간행물

Carbon Letters KCI 등재 Carbon letters

권호리스트/논문검색
이 간행물 논문 검색

권호

Vol.1 No.2 (2000년 12월) 9

1.
2000.12 구독 인증기관 무료, 개인회원 유료
The synthetic methods for high yield of multiwalled carbon nanotube (MWNT) and singlewalled carbon nanotube (SWNT) with high purity by arc discharge have been investigated. MWNTs were synthesized under different pressures of helium and the gas mixture of argon and hydrogen. Relatively high pressure of 300-400 torr was required for high yield MWNTs synthesis at low bias voltage of about 20 V and 55 A, whereas low pressure of about 100 torr was required for SWNTs. The introduction of hydrogen gases during the synthesis of MWNTs improved the yield and purity of the samples. The SWNTs were synthesized by the assistance of a small amount of mixture of transition metals, which played as a catalyst during the formation process. The purity and yield of SWNTs were higher at a lower pressure and enhanced by mixing more components of the transition metals.
4,000원
2.
2000.12 구독 인증기관 무료, 개인회원 유료
In this work, the carbon fibers-reinforced carbon matrix composites made with different carbon char yields of phenolic resin matrix have been characterized by mechanical flexural tests for acoustic emission properties. The composites had been fabricated in the form of two-dimensional polyacrylonitrile based carbon fibers during the carbonization process. It was found that the composites made with the carbon char yield-rich of resin matrix result in better mechanical interfacial properties, i.e., the interlaminar shear strength (ILSS) of the composites. The data obtained from the acoustic emission monitored appeared to show that the composites made with carbon char yield-rich were also more ductile. From the acoustic emission results, the primary composite failure was largely depended on the debonding at interfaces between fibers and matrix. The interlaminar shear strengths of the composites were correlated with the acoustic emission results.
3,000원
3.
2000.12 구독 인증기관 무료, 개인회원 유료
This paper describes the mechanical properties and oxidation resistance of carbon fibers with and without additions of boron oxide additives, and describes the changes in the properties resulting from increased heat treatment temperature (HTT) of the fibers. Carbon fibers in this experiment were heat treated up to 2800℃ each with and without boron oxide treated on the surface of fibers. In the case of boron oxide added carbon fibers, they do not show the improvement of tensile strength and modulus compared to those of no treated carbon fibers below 2200℃ since they are doped substitutionally with boron above 2600℃, which accelerate the graphitization of carbon fibers. Boron oxide implanted carbon fibers showed high resistance to oxidation, however, when carbon fibers were heat treated below 2200℃, they showed almost the same trend of air oxidation.
4,000원
4.
2000.12 구독 인증기관 무료, 개인회원 유료
Naphtha cracking bottom oil was reformed with heat treatment and then spun at 310℃. These pitch-based carbon fibers were carbonized at 1000℃ after oxidation at 280℃, for 90 min. These fibers were chemically activated with molar ratio of KOH/CF (1 : 1) at different temperatures (250~900℃) for 1 hr. The process of activation was characterized with DTA, TGA, BET surface area and pore size distribution. The activation of fibers by KOH was performed by several process. One is the reduction process that carbon fiber was reacted with K2O produced from dehydration process above 400℃. The other is the process that K2CO3 was directly reacted with carbon fiber. At 800℃, the activation was performed by catalyzed mechanism that K2O was obtained from the reaction of metal potassium with CO2, then was changed to K2CO3. At 870℃, the activation was also observed that activation mechanism was promoted by metal catalyst with CO2 from decomposition of K2CO3. The specific surface area of prepared activated carbon fibers was dependent on the activation mechanism. The specific surface area was in the range of 1519~2000 cm3/g and was the largest prepared at 870℃. The pores developed were mostly micropores which was very narrow and uniform. The total pore volume was 0.58~0.77 cm3/g.
4,000원
5.
2000.12 구독 인증기관 무료, 개인회원 유료
Physical properties of artificial graphite electrodes were evaluated along three different directions; circumferential (X), radial (Y), and axial (Z) directions. Four kinds of commercial electrode products were used in this study for the evaluation; pole (AP) and nipple (AN) of manufacturer A, pole (BP) and nipple (BN) of manufacturer B. The mechanical, electrical, and thermal properties in X and Y directions were very similar to each other. In Z direction, however, the mechanical properties, including flexural strength and compressive strength, were higher, and electric resistance and thermal expansion were much lower than those in the other directions. The microstructures observed by optical microscope and scanning electron microscope revealed that the differences in properties by the measuring direction were caused by the preferential alignment of needle cokes along the Z direction. When comparing the properties of the electrode samples in the same direction, the mechanical properties mainly depended on the bulk density or porosity of the samples as well as preferential alignment of needle cokes.
4,000원
6.
2000.12 구독 인증기관 무료, 개인회원 유료
The present research was undertaken to evaluate the possibility of water purification filter with activated carbon fibers (ACFs) using a very low cost precursor consisting of phenolic resin coated on glass fibers. The simplified procedure involving coating, curing and activation and a very low cost glass fiber as a raw material were adopted in order to reduce manufacturing cost. The breakthrough curves of the manufactured ACFs and the commercial activated carbon (AC, Calgon F-200) were investigated in the initial concentration range from 19 to 49 ppm for benzene, toluene and ethylbenzene. From breakthrough profiles, the manufactured ACFs had significantly faster adsorption kinetics than the AC. Especially the benzene breakthrough curves, the manufactured ACF (13 g of ACF with 32% of carbon on the glass) was over the limited level (5 ppb) after flowing of 32 l at initial concentration of 15 ppm, while the commercial AC was shown about 3 ppm in initial adsorption.
4,000원
7.
2000.12 구독 인증기관 무료, 개인회원 유료
Porous carbon from charcoal filled polypropylene composites were prepared and their mechanical properties were evaluated. In preparing the composites, crosslinking agent (sodium benzonate) were used in order to improve the bonding force between matrix and fillers. In this study, the effects of charcoal powder and sodium benzonate concentration on the mechanical properties and interface phenomena on the composites were evaluated. The mechanical properties of composites increased progressively with the decrease of filler loading. In the case of addition of the crosslinking agent into the composite, the mechanical properties were increased and showed maximum value at the 3 wt% concentration of sodium benzonate. According to the result of the TGA, the weight loss of composite according to crosslinking agent was not observed and initial thermal degradation temperature of composite reinforced charcoal was located at 390℃.
3,000원
8.
2000.12 구독 인증기관 무료, 개인회원 유료
4,000원
9.
2000.12 구독 인증기관 무료, 개인회원 유료
4,000원