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Carbon Letters KCI 등재 Carbon letters

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Vol.32 No.4 (2022년 6월) 14건

1.
2022.06 구독 인증기관 무료, 개인회원 유료
Comparison and evaluation of the performance of graphene‑based biosensors
Walid Kamal Abdelbasset, Saade Abdalkareem Jasim, Dmitry Olegovich Bokov, Maria Sergeevna Oleneva, Anvar Islamov, Ali Thaeer Hammid, Yasser Fakri Mustafa, Ghulam Yasin, Arnold C. Alguno, Ehsan Kianfar
Carbon Letters Vol.32 No.4 pp.927-951 한국탄소학회
Abstract Biosensors are a group of measurement systems and their design is based on the selective identification of analyses based on biological components and physical and chemical detectors. Biosensors consist of three components: biological element, detector, and converter. The design of biosensors in various fields of biological sciences, medicine has expanded significantly. Biosensor technology actually represents a combination of biochemistry, molecular biology, chemistry, physics, electronics, and telecommunications. A biosensor actually consists of a small sensor and biological material fixed on it. Because biosensors are a powerful tool for identifying biological molecules, today they are used in various medical sciences, chemical industry, food industry, environmental monitoring, pharmaceutical production, health, etc. In fact, these sensors are a powerful tool to identify biological molecules. In fact, biosensors are analytical tools that can use biological intelligence to detect and react with a compound or compounds, and thus create a chemical, optical, or electrical message. The basis of a biosensor is to convert a biological response into a message. In this category, the use of telecommunication engineering technology and electromagnetic waves and frequency and radio spectrum is growing more and more to detect, measure, and determine the desired parameters in microbiology and laboratory sciences. The use of radio, optical, electromagnetic, ultrasonic, and infrared wave detection technology is part of the applications of telecommunication science in this field. Even image and audio processing systems have been instrumental in the discussion of biosensors in microbiology. The science of using fiber optics and waveguides, micro-strip antennas, and microelectromechanical technology is also very efficient in the construction and design of these biosensors.
6,300원
2.
2022.06 구독 인증기관 무료, 개인회원 유료
Current scenario and recent advancement of doped carbon dots: a short review scientocracy update (2013–2022)
Trisita Ghosh, Tushar Kanti Das, Poushali Das, Pallab Banerji, Narayan Ch. Das
Carbon Letters Vol.32 No.4 pp.953-977 한국탄소학회
The serendipitous uncovering of carbon dot (CQDs) as budding candidate of carbonaceous nanomaterial has become now one of the hot topics in the research of material science and technology. The unique features of CQDs such as photo-physical properties, excellent biocompatibility, ease of synthesis, good aqueous dispersity, high chemical stability, and accessible functional groups for further modification make them one of the promising competitors in biological, photonic and energyrelated applications. Although some review articles on CQDs have been published, they typically cover all areas of CQDs applications, and no particular evaluation on the advancement of doped CQDs (D-CQDs) has been reported so far. In this review, we demonstrated characteristic features of D-CQDs focusing on doping strategies, discussion on recently adopted various synthesis processes, its applications and its qualitative comparison with each other. The recently developed concept on understanding the structure and optical properties of D-CQDs are also briefly described followed by their application on various fields primarily concentrated on bio-imaging and sensing applications. We also speculate its use in a variety of intriguing fields and its perspectives in near future.
6,300원
3.
