Modification of C/C composite bipolar plate for improving electrical conductivity was carried out by addition of electroconductive carbon black (EC-CB). Carbon black was carefully mixed to methanol-containing phenolic resin, impregnated into 2D-carbon fabrics, hot pressed and then carbonized to obtain composite plate. Inclusion of electro-conductive carbon black enhanced the electrical conductivity of the C/C composites by increasing the conduction path. Addition of 10 vol% carbon black increased the electrical conductivity from 5.5/Ωcm to 32/Ωcm and reduced the crack formation by filling effect, resulting in the increase of flexural properties of composite plate. However, at carbon black content over 10 vol%, flexural properties decreased by delaminating role of excess carbon black at the interface in C/C composites.

The pack-cementation process is the method which is formed SiC coating layer to improve weak oxidation properties of CFRCs (carbon fiber-reinforced carbons). This method develops the anti-oxidation coating layer having no dimensional changes and good wetting properties. In this study to improve the oxidative resistance of the prepared 4D CFRCs, the surface of CFRCs is coated by SiC using pack cementation method. The mechanical properties of SiC-coated 4D CFRCs are measured by the 3-point bending test, and their ablation properties are investigated by the arc torch plasma test. From the results, it is found that both mechanical and ablation properties of SiC-coated 4D CFRCs are much better than bare CFRCs.

Porous carbon from charcoal filled polypropylene composites were prepared and their mechanical properties were evaluated. In preparing the composites, crosslinking agent (sodium benzonate) were used in order to improve the bonding force between matrix and fillers. In this study, the effects of charcoal powder and sodium benzonate concentration on the mechanical properties and interface phenomena on the composites were evaluated. The mechanical properties of composites increased progressively with the decrease of filler loading. In the case of addition of the crosslinking agent into the composite, the mechanical properties were increased and showed maximum value at the 3 wt% concentration of sodium benzonate. According to the result of the TGA, the weight loss of composite according to crosslinking agent was not observed and initial thermal degradation temperature of composite reinforced charcoal was located at 390℃.

프로판(C3H8)을 반응가스로 사용하여 등온 저압화학기상침투법(low-pressure chemical vapor infiltration)으로 탄소/탄소 복합재료를 치밀화 할 때 반응온도, 반응가스농도, 가스유량, 반응압력 등의 제조공정변수들이 치밀화에 미치는 영향을 알아보기 위하여 실험계획법(Rdbust design method)에 의한 실험을 행하였다. 1회의 등온 저압화학기상침투 실험으로 탄소/탄소 복합재료의 부피 밀도와 표면과 내부의 부피 밀도의 차이를 특성치(characteristic value)로 한 실험계획법의 분산분석(analysis of variance)에 의하면 반응온도, 반응가스농도, 가스유량 등의 제고공정변수가 치밀화에 기여도가 높으며, 반응압력의 기여도와 제조공정변수들의 교호작용(interaction)에 의한 기여도는 낮은 것으로 나타났다. 반응온도가 1100˚C, 반응가스농도가 100% C3H8, 가스유량이 100 SCCM, 반응압력이 5torr인 조건에서 탄소/탄소 복합재료는 가장 높은 부피 밀도값을 나타내었으나 시편의 표면과 내부의 부피 밀도 차이값은 컸다.

The purpose of the present study is to examine characteristics of hydrogen sulfide adsorption using iron-activated carbon composite adsorbents prepared by ferric nitrate and ferric chloride. Prepared adsorbents were discussed on H2S adsorption capacity. Also, adsorbents were analyzed by surface analysis methods for illustrating the physical characteristics of H2S adsorption. The breakthrough tests of H2S were conducted at 3,333 ppm of inlet concentration, demonstrating that the adsorption capacity for iron-activated carbon composite adsorbents was in order of FC_AC (Ferric chloride_Activated carbon), FN_AC (Ferric nitrate_Activated carbon), FC (Ferric chloride) and FN (Ferric nitrate). Adsorption capacity of FC was 0.06 g/g, whereas FC_AC showed the highest capacity of 0.171 g/g. All adsorbents exhibited the amorphous type in physical appearance based on XRD analysis and high Fe content based on EDS analysis. The surface areas of composites were increased by adding activated carbon, exhibiting better adsorption capacity.

본 연구에서는 기존 강재브레이스 내진보강법이 가지는 좌굴문제 등 단점을 극복할 수 있는 중 저층 철근콘크리트 건축물에 효과적으로 적용할 수 있는 새로운 내진보강법을 개발하였다. Carbon Fiber Composite Cable (CFCC)을 이용하여 건축물 골조 외부에 X자 형태로 내진보강을 실시하고, 상부 및 하부 보 양 단부에 CFCC X-브레이싱을 고정하기 위해서 평판 및 돌출형 나사식 접합으로 내진보강을 실시하는 내진보강법으로서, 반복하중 실험을 통하여 내진보강 효과를 규명하였다. 실험체는 비교용 비보강 골조, 평판형 및 돌출형 CFCC X-브레이싱 내진보강 골조 실험체 총 3개를 제작하였다. 실험결과, 본 연구에서 개발한 CFCC 내진보강법은 강도증진형 내진보강법으로 드러났으며, 기존 강재브레이스 보강법 대비 중량증가가 거의 없으며, 재료자체가 압축에 대한 좌굴이 없으며, 경량이므로 시공성이 매우 우수하고 중량 및 체적대비 우수한 강도가 발휘될 뿐만 아니라 특히, CFCC의 직경을 변경함으로서 내진보강 목적 (강도 보강량)에 대응하여 내진성능을 쉽게 변화시킬 수 있는 장점이 있다.

The purpose of this paper is to verify the seismic strengthening effect of R/C buildings strengthened with the Carbon Fiber Composite Cable (CFCC) In this study, a three-story R/C building that constructed in the 1980s was selected, and its seismic performance before and after strengthening was evaluated based on the nonlinear dynamic analyses of members levels. The result indicated that the seismic strengthening effect of the proposed CFCC method was verified in terms of both strength and ductility demands, compared to the building before strengthening.

새로운 재료의 적용 실험을 통하여, 탄소섬유 분말 혼입 모르타르 복합 구조체의 파괴예측 자가진단 적용 특성에 대해 검토하였다. 본 연구에서는 자가진단 성능을 부여하기 위해 코크스와 탄소섬유분말(미분쇄 탄소섬유)이 혼입된 전도성 모르타르의 개발 및 자가진단 재료로서의 사용이 제안되었다. 각 하중재하단계에서의 균열발생 전후의 전기저항값과 AE특성치의 변화특성 시험을 통해, 이들 각 인자의 상호 연관성을 검토하였다. 그 결과, 코크스와 탄소섬유분말(미분쇄 탄소섬유)을 사용하여 새롭게 제안된 복합재료는 모르타르 시험체의 파괴 자가진단에 사용이 가능함을 알 수 있었다.

A biofiltration system using activated carbon/polyurethane composite as solid support inoculated with Bacillus sp. was developed for treating a gaseous stream containing high concentrations of H2S. The effects of operating condition such as the influent H2S concentration and the empty bed contact time (EBCT) on the removal efficiency of H2S were investigated. The biofilter showed the stable removal efficiencies of over 99 % under the EBCT range from 15 to 60 sec at the 300 ppmv of H2S inlet concentration. When the inlet concentration of H2S was increased, the removal efficiencies decreased, reaching 95 and 74%, at EBCTs of 10 and 7.5 sec, respectively. The maximum elimination capacity in the biofilter packed with activated carbon/polyurethane composite media was 157 g/m3/hr.