiment results showed 62% at 60°C, 85% at 70°C, 94% at 80°C, over 99% at 90°C. The results showed that the removal efficiency of the oxide film increased as the temperature increased. Following the results of experimental, the optimum temperature of oxide removal in composed of the stainless steel material is to be 90°C for decontamination of PHWR.

Laser scabbling has the potential to be a valuable technique capable of effectively decontaminating highly radioactive concrete surface at nuclear decommissioning sites. Laser scabbling tool using an optical fiber has a merits of remote operation at a long range, which provides further safety for workers at nuclear decommissioning sites. Furthermore, there is no reaction force and low secondary waste generation, which reduces waste disposal costs. In this study, an integrated decontamination system with laser scabbling tool was employed to test the removal performance of the concrete surface. The integrated decontamination system consisted of a fiber laser, remote controllable mobile cart, and a debris collector device. The mobile cart controlled the translation speed and position of the optical head coupled with 20 m long process fiber. A 5 kW high-powered laser beam emitted from the optical head impacted the concrete block with dimensions of 300 mm × 300 mm × 80 mm to induce explosive spalling on its surface. The concrete debris generated from the spalling process were collected along the flexible tube connected with collector device. We used a three-dimensional scanner device to measure the removed volume and depth profile.

In this research, KPS manufactured Full System Decontamination (FSD) equipment, which is consisted of Oxidizing Agent Manufacturing System (OAMS), Chemical Injection System (CIS), RadWaste Treatment System (RWTS), Chemical Waste Decomposition & Treatment System (CWDS) and conducted demonstration test to prepare Decontamination and Decommissioning (D&D) project of Kori nuclear power plant in Korea. Each equipment of FSD was modularized due to the limited size of equipment hatch of Kori nuclear power plant. To simulate the expected circumstances in nuclear power plant such as usage of heater or position of each equipment, additional equipment was used. The chemical concentration and flow rate of process water for FSD were used as mentioned in the previous study by KHNP CRI. FSD was conducted for three cycles and each cycle was consisted of oxidation, reduction, chemical decomposition and purification. Oxidation and reduction process were conducted at 90°C. Chemical decomposition and purification process were conducted at 40°C due to the damage of UV lamp and IX by the heat. Total volume of process water for FSD demonstration test was 2.5 m2. KPS conducted decontamination performance review by calculating thickness reduction and weight loss of installed specimen. Operational review was conducted as if FSD test was conducted in the field based on the result of demonstration test. One of the most prioritized features is the workers’ safety. Also, the appropriate position of equipment needs to be considered to meet the required specification of component.

Minimizing of radiation exposure for the operating and decommissioning personnel is a key indicator for safe operation of the NPP. This is reflected in the application of the ALARA (As Low As Reasonable Achievable) principle. The main objectives of radiation management during full system decontamination for NPP decommissioning are to reduce the exposure dose, prevent contamination of the body and reduce solid radioactive waste. In order to reduce exposure of workers, the dose rate should be reduced by installing a temporary shield after evaluating the dose rate for the piping, component and decontamination equipment of the decontamination path before full system decontamination. Furthermore, unnecessary exposure to radiation should be reduced by thoroughly entering and exciting the radiation area and limiting the access to the high-radiation area except for workers or persons concerned. A telemetric dosimetry system should be as installed to remotely monitor radiation levels at different locations within the decontamination flow path. Remote monitoring of radiation fields using teledosimetry worked well in assessing process effectiveness and is highly recommended. However, care must be taken to place the detectors in appropriate locations. For the prevent of body contamination, it is necessary to install a fence using a heat-resistant waterproof sheet to prevent leakage of highly radioactive contamination water. When replacing high-dose filters and ion exchange resins, it is necessary to remotely monitor to reduce the exposure dose of workers.

The purpose of full system decontamination before decommissioning a nuclear power plant is to reduce radiation exposure of decommissioning workers and to reduce decommissioning waste. In general, full system decontamination removes the CRUD nuclides deposited on the inner surface of the reactor coolant system, chemical and volume control system, residual heat removal system, pressurizer, steam generator tube, etc. by chemical decontamination method. The full system decontamination process applied to Maine Yankee and Connecticut Yankee in the USA, Stade, Obrigheim, Unterweser, Nekawestheim Unit 1 in Germany, Mihama Unit 1 and 2 in Japan, Jose Cabrera Unit 1 in Spain, and Barseback Unit 1 and 2 in Sweden are HP/CORD UV, NP/CORD UV, and DfD. In this study, the quantity of 60Co radioactivity removal, metal removal, ion exchange resin and filter generation according to reactor power, surface area and volume of the full system decontamination flow path, and the decontamination process were compared and analyzed. In addition, the quantity of 60Co radioactivity removal by each nuclear power plant was compared and analyzed with the evaluation results of the 60CO radioactivity inventory of the Kori Unit 1 full system decontamination loops conducted by SAE-AN Enertech Corporation.

원전 일차계통 HyBRID 제염공정에서 발생되는 제염폐액에는 황산이온과 방사성 핵종을 포함한 금속이온 및 발암성 물질의 하이드라진을 포함하고 있어 이를 안전한 수준으로 처리할 수 있는 기술개발이 필요하다. 본 연구에서는 모의 제염폐액 내 황산 및 금속이온의 제거와 하이드라진의 분해시험을 실시하여 황산이온, 금속이온 및 하이드라진을 효과적으로 제거할 수 있는 HyBRID 제염폐액 처리공정을 도출하였으며, 1 L 규모에서의 반복실험과 Pilot 규모(300 L/batch)에서의 평가시험을 통해 도출한 HyBRID 제염폐액 처리공정의 성능 재현성과 적용성을 검증하였다.

원자력발전소 운영 과정에서 발생되는 폐기물인 폐수지를 원천적으로 저감하기 위해, 새로운 폐수 정화기술을 개발하고 원전 폐수처리시스템에 가상적으로 적용하여 효용성을 평가하고자 하였다. 본 기술의 기본 원리는 폐수에 존재하는 주요 핵 종이온들을 생물학적 혹은 화학적 방법을 통해 무기 결정광물로 바꾸는 방식이다. 실험실에서 폐수를 대상으로 회분식실험을 통해 핵종 제거율을 측정한 결과, 생물학적 방법은 24시간 이내에 세슘을 80% 이상 제거하였고, 화학적 방법은 95% 이상 세슘을 선택적으로 제거할 수 있었다. 그리고 원전 폐수에 존재하는 다른 주요 핵종들(Co, Ni, Fe, Cr, Mn, Eu)에 대해서도 초기 99% 이상의 높은 제거율을 보여 주었다. 우리는 APR1400 원자력발전소의 폐수처리시스템 공정에서 역삼투압(R/O)과 유기 이온교환수지 모듈 사이에 가상으로 본 기술 모듈을 설치하였다. 가상의 모듈 설치를 통한 기술적 타당성 평가를 통해, 우리는 폐수의 주요 핵종들이 90% 이상 선택적으로 제거되고 폐수지의 발생량이 대폭 감소된다는 결과를 얻을 수 있었다. 이러한 결과가 의미하는 바는 본 기술이 향후 미래에 상용화되었을 경우, 폐수지 관리 비용을 크게 감소시키고 수지 수명도 대폭 연장시킬 수 있어, 결과적으로 월성 방사성폐기물 처분시설의 저장고 포화시점을 최대한 늦출 수 있는 이점이 있다.