2022.06 구독 인증기관 무료, 개인회원 유료
Pristine graphene‑ink for 3D‑printed flexible solid‑state supercapacitor
Satendra Kumar, Manoj Goswami, Netrapal Singh, Prachi Soni, N. Sathish, Surender Kumar
Carbon Letters Vol.32 No.4 pp.979-985 한국탄소학회
Due to its capacity to manufacture low-cost 3D-printed structures, 3D-printing technology offers a unique opportunity for the fast epitome of various applications. Using a typical fused deposition modeling 3D printer along with a Discovery extruder, a graphene-ink can be 3D printed to produce an interdigitated electrode (IDE) arrangement. This work fabricated a 3D-printed planar supercapacitor from pristine graphene-ink without using high-temperature processing or functional additives. The printable ink (89%) is formulated from pristine graphene without the addition of any functional additives. The symmetric flexible supercapacitor is demonstrated with an excellent specific capacitance of 137.50 F/g at 0.5 A/g and an energy density of 12.23 Wh/kg. The obtained gravimetric energy density beats reported earlier carbon-based supercapacitors that are 3D or inkjet printed. The flexibility and robustness of 3D-printed devices are achieved up to 150° folding angles. This work demonstrates an efficient and easy method for fabricating practical energy storage devices featuring a customizable shape and excellent flexibility.
4,000원
4.
2022.06 구독 인증기관 무료, 개인회원 유료
Influence of carbon nanotube inclusions to electrical, thermal, physical and mechanical behaviors of carbon‑fiber‑reinforced ABS composites
Alinda Oyku Akar, Umit Hakan Yildiz, Seha Tirkes, Umit Tayfun, Ferda Hacivelioglu
Carbon Letters Vol.32 No.4 pp.987-998 한국탄소학회
Acrylonitrile–butadiene–styrene (ABS) terpolymer was compounded with short carbon fiber (CF) and carbon nanotube (CNT) using a micro-extruder followed by the injection molding process. Composite samples were fabricated with loading ratios of 20 wt.% CF and 0.1, 0.5 and 1.0 wt.% of CNT. Mechanical, electrical, thermo-mechanical, thermal, melt-flow, and structural investigations of ABS-based composites were conducted by performing tensile, impact, hardness, and wear tests, conductive atomic force microscopy (AFM), dynamic mechanical analysis (DMA), thermal gravimetric analysis (TGA), melt flow rate test (MFR), scanning electron microscopy (SEM) characterization techniques, respectively. According to mechanical test data of resultant composites including tensile and impact test findings, CNT additions led to the remarkable increase in tensile strength and impact resistance for CF reinforced ABS composites. The formation of synergy between CNT nanoparticles and CF was confirmed by electrical conduction results. The conductive path in ABS/CF composite system was achieved by the incorporation of CNT with different loading levels. SEM micrographs of composites proved that CNT nanoparticles exhibited homogeneous dispersion into ABS matrix for lower loadings.
4,300원
5.
2022.06 구독 인증기관 무료, 개인회원 유료
Photoelectrochemical and electrochemical urea oxidation with microwave‑assisted synthesized Co‑Fe2O3@NiO core–shell nanocomposites
Assia Karrab, Remi Bensimon, Diane Muller, Stéphane Bastide, Christine Cachet‑Vivier, Salah Ammar
Carbon Letters Vol.32 No.4 pp.999-1015 한국탄소학회
This work reported the electrochemical and photoelectrochemical (PEC) properties of a new photoelectrode based on hematite Co-Fe2O3@NiO, a photoactive semiconductor, was prepared using a process involving a combination of the co-precipitation and microwave-assisted synthesis of Fe2O3, Co-Fe2O3 and Co-Fe2O3@NiO, respectively. The obtained products were characterized by X-Ray powder Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray analysis (EDX), Ultraviolet–Visible (UV–vis) analysis, Fourier Transform Infrared spectroscopy (FT-IR). X-ray diffraction (XRD) pattern of the sample determined the crystal structure of α-Fe2O3 nanoparticles. The SEM image shows spherical nanoparticles. FTIR spectrospy spectrum confirmed the phase purity and chemical bond for the sample. Optical studies show a variation of band gap from 2.118 to 2.07 eV. The electrochemical and photoelectrochemical (PEC) performance of the films were examined by cyclic voltammetry, linear sweep voltammetry and chronoamperometry. The electrochemical oxidation of water achieved by Cobalt-doped Fe2O3@ GCE modified electrode exhibited the current density of 21 mA/g at 0.5 V vs. SCE for 5 at% of Co and reveals enhanced specific capacitance of 352.11 F/g. The catalytic performance of urea oxidation was measured by cyclic voltammetry on Co-Fe2O3@NiO nanoparticles modified glassy carbon electrode (GCE) in alkaline medium. The electrode Co-Fe2O3@NiO without annealing showed a peak current density of 1.59 mA/cm2 at 0.1 M urea in 1.0 M NaOH, which was 3.6 fold higher than that of Co-Fe2O3@NiO with annealing. In another part, this work reported the photoelectrochemical (PEC) properties of photoanode prepared by spin coating. The highest photocurrent 0.042 mA/cm2 at 0.5 V Vs SCE was obtained for 5% Co-Fe2O3@NiO while the photocatalytic oxidation of urea.
5,100원
6.
2022.06 구독 인증기관 무료, 개인회원 유료
Electrocatalytic reduction of 2,4 dinitrophenol on carbon black‑modified glassy carbon electrode and its selective recognition in cold beverages
Bose Dinesh, Anantharamakrishnan Aadhav, K. S. Shalini Devi, Uma Maheswari Krishnan
Carbon Letters Vol.32 No.4 pp.1017-1029 한국탄소학회
Nitrophenol sensors have garnered interest in pharmaceuticals, agriculture, environment safety and explosives. Various methods have been proposed to detect 4-nitrophenol, but nitrophenol isomers such as 2,4-dinitrophenol (DNP) and 2,4,6-trinitrophenol have been comparatively less studied. For the first time, the present work explores graphitic nanocarbon, i.e., carbon black (CB) interface for sensing of DNP. Two reduction potentials were noted at − 0.48 and − 0.64 V for o-NO2 and p-NO2 moieties, respectively, at CB/GCE. At the same time, bare GCE (glassy carbon electrode) shows a single reduction potential at − 0.7 V. The electrocatalytic effect and adsorption ability of the interface was studied from the DNP concentration effect. Scan rate and pH studies suggest that the CB acquires four electrons for NO2 reduction by the diffusion phenomenon. A broad detection range of 10–250 μM DNP with a very low detection limit of 0.13 (o-form) and 0.15 μM (p-form) was achieved using the CB interface. The real-time applicability of the fabricated sensor was evaluated using commercially available beverages with excellent recovery values. The stability, repeatability and reproducibility of the CB interface were successfully confirmed. Comparison of the sensing parameters of the developed sensor with those reported in literature reveals excellent detection limit and response time for the CB-interfaced DNP sensor, indicating its potential for environmental and commercial applications.
4,500원
7.
2022.06 구독 인증기관 무료, 개인회원 유료
Facile scalable synthesis of graphene oxide and reduced graphene oxide: comparative investigation of different reduction methods
Neeraj Kumar, Katlego Setshedi, Mike Masukume, Suprakas Sinha Ray
Carbon Letters Vol.32 No.4 pp.1031-1046 한국탄소학회
As frontier materials, graphene oxide (GO) and graphene have penetrated almost all research areas and advanced numerous technologies in sensing, electronics, energy storage, catalysis, water treatment, advanced composites, biomedical, and more. However, the affordable large-scale synthesis of high-quality GO and graphene remains a significant challenge that negatively affects its commercialisation. In this article, firstly, a simple, scalable approach was demonstrated to synthesise high-quality, high yield GO by modifying the improved Hummers method. The advantages of the optimised process are reduced oxidation time, straightforward washing steps without using coagulation step, reduction in cost as eliminating the use of phosphoric acid, use of minimum chemical reagents, and increased production of GO per batch (~ 62 g). Subsequently, the produced GO was reduced to reduced graphene oxide (rGO) using three different approaches: green reduction using ascorbic acid, hydrothermal and thermal reduction techniques. The GO and rGO samples were characterised using various microscopy and spectroscopy techniques such as XRD, Raman, SEM, TEM, XPS and TGA. The rGO prepared using different methods were compared thoroughly, and it was noticed that rGO produced by ascorbic acid reduction has high quality and high yield. Furthermore, surface (surface wettability, zeta potential and surface area) and electrical properties of GO and different rGO were evaluated. The presented synthesis processes might be potentially scaled up for large-scale production of GO and rGO.
4,900원
8.
2022.06 구독 인증기관 무료, 개인회원 유료
Reusable, magnetic laser‑induced graphene for efficient removal of organic pollutants from water
Ye Jiang, Sijie Wan, Weiwei Zhao, Wenjie Yu, Shuaipeng Wang, Zeqi Yu, Qiu Yang, Weihua Zhou, Xiaoqing Liu
Carbon Letters Vol.32 No.4 pp.1047-1064 한국탄소학회
The hybridization of graphene with magnetic nanoparticles has endowed graphene with increasing interest as the adsorbent for wastewater treatment. However, its fabrication often involves a multi-stepped chemical synthesis process. In this work, we demonstrate a facile, one-step, and solvent-free approach to fabricate Fe3O4 nanoparticle-anchored Laser-Induced Graphene ( Fe3O4@LIG) as an efficient adsorbent by direct laser irradiation on a ferric acetylacetonate containing polybenzoxazine film. Raman and X-ray diffraction analysis confirm the graphene component in the adsorbent, and the morphology characterizations show that Fe3O4 nanoparticles are distributed uniformly on LIG with hierarchical meso- and macro-porous structures. Adsorption experiments indicate that Fe3O4@ LIG can adsorb methylene blue (MB) from aqueous solutions in a fast and effective manner, with a maximum adsorption capacity up to 350.9 mg/g. The adsorption kinetics and isotherms are also investigated, which are well-described by the pseudo-second-order model and Langmuir model, respectively. Additionally, Fe3O4@ LIG is also demonstrated with the efficient removal of a variety of organic solvents from water. The favorable adsorption behavior of Fe3O4@ LIG is attributed to its unique porous structure and the molecular interactions with adsorbates. On the other hand, Fe3O4@ LIG has high magnetic property, and therefore, it could be easily recovered from water and well regenerated for repeated use. With the efficient adsorption of organic pollutants, magnetic separability, and good
5,200원
9.
2022.06 구독 인증기관 무료, 개인회원 유료
Development of nitrogen‑decorated carbon dots (NCDs) thermally conductive film for windows application
Ronn Goei, Frankie Ting Feng Tan, Amanda Jiamin Ong, Daniel Mandler, Alfred Iing Yoong Tok
Carbon Letters Vol.32 No.4 pp.1065-1072 한국탄소학회
A thermally conductive film can be used to laterally conduct heat along the surface of glass windows, toward its edges where a heat sink could be located, thereby reducing temperature differential between the inside and outside surfaces of the window and thus lowering cross-sectional conductive heat transfer. This technique can offer optimized thermal energy management to modern buildings without the weight and cost of double- or triple-glazed window panels. In this work, a thermally conductive film was developed using carbon dots with inherently high thermal conductivity. Nitrogen atoms were then added to the carbon dots structure to intensify high-frequency phonon that would result in higher lateral thermal conductivity. The nitrogen-decorated carbon dots (NCDs) were prepared by a simple hydrothermal synthesis of citric acid with the addition of ethylenediamine as the N source. The NCDs were added to a cellulose-based solution and drop-casted onto FTO glass resulting in a transparent, laterally thermally conductive film, that also blocks ultraviolet (UV) and high-intensity blue light radiation. The visible-light transmission of the NCDs’ film was found to be up to 65%, comparable to the commercial solar films. The lateral thermal conductivity of the NCDs’ film increases with increasing N content up to an optimum level, suggesting the role of N to “concentrate’ the high-frequency phonons responsible for effective lateral thermal conductivity of the films.
4,000원
10.
2022.06 구독 인증기관 무료, 개인회원 유료
In situ synthesis NiO/F‑MWCNTs nanocomposite for adsorption of malachite green dye from polluted water
Salam Hussein Alwan, Hassan Abbas Alshamsi
Carbon Letters Vol.32 No.4 pp.1073-1084 한국탄소학회
The presence of dyes in water is the most popular problem recently, so the current study was directed towards the synthesis of an effective material consisting of NiO and MWCNTs. The NiO/F-MWCNTs nanocomposite was synthesized using a simple hydrothermal method after functionalization of MWCNTs using sulfuric acid and nitric acid and utilized as an efficient surface to adsorption of malachite green dye from polluted water. The nanocomposite sample was characterized using several techniques are X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis (TGA), Field emission scanning electron microscopy (FESEM), High- resolution transmission electron microscopy (HRTEM), Brunauer–Emmett–Teller (BET) surface area analysis, Barrett-Joyner-Halenda (BJH) analysis and Energy dispersive X-ray (EDX). The analytical results showed that the prepared nanocomposite is of good crystalline nature with a particle size of 25.43 nm. A significant specific surface area was 412.08 m2/ g which indicates the effective impact of the nanocomposite in the adsorption of malachite green (MG) dye. On the other hand, the effect of adsorbent dose, temperature, acidic function and contact time on the adsorption efficiency of dye was studied. The kinetics of dye adsorption were also investigated employing two kinetic models, pseudo-first-order model and pseudo-second-order model. Finally, the thermodynamic functions were determined to identify the type of the reaction and the spontaneity of the process.
4,300원
11.
2022.06 구독 인증기관 무료, 개인회원 유료
Assessment of carbon fibers recovered from lab‑scale versus pilot‑scale mechanochemical CFRP depolymerization process based on fastrack thermal oxidation‑resistance characteristics
Caozheng Yan, Lewis Kamande Njaramba, Antony Mutua Nzioka, Benard Ouma Alunda, Myung‑Gyun Kim, Ye‑Jin Sim, Young‑Ju Kim
Carbon Letters Vol.32 No.4 pp.1085-1099 한국탄소학회
This study assessed the changes in the fiber properties of virgin and recovered fibers from lab-scale and pilot-scale depolymerization reactors based on the thermal air oxidation-resistance characteristics. Lab-scale and pilot-scale depolymerization reactors had different depolymerization volumes. Results showed that the lab-scale and pilot-scale peak solvent temperatures were 185 °C and 151 °C, respectively. The lab-scale had highest solvent temperature rate increase because of the small depolymerization volume and the dominant role of the cavitation volume. The structural properties of the recovered and virgin fibers were intact even after the depolymerization and after the pretreatment and oxidation-resistance test. We observed 1.213%, 1.027% and 0.842% weight loss for the recovered (lab-scale), the recovered (pilot-scale) and virgin fibers because of the removal of impurities from the surface and chemisorbed gases. Further, we observed 0.8% mass loss of the recovered fibers (lab-scale) after the oxidative-onset temperature because of the “cavitation erosion effect” from the dominant of the cavitation bubbles. The “cavitation erosion effect” was subdued because of the increased depolymerization volume in the pilot-scale reactor. Therefore, negligible impact of the pilot-scale mechanochemical recycling process on the structure and surface characteristics of the fibers and the possibility of reusing the recovered fibers recycling process were characteristic. Representative functional groups were affected by the thermal oxidation process. We conducted HPLC, HT-XRD, TGA– DSC, XPS, SEM, and AFM analysis and provided an extensive discussion of the test thereof. This study highlighted how misleading and insufficient small-lab-scale results could be in developing viable CFRP depolymerization process.
4,800원
12.
2022.06 구독 인증기관 무료, 개인회원 유료
The relationship between the molecular composition of coal and the conversion of its organic matter during thermal dissolution
V. A. Safin, P. N. Kuznetsov, B. Avid, L. I. Kuznetsova, Xing Fan, Z. R. Ismagilov
Carbon Letters Vol.32 No.4 pp.1101-1109 한국탄소학회
The team has studied the relationship between the ability of the coals to be dissolved in crude anthracene oil and their composition. The coal samples taken from different deposits in Russia and Mongolia were characterized by different stages of metamorphism and tested by the Fourier transform infrared spectroscopy and Carbon-13 nuclear magnetic resonance. The data of a correlation analysis enabled us to find out that an amount of aromatic structures in coal macromolecules provided the main influence on the thermal dissolution of the coals. The middle-rank coals had the highest rates of coal organic matter transfer to liquid products. The data showed that the dissolution process was accompanied by destruction of weak bonds among aliphatic groups. The amount of methylene groups in the aliphatic part of coal macromolecules had a direct impact on conversion of the coal organic matter into soluble products.
4,000원
13.
2022.06 구독 인증기관 무료, 개인회원 유료
Fibrous and granular activated carbon mixed media for effective gas removal as a cabin air filter
Jae‑Hyung Wee, Younghwan Bae, Hyunchul Ahn, Yeong Og Choi, Euigyung Jeong, Sang Young Yeo
Carbon Letters Vol.32 No.4 pp.1111-1118 한국탄소학회
There is a need for the purification of indoor air owing to a high rate of pollution in today’s world. For this, cabin air filters (CAFs) are widely used, which requires the addition of certain adsorbents to increase the volatile organic compound (VOC) removal efficiency. However, this addition causes high-pressure resistance, which may hamper commercial applications by requiring more energy and negatively affecting fresh air delivery rate. Hence, in this study, a high-performance combined CAF (CCAF) with excellent dust and chemical filtration performance and low differential pressure was prepared using granular activated carbon (GAC)/activated carbon fiber (ACF) mixed medium. The GAC/ACF mixed medium had higher air permeability than the ACF medium of the same weight, and it exhibited similar ultrafine dust filtration performance to the ACF medium without an increase in differential pressure. In addition, the GAC/ACF mixed medium showed excellent gas removal performance without increasing differential pressure by combining the VOC removal characteristics of the GAC and ACF filter media. The improved VOC removal performance of the GAC/ACF mixed medium was due to the hybrid effect of the hierarchical pore structures of the GAC and the nearly uniform pore structures of the ACF, which resulted in a slow and increased gas adsorption by the GAC and rapid gas adsorption of the ACF.
4,000원
14.
2022.06 구독 인증기관 무료, 개인회원 유료
Realization of diamond nucleation within the multi‑walled carbon nanotubes matrix upon electron irradiation
Surakanti Srinivas Reddy, Balmukund Shukla, V. Srihari, G. M. Bhalerao, N. V. Chandra Shekar
Carbon Letters Vol.32 No.4 pp.1119-1130 한국탄소학회
Individual multi-walled carbon nanotubes (MWCNTs) were exposed to the electron beam of 200 kV energy and high resolution transmission electron micrographs were recorded at several time intervals. Interestingly, the nucleation of diamond nanoparticles with in the highly disordered MWCNT matrix upon electron-irradiation is observed. This happens without any assistance of high pressures and temperatures. High pressure X-ray diffraction experiments were performed on core/shell structures which suggest that even the closed structures of carbon resist any inward pressure, thereby ruling out the possibility of a hypothetical internal pressure under the electron irradiation conditions. Our experiments suggest that the transformation of graphitic carbon into diamond in the size window of a few nanometers is possible due to the stability of the diamond and a selective dissolution effect of 200 kV electrons on graphite. A mechanism for the same is proposed.
4,300원
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